Cited by 1,397Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPhotopolymerization techniques and applications

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Radical addition–fragmentation chemistry in polymer synthesis

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Moad, Graeme, Rizzardo, Ezio, Thang, San H.·2008·Polymer

DOI 10.1016/j.polymer.2007.11.020

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Abstract

This review traces the development of addition–fragmentation chain transfer agents and related ring-opening monomers highlighting recent innovation in these areas. The major part of this review deals with reagents that give reversible addition–fragmentation chain transfer (RAFT). These reagents include dithioesters, trithiocarbonates, dithiocarbamates and xanthates. The RAFT process is a versatile method for conferring living characteristics on radical polymerizations providing unprecedented control over molecular weight, molecular weight distribution, composition and architecture. It is suitable for most monomers polymerizable by radical polymerization and is robust under a wide range of reaction conditions. It provides a route to functional polymers, cyclopolymers, gradient copolymers, block polymers and star polymers.

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Chiefari, J., Chong, Y. K. (., Ercole, F., Krstina, J., Jeffery, J. L., Le, T. P. T., Mayadunne, R. T. A., Meijs, G. F., Moad, C. L., Moad, G., et al. (1998) · Macromolecules · doi:10.1021/ma9804951 · Cited by 5,147
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Moad, G., Rizzardo, E., & Thang, S. H. (2005) · Australian Journal of Chemistry · doi:10.1071/ch05072 · Cited by 2,286
Self-citation
A new method for the deoxygenation of secondary alcohols
Barton, D. H. R., & McCombie, S. W. (1975) · Journal of the Chemical Society Perkin Transactions 1 · doi:10.1039/p19750001574 · Cited by 1,666
Handbook of Radical Polymerization
Matyjaszewski, K. A., & Davis, T. P. (2002) · Wiley eBooks · doi:10.1002/0471220450 · Cited by 1,595
Functional Polymers from Novel Carboxyl-Terminated Trithiocarbonates as Highly Efficient RAFT Agents
Lai, J. T., Filla, D., & Shea, R. (2002) · Macromolecules · doi:10.1021/ma020362m · Cited by 1,484
Macromolecular design via reversible addition–fragmentation chain transfer (RAFT)/xanthates (MADIX) polymerization
Perrier, S., & Takolpuckdee, P. (2005) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.20986 · Cited by 1,157
Radicals in organic synthesis : formation of carbon-carbon bonds
Giese, B. (1986) · Pergamon Press eBooks · Cited by 1,083
A more versatile route to block copolymers and other polymers of complex architecture by living radical polymerization: The raft process
Chong, ). Y. K., Le, T. P. T., Moad, G., Rizzardo, E., & Thang, S. H. (1999) · Macromolecules · doi:10.1021/ma981472p · Cited by 850
Self-citation
Living Radical Polymerization by the RAFT Process—A First Update
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Self-citation

Show all 528 references

Research works printed but not linked: 25

Otsu, 1982, Polym Bull, 7, 45
McCormick, 2006, Polym Rev, 46, 421
Yakimansky, 2005, Polym Sci Ser C, 47, 1
Golubev, 2005, Polym Sci Ser A, 47, 678
Cho, 1990, J Polym Sci Part A Polym Chem, 28, 417
Bailey WJ, Arfaei PY, Chen PY, Chen S-C, Endo T, Pan C-Y, et al. Proc. IUPAC 28th Macromol. Symp. Amherst, MA; 1982. p. 214.
Sidney, 1981, Polym Prepr (Am Chem Soc Div Polym Chem), 22, 373
Kobayashi, 1991, Macromol Rep, A28, 1
Kobayashi, 1992, Macromol Rep, A29, 243
Meijs, 1992, Polym Prepr (Am Chem Soc Div Polym Chem), 33, 893
Chaumont, 1995, Macromol Chem Phys, 196, 947, 10.1002/macp.1995.021960322 · DOI
Harrison DS. M.Sc. thesis. Hawthorn, Victoria: Swinburne University; 1988.
Zhu, 2003, e-Polymers, 043
Aoyagi, 2006, Synlett, 636
Zhou, 2006, e-Polymers, 59
Yu, 2007, e-Polymers
Fox, 2003, Synlett, 2037
You, 2002, Macromol Chem Phys, 203, 477, 10.1002/1521-3935(20020201)203:3<477::AID-MACP477>3.0.CO;2-M · DOI
Bai, 2001, Macromol Chem Phys, 202, 1970, 10.1002/1521-3935(20010601)202:9<1970::AID-MACP1970>3.0.CO;2-Q · DOI
Arita, 2004, e-Polymers, 003
Uzulina, 2000, Macromol Symp, 150, 33, 10.1002/1521-3900(200002)150:1<33::AID-MASY33>3.0.CO;2-C · DOI
Butte, 2001, DECHEMA Monograph, 137, 273
Chong YK, Moad G, Rizzardo E, Skidmore MA, Thang SH. Macromolecules, in press.
Cerreta, 1995, Bull Soc Chim Fr, 132, 67
Rizzardo, 2001, Macromol Symp, 174, 209, 10.1002/1521-3900(200109)174:1<209::AID-MASY209>3.0.CO;2-O · DOI

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Authors: Moad, G., Rizzardo, E., & Thang, S. H.
Affiliations: Commonwealth Scientific and Industrial Research Organisation (AU)
Corresponding author: Moad, Graeme
Rizzardo, Ezio
Thang, San H.
ORCID: Moad, Graeme
Thang, San H.
Venue: Polymer
Publisher: Elsevier BV
Published: 2008-03
Volume: 49
Issue: 5
Pages: 1079-1131
ISSN: 0032-3861 (ISSN-L)
DOI: 10.1016/j.polymer.2007.11.020
OpenAlex: W2040062577
Cited by: 1,397
References: 528
Citations by year: 2026: 13 · 2025: 29 · 2024: 41 · 2023: 29 · 2022: 41 · 2021: 71 · 2020: 64 · 2019: 92 · 2018: 76 · 2017: 79 · 2016: 85 · 2015: 93 · 2014: 90 · 2013: 100 · 2012: 117
FWCI: 46.82
Type: journal article
Language: en
Open access: hybrid
doi.org
Licence: cc-by-nc-nd
www.elsevier.com/tdm/userlicense/1.0/ (tdm)
creativecommons.org/licenses/by-nc-nd/4.0/ (vor, 1963 d)
Locations: Polymer (publishedVersion, cc-by-nc-nd)
Funders: Commonwealth Scientific and Industrial Research Organisation
Topics: Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
Physical Sciences › Chemistry › Organic Chemistry › Photopolymerization techniques and applications
Keywords: RAFT polymerization, RAFT agents, dithioesters, trithiocarbonates, dithiocarbamates, xanthates, controlled radical polymerization, block copolymers, star polymers, cyclopolymers, gradient copolymers, molecular weight control

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Radical addition–fragmentation chemistry in polymer synthesis

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