Cited by 1,397Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPhotopolymerization techniques and applications

The DOI matches its Crossref record; 517 of the 528 references it cites were found in a registry or an index.

Radical addition–fragmentation chemistry in polymer synthesis

Open access

Moad, Graeme, Rizzardo, Ezio, Thang, San H.·2008·Polymer

DOI 10.1016/j.polymer.2007.11.020

Open this paper in CoChat — free account Open PDF

Abstract

This review traces the development of addition–fragmentation chain transfer agents and related ring-opening monomers highlighting recent innovation in these areas. The major part of this review deals with reagents that give reversible addition–fragmentation chain transfer (RAFT). These reagents include dithioesters, trithiocarbonates, dithiocarbamates and xanthates. The RAFT process is a versatile method for conferring living characteristics on radical polymerizations providing unprecedented control over molecular weight, molecular weight distribution, composition and architecture. It is suitable for most monomers polymerizable by radical polymerization and is robust under a wide range of reaction conditions. It provides a route to functional polymers, cyclopolymers, gradient copolymers, block polymers and star polymers.

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

Integrity signals

Registry

Crossref · 10.1016/j.polymer.2007.11.020

Cites

517 of 517 references verified0 citation errors · 0 not checkable

Statistics

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Living Free-Radical Polymerization by Reversible Addition−Fragmentation Chain Transfer: The RAFT Process
Chiefari, J., Chong, Y. K. (., Ercole, F., Krstina, J., Jeffery, J. L., Le, T. P. T., Mayadunne, R. T. A., Meijs, G. F., Moad, C. L., Moad, G., et al. (1998) · Macromolecules · doi:10.1021/ma9804951 · Cited by 5,147
Self-citation
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
Living Radical Polymerization by the RAFT Process
Moad, G., Rizzardo, E., & Thang, S. H. (2005) · Australian Journal of Chemistry · doi:10.1071/ch05072 · Cited by 2,286
Self-citation
A new method for the deoxygenation of secondary alcohols
Barton, D. H. R., & McCombie, S. W. (1975) · Journal of the Chemical Society Perkin Transactions 1 · doi:10.1039/p19750001574 · Cited by 1,666
Handbook of Radical Polymerization
Matyjaszewski, K. A., & Davis, T. P. (2002) · Wiley eBooks · doi:10.1002/0471220450 · Cited by 1,595
Functional Polymers from Novel Carboxyl-Terminated Trithiocarbonates as Highly Efficient RAFT Agents
Lai, J. T., Filla, D., & Shea, R. (2002) · Macromolecules · doi:10.1021/ma020362m · Cited by 1,484
Macromolecular design via reversible addition–fragmentation chain transfer (RAFT)/xanthates (MADIX) polymerization
Perrier, S., & Takolpuckdee, P. (2005) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.20986 · Cited by 1,157
Radicals in organic synthesis : formation of carbon-carbon bonds
Giese, B. (1986) · Pergamon Press eBooks · Cited by 1,083
A more versatile route to block copolymers and other polymers of complex architecture by living radical polymerization: The raft process
Chong, ). Y. K., Le, T. P. T., Moad, G., Rizzardo, E., & Thang, S. H. (1999) · Macromolecules · doi:10.1021/ma981472p · Cited by 850
Self-citation
Living Radical Polymerization by the RAFT Process—A First Update
Moad, G., Rizzardo, E., & Thang, S. H. (2006) · Australian Journal of Chemistry · doi:10.1071/ch06250 · Cited by 847
Self-citation

