Lipase-catalysed degradation of copolymers prepared from ɛ-caprolactone and dl-lactide
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Lipases were shown to degrade PCL, PLLA, poly(g-butyrolactone), PHB, poly(butylene succinate adipate), PCL/PBS blend and poly(propylene carbonate) in PBS at 37 °C, producing mainly short oligomers.
“Lipases were shown to degrade PCL, [504][505][506][507][508]504,505 PLLA,509 poly(g-butyrolactone), 507 PHB, 508,510 poly(butylene succinate adipate), 511 PCL/PBS blend 511 and poly(propylene carbonate) 508 in PBS at 37 °C, producing mainly short oligomers.”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [504]
Vert et al. showed that Pseudomonas lipase could break down the crystalline domains of PCL within days, in contrast to hydrolytic degradation that would take several years.
“Noteworthy, Vert et al. showed that Pseudomonas lipase could break down the crystalline domains of PCL within days in contrast to hydrolytic degradation that would take several years to do the same.504”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [504]
Cites
Biodegradable polyesters for medical and ecological applications
Ikada, Y., & Tsuji, H. (2000) · Macromolecular Rapid Communications · doi:10.1002/(sici)1521-3927(20000201)21:3 · Cited by 1,515 · see citing works
Large-scale production, properties and commercial applications of polylactic acid polymers
Lunt, J. (1998) · Polymer Degradation and Stability · doi:10.1016/s0141-3910(97)00148-1 · Cited by 1,366 · see citing works
The Case for Polylactic Acid as a Commodity Packaging Plastic
Sinclair, R. (1996) · Journal of Macromolecular Science Part A · doi:10.1080/10601329608010880 · Cited by 455 · see citing works
Polylactide stereochemistry: effect on enzymic degradability
Reeve, M. S., McCarthy, S. P., Downey, M. J., & Gross, R. A. (1994) · Macromolecules · doi:10.1021/ma00081a030 · Cited by 433 · see citing works
Enzymic Hydrolysis of Polylactic Acid
Williams, D. F. (1981) · Engineering in Medicine · doi:10.1243/emed_jour_1981_010_004_02 · Cited by 358 · see citing works
(1984) · Springer eBooks · doi:10.1007/978-1-4613-2433-1 · Cited by 314 · see citing works
Polylactide Degradation by an Amycolatopsis sp
Pranamuda, H., Tokiwa, Y., & Tanaka, H. (1997) · Applied and Environmental Microbiology · doi:10.1128/aem.63.4.1637-1640.1997 · Cited by 288 · see citing works
Selective Enzymatic Degradations of Poly( l -lactide) and Poly(ε-caprolactone) Blend Films
Liu, L., Li, S., Garreau, H., & Vert, M. (2000) · Biomacromolecules · doi:10.1021/bm000046k · Cited by 272 · see citing works
Self-citationEnzymatic degradation of poly(ε-caprolactone) film in phosphate buffer solution containing lipases
Gan, Z., Liang, Q., Zhang, J., & Jing, X. (1997) · Polymer Degradation and Stability · doi:10.1016/s0141-3910(96)00208-x · Cited by 233 · see citing works
Structural Effects upon Enzymatic Hydrolysis of Poly(butylene succinate-co-ethylene succinate)s
Mochizuki, M., Mukai, K., Yamada, K., Ichise, N., Murase, S., & Iwaya, Y. (1997) · Macromolecules · doi:10.1021/ma970036k · Cited by 223 · see citing works
Huang, M.-H., Li, S., & Vert, M. (2004) · Polymer · doi:10.1016/j.polymer.2004.10.054 · Cited by 222 · see citing works
Self-citationEnzymatic degradation of poly(ε-caprolactone)/poly(dl-lactide) blends in phosphate buffer solution
Gan, Z., Yu, D., Zhong, Z., Liang, Q., & Jing, X. (1999) · Polymer · doi:10.1016/s0032-3861(98)00549-7 · Cited by 217 · see citing works
Influence of Crystallinity and Stereochemistry on the Enzymatic Degradation of Poly(lactide)s
Li, S., & McCarthy, S. (1999) · Macromolecules · doi:10.1021/ma990117b · Cited by 212 · see citing works
Self-citationBiodegradable plastics: A review
