The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.
Integrating the g-C3N4 Nanosheet with B–H Bonding Decorated Metal–Organic Framework for CO2 Activation and Photoreduction
Abstract
BIF-20, a zeolite-like porous boron imidazolate framework with high density of exposed B–H bonding, is combined with graphitic carbon nitride (g-C 3 N 4 ) nanosheets via a facile electrostatic self-assembly approach under room temperature, forming an elegant composite BIF-20@g-C 3 N 4 nanosheet. The as-constructed composite preferably captures CO 2 and further photoreduces CO 2 in high efficiency. The photogenerated excitations from the carbon nitride nanosheet can directionally migrate to B–H bonding, which effectively suppresses electron–hole pair recombination and thus greatly improves the photocatalytic ability. Compared to the g-C 3 N 4 nanosheet, the BIF-20@g-C 3 N 4 nanosheet composite displayed a much-enhanced photocatalytic CO 2 reduction activity, which is equal to 9.7-fold enhancements in the CH 4 evolution rate (15.524 μmol g –1 h –1 ) and 9.85-fold improvements in CO generation rate (53.869 μmol g –1 h –1 ). Density functional theory simulations further prove that the presence of B–H bonding in the composite is favorable for CO 2 adhesion and activation in the reaction process. Thus, we believe that the implantation of functional active sites into the porous matrix provides important insights for preparation of a highly efficient photocatalyst.
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A metal-free polymeric photocatalyst for hydrogen production from water under visible light
Wang, X., Maeda, K., Thomas, A., Takanabe, K., Xin, G., Carlsson, J. M., Domen, K., & Antonietti, M. (2009) · Nature Materials · doi:10.1038/nmat2317 · Cited by 12,532
Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy
Linic, S., Christopher, P., & Ingram, D. B. (2011) · Nature Materials · doi:10.1038/nmat3151 · Cited by 4,852
Carbon Dioxide Capture: Prospects for New Materials
D'Alessandro, D. M., Smit, B., & Long, J. R. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000431 · Cited by 4,046
Polymeric Photocatalysts Based on Graphitic Carbon Nitride
Cao, S., Low, J., Yu, J., & Jaroniec, M. (2015) · Advanced Materials · doi:10.1002/adma.201500033 · Cited by 3,674
Yang, S., Gong, Y., Zhang, J., Zhan, L., Ma, L., Fang, Z., Vajtai, R., Wang, X., & Ajayan, P. M. (2013) · Advanced Materials · doi:10.1002/adma.201204453 · Cited by 2,515
Self-citationYu, H., Shi, R., Zhao, Y., Bian, T., Zhao, Y., Zhou, C., Waterhouse, G. I. N., Wu, L., Tung, C., & Zhang, T. (2017) · Advanced Materials · doi:10.1002/adma.201605148 · Cited by 2,257
Enhanced Photoresponsive Ultrathin Graphitic-Phase C3N4Nanosheets for Bioimaging
Zhang, X., Xie, X., Wang, H., Zhang, J., Pan, B., & Xie, Y. (2013) · Journal of the American Chemical Society · doi:10.1021/ja308249k · Cited by 2,136
Self-citationCO2 photo-reduction: insights into CO2 activation and reaction on surfaces of photocatalysts
Chang, X., Wang, T., & Gong, J. (2016) · Energy & Environmental Science · doi:10.1039/c6ee00383d · Cited by 2,018
Fu, Y., Sun, D., Chen, Y., Huang, R., Ding, Z., Fu, X., & Li, Z. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201108357 · Cited by 1,741
Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes
White, J. L., Baruch, M. F., Pander, J. E., Hu, Y., Fortmeyer, I. C., Park, J. E., Zhang, T., Liao, K., Gu, J., Yan, Y., et al. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00370 · Cited by 1,673
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Surface Modification of 2D Photocatalysts for Solar Energy Conversion
Feng, C., Wu, Z., Huang, K., Ye, J., & Zhang, H. (2022) · Advanced Materials · doi:10.1002/adma.202200180 · Cited by 456
Self-citationYu, Y., & Huang, H. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.139755 · Cited by 280
Synthesis of ultrathin porous C3N4-modified Co3O4 nanosheets for enhanced oxygen evolution reaction
Wang, H., Liu, Y., Sun, Z., Ren, J., Zou, X., & Zhang, C.-Y. (2021) · Electrochimica Acta · doi:10.1016/j.electacta.2020.137537 · Cited by 17
Metadata
- Authors
- Xu, G., Zhang, H., Wei, J., Zhang, H.-X., Wu, X., Li, Y., Li, C., Zhang, J., & Ye, J.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-05-29
- Volume
- 12
- Issue
- 6
- Pages
- 5333-5340
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2806280576
- Cited by
- 298
- References
- 45
- FWCI
- 9.11
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xu, G., Zhang, H., Wei, J., Zhang, H.-X., Wu, X., Li, Y., Li, C., Zhang, J., & Ye, J. (2018). Integrating the g-C3N4 Nanosheet with B–H Bonding Decorated Metal–Organic Framework for CO2 Activation and Photoreduction. ACS Nano. https://doi.org/10.1021/acsnano.8b00110
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