Show all 528 references

Research works printed but not linked: 25

Otsu, 1982, Polym Bull, 7, 45
McCormick, 2006, Polym Rev, 46, 421
Yakimansky, 2005, Polym Sci Ser C, 47, 1
Golubev, 2005, Polym Sci Ser A, 47, 678
Cho, 1990, J Polym Sci Part A Polym Chem, 28, 417
Bailey WJ, Arfaei PY, Chen PY, Chen S-C, Endo T, Pan C-Y, et al. Proc. IUPAC 28th Macromol. Symp. Amherst, MA; 1982. p. 214.
Sidney, 1981, Polym Prepr (Am Chem Soc Div Polym Chem), 22, 373
Kobayashi, 1991, Macromol Rep, A28, 1
Kobayashi, 1992, Macromol Rep, A29, 243
Meijs, 1992, Polym Prepr (Am Chem Soc Div Polym Chem), 33, 893
Chaumont, 1995, Macromol Chem Phys, 196, 947, 10.1002/macp.1995.021960322 · DOI
Harrison DS. M.Sc. thesis. Hawthorn, Victoria: Swinburne University; 1988.
Zhu, 2003, e-Polymers, 043
Aoyagi, 2006, Synlett, 636
Zhou, 2006, e-Polymers, 59
Yu, 2007, e-Polymers
Fox, 2003, Synlett, 2037
You, 2002, Macromol Chem Phys, 203, 477, 10.1002/1521-3935(20020201)203:3<477::AID-MACP477>3.0.CO;2-M · DOI
Bai, 2001, Macromol Chem Phys, 202, 1970, 10.1002/1521-3935(20010601)202:9<1970::AID-MACP1970>3.0.CO;2-Q · DOI
Arita, 2004, e-Polymers, 003
Uzulina, 2000, Macromol Symp, 150, 33, 10.1002/1521-3900(200002)150:1<33::AID-MASY33>3.0.CO;2-C · DOI
Butte, 2001, DECHEMA Monograph, 137, 273
Chong YK, Moad G, Rizzardo E, Skidmore MA, Thang SH. Macromolecules, in press.
Cerreta, 1995, Bull Soc Chim Fr, 132, 67
Rizzardo, 2001, Macromol Symp, 174, 209, 10.1002/1521-3900(200109)174:1<209::AID-MASY209>3.0.CO;2-O · DOI