Huang, J., Shetty, A., & Wang, M. (1990) · Advances in Polymer Technology · doi:10.1002/adv.1990.060100103 · Cited by 188 · see citing works
Hydrolysis of polycaprolactone fibers by lipase: Effects of draw ratio on enzymatic degradation
Mochizuki, M., Hirano, M., Kanmuri, Y., Kudo, K., & Tokiwa, Y. (1995) · Journal of Applied Polymer Science · doi:10.1002/app.1995.070550212 · Cited by 175 · see citing works
Enzymatic Degradation of Block Copolymers Prepared from ε-Caprolactone and Poly(ethylene glycol)
Li, S., Garreau, H., Pauvert, B., McGrath, J. G., Toniolo, A., & Vert, M. (2002) · Biomacromolecules · doi:10.1021/bm010168s · Cited by 128 · see citing works
Self-citationTsuji, H., & Miyauchi, S. (2001) · Polymer · doi:10.1016/s0032-3861(00)00792-8 · Cited by 127 · see citing works
Tsuji, H., Mizuno, A., & Ikada, Y. (1998) · Journal of Applied Polymer Science · doi:10.1002/(sici)1097-4628(19981212)70:11 · Cited by 126 · see citing works
He, F., Li, S., Vert, M., & Zhuo, R. (2003) · Polymer · doi:10.1016/s0032-3861(03)00562-7 · Cited by 118 · see citing works
Self-citationFukuzaki, H., Yoshida, M., Asano, M., Kumakura, M., Mashimo, T., Yuasa, H., Imai, K., & Yamanaka, H. (1990) · Polymer · doi:10.1016/0032-3861(90)90031-s · Cited by 118 · see citing works
Poly(lactic acid) degradation in soil or under controlled conditions
Torres, A., Li, S., Roussos, S., & Vert, M. (1996) · Journal of Applied Polymer Science · doi:10.1002/(sici)1097-4628(19961226)62:13 · Cited by 116 · see citing works
Self-citationWang, J., & Dong, C. (2006) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200500546 · Cited by 76 · see citing works
Li, S., Espartero, J. L., Foch, P., & Vert, M. (1997) · Journal of Biomaterials Science Polymer Edition · doi:10.1163/156856296x00237 · Cited by 65 · see citing works
Self-citationBiodegradation of polycaprolactone by micro-organisms from an industrial compost of household refuse
Lefebvre, F., David, C., & Wauven, C. V. (1994) · Polymer Degradation and Stability · doi:10.1016/0141-3910(94)90204-6 · Cited by 63 · see citing works
Zhao, Z., Yang, L., Hu, Y., He, Y., Wei, J., & Li, S. (2007) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2007.07.012 · Cited by 56 · see citing works
Self-citationLi, S., Pignol, M., Gasc, F., & Vert, M. (2004) · Macromolecules · doi:10.1021/ma0489422 · Cited by 41 · see citing works
Self-citationPreparation and biodegradation of polycaprolactone-paper composites
Akahori, S.-I., & Osawa, Z. (1994) · Polymer Degradation and Stability · doi:10.1016/0141-3910(94)90194-5 · Cited by 31 · see citing works
Liu, F., Zhao, Z., Yang, J., Wei, J., & Li, S. (2009) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2008.10.023 · Cited by 29 · see citing works
Self-citationRelationship between Enzyme Adsorption and Enzyme‐Catalyzed Degradation of Polylactides
Zhao, Z., Yang, L., Hua, J., Wei, J., Gachet, S., Ghzaoui, A. E., & Li, S. (2008) · Macromolecular Bioscience · doi:10.1002/mabi.200700180 · Cited by 25 · see citing works
Self-citationBraud, C. (2004) · Journal of Biomaterials Science Polymer Edition · doi:10.1163/156856204323005299 · Cited by 7 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Catalysis as an Enabling Science for Sustainable Polymers
Zhang, X., Fevre, M., Jones, G. O., & Waymouth, R. M. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00329 · Cited by 936 · see citing works
Microbial Enzymes Used in Bioremediation
Bhandari, S., Poudel, D. K., Marahatha, R., Dawadi, S., Khadayat, K., Phuyal, S., Shrestha, S., Gaire, S., Basnet, K., Khadka, U., et al. (2021) · Journal of Chemistry · doi:10.1155/2021/8849512 · Cited by 298 · see citing works
Biodegradation of Hazardous and Special Products
Chamy, R., & Rosenkranz, F. (2013) · InTech eBooks · doi:10.5772/52778 · Cited by 54 · see citing works
