Cited by 1,397Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPhotopolymerization techniques and applications

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Radical addition–fragmentation chemistry in polymer synthesis

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Moad, Graeme, Rizzardo, Ezio, Thang, San H.·2008·Polymer

DOI 10.1016/j.polymer.2007.11.020

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Abstract

This review traces the development of addition–fragmentation chain transfer agents and related ring-opening monomers highlighting recent innovation in these areas. The major part of this review deals with reagents that give reversible addition–fragmentation chain transfer (RAFT). These reagents include dithioesters, trithiocarbonates, dithiocarbamates and xanthates. The RAFT process is a versatile method for conferring living characteristics on radical polymerizations providing unprecedented control over molecular weight, molecular weight distribution, composition and architecture. It is suitable for most monomers polymerizable by radical polymerization and is robust under a wide range of reaction conditions. It provides a route to functional polymers, cyclopolymers, gradient copolymers, block polymers and star polymers.

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Thermal degradation of nylon polymers
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Copolymerization of ω-Unsaturated Oligo(Methyl Methacrylate): New Macromonomers
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Ambient temperature reversible addition–fragmentation chain transfer polymerisation
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Preparation of controlled-molecular-weight, olefin-terminated polymers by free radical methods. Chain transfer using allylic sulfides
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Self-citation
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Computational Studies of RAFT Polymerization–Mechanistic Insights and Practical Applications
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General Kinetic Analysis and Comparison of Molecular Weight Distributions for Various Mechanisms of Activity Exchange in Living Polymerizations
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Modeling RAFT polymerization kinetics via Monte Carlo methods: cumyl dithiobenzoate mediated methyl acrylate polymerization
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Z-RAFT Star Polymerizations of Acrylates: Star Coupling via Intermolecular Chain Transfer to Polymer
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Free Radical Ring-Opening Polymerization
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See all 1,397

Authors: Moad, G., Rizzardo, E., & Thang, S. H.
Affiliations: Commonwealth Scientific and Industrial Research Organisation (AU)
Corresponding author: Moad, Graeme
Rizzardo, Ezio
Thang, San H.
ORCID: Moad, Graeme
Thang, San H.
Venue: Polymer
Publisher: Elsevier BV
Published: 2008-03
Volume: 49
Issue: 5
Pages: 1079-1131
ISSN: 0032-3861 (ISSN-L)
DOI: 10.1016/j.polymer.2007.11.020
OpenAlex: W2040062577
Cited by: 1,397
References: 528
Citations by year: 2026: 13 · 2025: 29 · 2024: 41 · 2023: 29 · 2022: 41 · 2021: 71 · 2020: 64 · 2019: 92 · 2018: 76 · 2017: 79 · 2016: 85 · 2015: 93 · 2014: 90 · 2013: 100 · 2012: 117
FWCI: 46.82
Type: journal article
Language: en
Open access: hybrid
doi.org
Licence: cc-by-nc-nd
www.elsevier.com/tdm/userlicense/1.0/ (tdm)
creativecommons.org/licenses/by-nc-nd/4.0/ (vor, 1963 d)
Locations: Polymer (publishedVersion, cc-by-nc-nd)
Funders: Commonwealth Scientific and Industrial Research Organisation
Topics: Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
Physical Sciences › Chemistry › Organic Chemistry › Photopolymerization techniques and applications
Keywords: RAFT polymerization, RAFT agents, dithioesters, trithiocarbonates, dithiocarbamates, xanthates, controlled radical polymerization, block copolymers, star polymers, cyclopolymers, gradient copolymers, molecular weight control

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Radical addition–fragmentation chemistry in polymer synthesis

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