Sorted by citations

Items 501–600 of 1,001

Visual recognition of supramolecular graft polymer formation via phenolphthalein–cyclodextrin association
Hetzer, M., Fleischmann, C., Schmidt, B. V. K. J., Barner‐Kowollik, C., & Ritter, H. (2013) · Polymer · doi:10.1016/j.polymer.2013.07.031 · Cited by 35
Well‐defined amphiphilic graft copolymer consisting of hydrophilic poly(acrylic acid) backbone and hydrophobic poly(vinyl acetate) side chains
Li, Y., Zhang, Y., Yang, D. S., Feng, C., Zhai, S., Hu, J., Lu, G., & Huang, X. (2009) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.23646 · Cited by 35
Efficient synthesis of monodisperse, highly crosslinked, and “living” functional polymer microspheres by the ambient temperature iniferter‐induced “living” radical precipitation polymerization
Zhao, M., Zhang, H., Ma, F., Zhang, Y., Guo, X., & Zhang, H. (2013) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.26579 · Cited by 35
Cation-Condensed Microgel-Core Star Polymers as Polycationic Nanocapsules for Molecular Capture and Release in Water
Fukae, K., Terashima, T., & Sawamoto, M. (2012) · Macromolecules · doi:10.1021/ma300266k · Cited by 35
One-Step Synthesis of Amphiphilic, Double Thermoresponsive Diblock Copolymers
Weiss, J., & Laschewsky, A. (2012) · Macromolecules · doi:10.1021/ma300285y · Cited by 35
PLMA‐b‐POEGMA amphiphilic block copolymers: Synthesis and self‐assembly in aqueous media
Skandalis, A., & Pispas, S. (2016) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.28379 · Cited by 35
Recent Advances in the Synthesis of Polymer-Grafted Low-K and High-K Nanoparticles for Dielectric and Electronic Applications
Tawade, B. V., Apata, I. E., Pradhan, N. R., Karim, A., & Raghavan, D. (2021) · Molecules · doi:10.3390/molecules26102942 · Cited by 34
Dual Concurrent ATRP/RAFT of Methyl Acrylate Co-initiated by Alkyl Halides
Elsen, A. M., Nicolaÿ, R., & Matyjaszewski, K. A. (2011) · Macromolecules · doi:10.1021/ma200263w · Cited by 35
Synthesis of Hyperbranched Polymers with Pendent Norbornene Functionalities via RAFT Polymerization of a Novel Asymmetrical Divinyl Monomer
Dong, Z., Liu, X., Tang, X.-L., & Li, Y. (2009) · Macromolecules · doi:10.1021/ma9005796 · Cited by 35
Synthesis of click‐reactive HPMA copolymers using RAFT polymerization for drug delivery applications
Ebbesen, M. F., Schaffert, D., Crowley, M. L., Oupický, D., & Howard, K. A. (2013) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.26941 · Cited by 35
Tryptophan-Containing Block Copolymers Prepared by RAFT Polymerization: Synthesis, Self-Assembly, and Chiroptical and Sensing Properties
Mori, H., Takahashi, E., Ishizuki, A., & Nakabayashi, K. (2013) · Macromolecules · doi:10.1021/ma400596r · Cited by 35
Boron-Containing Polymers
Doshi, A., & Jäkle, F. (2013) · Elsevier eBooks · doi:10.1016/b978-0-08-097774-4.00130-3 · Cited by 36
Visible‐Light‐Induced Controlled Polymerization of Hydrophilic Monomers with Ir(ppy)3 as a Photoredox Catalyst in Anisole
Ma, W., Chen, H., Ma, Y., Zhao, C., & Yang, W. (2014) · Macromolecular Chemistry and Physics · doi:10.1002/macp.201400024 · Cited by 34
Convenient synthesis of thermo‐responsive PtBA‐g‐PPEGMEMA well‐defined amphiphilic graft copolymer without polymeric functional group transformation
Song, X., Zhang, Y., Yang, D. S., Li, Y., Hu, J., Lu, G., & Huang, X. (2011) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24769 · Cited by 34
One-pot synthesis of hyperbranched polymers using small molecule and macro RAFT inimers
Wei, Z., Hao, X., Kambouris, P. A., Gan, Z., & Hughes, T. C. (2012) · Polymer · doi:10.1016/j.polymer.2012.02.011 · Cited by 34
Direct optical observations of vesicular self-assembly in large-scale polymeric structures during photocontrolled biphasic polymerization