Dias, J. C., Ribeiro, C., Sencadas, V., Botelho, G., Ribelles, J. L. G., & Lanceros-Méndez, S. (2012) · Polymer Testing · doi:10.1016/j.polymertesting.2012.05.007 · Cited by 39 · see citing works
Ferreira, J. C. M., Gloria, A., Cometa, S., Coelho, J. F. J., & Domingos, M. A. N. (2017) · Journal of Applied Biomaterials & Functional Materials · doi:10.5301/jabfm.5000363 · Cited by 32 · see citing works
Study on the enzymatic degradation of aliphatic polyester–PBS and its copolymers
Ding, M., Zhang, M., Yang, J., & Qiu, J. (2011) · Journal of Applied Polymer Science · doi:10.1002/app.35347 · Cited by 24 · see citing works
Study on the enzymatic degradation of PBS and its alcohol acid modified copolymer
Ding, M., Zhang, M., Yang, J., & Qiu, J. (2011) · Biodegradation · doi:10.1007/s10532-011-9492-y · Cited by 21 · see citing works
Four-armed PCL-b-PDLA diblock copolymer: 1. Synthesis, crystallization and degradation
Ning, Z., Jiang, N., & Gan, Z. (2014) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2014.05.016 · Cited by 16 · see citing works
Liu, F., Yang, J. H., Fan, Z., Li, S., Kasperczyk, J., & Dobrzyński, P. (2012) · Journal of Biomaterials Science Polymer Edition · doi:10.1163/092050611x581525 · Cited by 15 · see citing works
Self-citationZhu, W., Sun, S., Xu, N., & Shen, Z. (2011) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24956 · Cited by 12 · see citing works
Review of crosslinked and non‐crosslinked copolyesters for tissue engineering and drug delivery
Zhao, X., Sun, L., Wang, M., Sun, Z., & Xie, J. (2013) · Polymer International · doi:10.1002/pi.4658 · Cited by 11 · see citing works
Biodegradation of in situ‐forming gel of poly(DLLA‐co‐CL) in vivo
Zhang, C., Zhang, X., Yang, D., & Wang, P. (2013) · Journal of Applied Polymer Science · doi:10.1002/app.39646 · Cited by 8 · see citing works
Cyclodextrin-based biodegradable polymer stars: synthesis and fluorescence studies
Tennekone, G. K., Wagner, B. D., & Shaver, M. P. (2013) · Green Materials · doi:10.1680/gmat.13.00012 · Cited by 8 · see citing works
Kodama, Y. (2013) · InTech eBooks · doi:10.5772/56231 · Cited by 6 · see citing works
Jiang, T., He, F., & Zhuo, R. (2012) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2012.09.009 · Cited by 5 · see citing works
Bazeed, A. Y., Clulow, A. J., Roeger, L., Bobrovskaya, L., Wiese, M. D., & Blencowe, A. (2026) · European Polymer Journal · doi:10.1016/j.eurpolymj.2026.114757 · Cited by 1 · see citing works
Biodegradability of lactide–caprolactone macromonomers in wastewater
Moore, R. K., Gleisner, R., & Houtman, C. J. (2021) · BioResources · doi:10.15376/biores.16.2.4081-4092 · Cited by 1 · see citing works
Emerging Perspectives in the Synthesis of Novel Degradable Biomedical Copolymers
Zhao, X., Wang, M., Gao, W., Sun, Z., & Xie, J. (2014) · Polymer-Plastics Technology and Engineering · doi:10.1080/03602559.2014.935426
- Authors
- Lenglet, S., Li, S., & Vert, M.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Li, Suming
- Venue
- Polymer Degradation and Stability
- Publisher
- Elsevier BV
- Published
- 2009-04
- Volume
- 94
- Issue
- 4
- Pages
- 688-692
- ISSN
- 0141-3910 (ISSN-L)
- OpenAlex
- W2080361156
- Cited by
- 19
- References
- 30
- Citations by year
- 2026: 1 · 2021: 2 · 2017: 2 · 2014: 2 · 2013: 5 · 2012: 3
- FWCI
- 1.02
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Polymer Degradation and Stability (publishedVersion)
- HAL (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Keywords
- ε-caprolactone, D,L-lactide, Pseudomonas lipase, ring-opening polymerization, semi-crystalline structure, surface erosion, biodegradable polymers, phosphate buffer
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review