Szymański, J. K., & Pérez‐Mercader, J. (2016) · Polymer Chemistry · doi:10.1039/c6py01497f · Cited by 34
Stability of Trithiocarbonate RAFT Agents Containing Both a Cyano and a Carboxylic Acid Functional Group
Fuchs, A. V., & Thurecht, K. J. (2017) · ACS Macro Letters · doi:10.1021/acsmacrolett.7b00100 · Cited by 34
Ultralow Dispersity Poly(vinyl alcohol) Reveals Significant Dispersity Effects on Ice Recrystallization Inhibition Activity
Vail, N. S., Stubbs, C., Biggs, C. I., & Gibson, M. I. (2017) · ACS Macro Letters · doi:10.1021/acsmacrolett.7b00595 · Cited by 34
Exploring the Upper Size Limit for Sterically Stabilized Diblock Copolymer Nanoparticles Prepared by Polymerization-Induced Self-Assembly in Non-Polar Media
Parker, B. R., Derry, M. J., Ning, Y., & Armes, S. P. (2020) · Langmuir · doi:10.1021/acs.langmuir.0c00211 · Cited by 34
Nucleobase‐Mediated Stereospecific Radical Polymerization and Combination with RAFT Polymerization for Simultaneous Control of Molecular Weight and Tacticity
Tao, Y., Satoh, K., & Kamigaito, M. (2010) · Macromolecular Rapid Communications · doi:10.1002/marc.201000614 · Cited by 34
Continuous Flow Aminolysis of RAFT Polymers Using Multistep Processing and Inline Analysis
Hornung, C., von Känel, K., Martinez‐Botella, I., Espiritu, M., Nguyen, X., Postma, A., Saubern, S., Chiefari, J., & Thang, S. H. (2014) · Macromolecules · doi:10.1021/ma501628f · Cited by 34
Self-citation
Branched polystyrene with abundant pendant vinyl functional groups from asymmetric divinyl monomer
Dong, Z., Liu, X., Lin, Y., & Li, Y. (2008) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.22913 · Cited by 34
A combination of RAFT and “Click” chemistry techniques to synthesize polymeric europium complexes with selective fluorescence emission
Li, D., Zhu, J., Cheng, Z., Zhang, W., & Zhu, X. (2009) · Reactive and Functional Polymers · doi:10.1016/j.reactfunctpolym.2009.01.008 · Cited by 33
Combining RAFT and Staudinger Ligation: A Potentially New Synthetic Tool for Bioconjugate Formation
Pötzsch, R., Fleischmann, S., Tock, C., Komber, H., & Voit, B. I. (2011) · Macromolecules · doi:10.1021/ma2000724 · Cited by 33
Synthesis of polyacrylonitrile by single‐electron transfer‐living radical polymerization using Fe(0) as catalyst and its adsorption properties after modification
Liu, D., Chen, H., Yin, P., Ji, N., Zong, G., & Qu, R. (2011) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24727 · Cited by 33
Ambient Temperature Transition-Metal-Free Dissociative Electron Transfer Reversible Addition–Fragmentation Chain Transfer Polymerization (DET-RAFT) of Methacrylates, Acrylates, and Styrene
Maximiano, P., Mendonça, P. V., Costa, J. R. C., Haworth, N. L., Serra, A. C., Guliashvili, T., Coote, M. L., & Coelho, J. F. J. (2016) · Macromolecules · doi:10.1021/acs.macromol.5b02647 · Cited by 33
Construction of PEG-based amphiphilic brush polymers bearing hydrophobic poly(lactic acid) side chains via successive RAFT polymerization and ROP
Qian, W., Song, X., Feng, C., Xu, P., Jiang, X., Li, Y., & Huang, X. (2016) · Polymer Chemistry · doi:10.1039/c6py00189k · Cited by 33
ROMP‐ and RAFT‐Based Guanidinium‐Containing Polymers as Scaffolds for Protein Mimic Synthesis
Sarapas, J. M., Backlund, C. M., deRonde, B. M., Minter, L. M., & Tew, G. N. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201700423 · Cited by 33
N-(2-Hydroxypropyl)methacrylamide-Based Linear, Diblock, and Starlike Polymer Drug Carriers: Advanced Process for Their Simple Production
Randárová, E., Kostka, L., Kotrchová, L., Šubr, V., Konefał, R., Nottelet, B., & Etrych, T. (2018) · Biomacromolecules · doi:10.1021/acs.biomac.8b00973 · Cited by 33
Characterization of New Amphiphilic Block Copolymers of N‐Vinylpyrrolidone and Vinyl Acetate, 2 ‐ Chromatographic Separation and Analysis by MALDI‐TOF and FT‐IR Coupling
Fandrich, N., Falkenhagen, J., Weidner, S. M., Staal, B. B. P., Thünemann, A. F., & Laschewsky, A. (2010) · Macromolecular Chemistry and Physics · doi:10.1002/macp.201000044 · Cited by 33
Synthesis of well-defined easily crosslinkable azobenzene side-chain liquid crystalline polymers via reversible addition–fragmentation chain transfer polymerization and photomechanical properties of their post-crosslinked fibers
Fang, L., Han, G., Zhang, J., Zhang, H., & Zhang, H. (2015) · European Polymer Journal · doi:10.1016/j.eurpolymj.2015.01.001 · Cited by 33
From-syndiotactic-to-isotactic stereogradient methacrylic polymers by RAFT copolymerization of methacrylic acid and its bulky esters
Ishitake, K., Satoh, K., Kamigaito, M., & Okamoto, Y. (2011) · Polymer Chemistry · doi:10.1039/c1py00401h · Cited by 33
Synthetic approaches towards structurally-defined electrochemically and (photo)redox-active polymer architectures
Schroot, R., Jäger, M., & Schubert, U. S. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00811a · Cited by 33
Functional multisite copolymer by one-pot sequential RAFT copolymerization of styrene and maleic anhydride
Moriceau, G., Gody, G., Hartlieb, M., Winn, J., Kim, H., Mastrangelo, A., Smith, T., & Perrier, S. (2017) · Polymer Chemistry · doi:10.1039/c7py00787f · Cited by 33
Responsive polymer nanoparticles for drug delivery applications
Saini, R. K., Bagri, L. P., Bajpai, A. K., & Mishra, A. (2018) · Elsevier eBooks · doi:10.1016/b978-0-08-101997-9.00015-1 · Cited by 33
Soluble Polymeric Dual Sensor for Temperature and pH Value
Pietsch, C., Hoogenboom, R., & Schubert, U. S. (2009) · Angewandte Chemie · doi:10.1002/ange.200901071 · Cited by 33
Thermoresponsive biotinylated star amphiphilic block copolymer: Synthesis, self-assembly, and specific target recognition
Bian, Q., Xiao, Y., & Lang, M. (2012) · Polymer · doi:10.1016/j.polymer.2012.02.031 · Cited by 32
Block copolymers based on 2‐vinyl‐4,4‐dimethyl‐5‐oxazolone by RAFT polymerization: Experimental and computational studies
Pascual, S., Blin, T., Saikia, P. J., Thomas, M., Gosselin, P., & Fontaine, L. (2010) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24303 · Cited by 32
Conventional free-radical and RAFT copolymerization of poly(ethylene oxide) containing macromonomers
Krivorotova, T., Vareikis, A., Gromadzki, D., Netopilı́k, M., & Makuška, R. (2009) · European Polymer Journal · doi:10.1016/j.eurpolymj.2009.12.001 · Cited by 32
Synthesis of Well-Defined Pyrrolidone-Based Homopolymers and Stimulus-Responsive Diblock Copolymers via RAFT Aqueous Solution Polymerization of 2-( N -Acryloyloxy)ethylpyrrolidone
Deane, O. J., Lovett, J. R., Musa, O. M., Fernyhough, A., & Armes, S. P. (2018) · Macromolecules · doi:10.1021/acs.macromol.8b01627 · Cited by 32
Impact of Reactive Amphiphilic Copolymers on Mechanical Properties and Cell Responses of Fibrin‐Based Hydrogels
Enezy‐Ulbrich, M. A. A., Malyaran, H., de Lange, R. D., Labude, N., Plum, R., Rütten, S., Terefenko, N., Wein, S., Neuß, S., & Pich, A. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202003528 · Cited by 32
Recent Advances in the Synthesis of Complex Macromolecular Architectures Based on Poly(N-vinyl pyrrolidone) and the RAFT Polymerization Technique
Ρόκα, Ν., Kokkorogianni, O., Kontoes-Georgoudakis, P., Choinopoulos, Ι., & Pitsikalis, M. (2022) · Polymers · doi:10.3390/polym14040701 · Cited by 35
Preparation of onion-like multilayered particles comprising mainly poly(iso-butyl methacrylate)-block-polystyrene by two-step AGET ATRP
Kitayama, Y., Yorizane, M., Kagawa, Y., Minami, H., Zetterlund, P. B., & Okubo, M. (2009) · Polymer · doi:10.1016/j.polymer.2009.04.055 · Cited by 32
Block Copolymerization of Vinyl Acetate and Vinyl neo-Decanoate Mediated by Dithionodisulfide
Gu, Y., He, J., Li, C., Zhou, C., Song, S., & Yang, Y. (2010) · Macromolecules · doi:10.1021/ma1000139 · Cited by 32
Synthesis and self-assembly behaviors of three-armed amphiphilic block copolymers via RAFT polymerization
Zhang, W., Zhang, W., Zhou, N., Cheng, Z., Zhu, J., & Zhu, X. (2008) · Polymer · doi:10.1016/j.polymer.2008.08.034 · Cited by 32
Comparison of Shell-Cross-Linked Micelles with Soft and Glassy Cores as a Drug Delivery Vehicle for Albendazole: Is There a Difference in Performance?
Kim, Y., Liemmawal, E. D., Pourgholami, M. H., Morris, D. L., & Stenzel, M. H. (2012) · Macromolecules · doi:10.1021/ma300644v · Cited by 32
RAFT‐Derived Polymer–Drug Conjugates: Poly(hydroxypropyl methacrylamide) (HPMA)–7‐Ethyl‐10‐hydroxycamptothecin (SN‐38) Conjugates
Williams, C. C., Thang, S. H., Hantke, T., Vogel, U., Seeberger, P. H., Tsanaktsidis, J., & Lepenies, B. (2011) · ChemMedChem · doi:10.1002/cmdc.201100456 · Cited by 31
Self-citation
Synthesis of PAA-g-PNIPAM well-defined graft polymer by sequential RAFT and SET-LRP and its application in preparing size-controlled super-paramagnetic Fe3O4 nanoparticles as a stabilizer
Jiang, X., Zhai, S., Jiang, X., Lu, G., & Huang, X. (2014) · Polymer · doi:10.1016/j.polymer.2014.05.050 · Cited by 31
Dual-temperature and pH responsive (ethylene glycol)-based nanogels via structural design
Kotsuchibashi, Y., & Narain, R. (2014) · Polymer Chemistry · doi:10.1039/c3py01772a · Cited by 31
Reversible polymer nanostructures by regulating SDS/PNIPAM binding
Jia, Z., Truong, N. P., & Monteiro, M. J. (2012) · Polymer Chemistry · doi:10.1039/c2py20628e · Cited by 31
Dual Responsive Nanoparticles from a RAFT Copolymer Library for the Controlled Delivery of Doxorubicin
Yildirim, T., Traeger, A., Preußger, E., Stumpf, S., Fritzsche, C., Hoeppener, S., Schubert, S., & Schubert, U. S. (2016) · Macromolecules · doi:10.1021/acs.macromol.5b02603 · Cited by 31
RAFT copolymerization of oppositely charged monomers and its use to tailor the composition of nonfouling polyampholytes with an UCST behaviour
Sponchioni, M., Palmiero, U. C., Manfredini, N., & Moscatelli, D. (2018) · Reaction Chemistry & Engineering · doi:10.1039/c8re00221e · Cited by 31
Thermal stability of RAFT-based poly(methyl methacrylate): A kinetic study of the dithiobenzoate and trithiocarbonate end-group effect
Bekanova, M. Z., Neumolotov, N. K., Jablanović, A. D., Plutalova, A. V., Chernikova, E. V., & Kudryavtsev, Y. V. (2019) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2019.03.017 · Cited by 31
Open-to-Air RAFT Polymerization on a Surface under Ambient Conditions
Kim, C. S., Cho, S., Lee, J. H., Cho, W. K., & Son, K. (2020) · Langmuir · doi:10.1021/acs.langmuir.0c01947 · Cited by 31
Screening RAFT agents and photocatalysts to mediate PET-RAFT polymerization using a high throughput approach
Ng, G., Jung, K., Li, J., Wu, C., Zhang, L., & Boyer, C. A. (2021) · Polymer Chemistry · doi:10.1039/d1py01258d · Cited by 31
ATRP with Alkyl Pseudohalides Acting as Initiators and Chain Transfer Agents: When ATRP and RAFT Polymerization Become One
Nicolaÿ, R., & Kwak, Y. (2012) · Israel Journal of Chemistry · doi:10.1002/ijch.201100124 · Cited by 31
Controlled synthesis of polyacrylonitrile via reversible addition-fragmentation chain-transfer pseudoliving radical polymerization and its thermal behavior
Chernikova, E. V., Потеряева, З. А., Belyaev, S. S., Nifant'ev, I. E., Shlyakhtin, A. V., Kostina, Y. V., Cherevan, A. S., Efimov, M. N., Bondarenko, G. N., & Sivtsov, E. V. (2011) · Polymer Science Series B · doi:10.1134/s1560090411070013 · Cited by 31
Self-Assembly of Lamellar Microphases in Linear Gradient Copolymer Melts
Tito, N. B., Milner, S. T., & Lipson, J. E. G. (2010) · Macromolecules · doi:10.1021/ma102296r · Cited by 31
Allyl sulfides and α‐substituted acrylates as addition–fragmentation chain transfer agents for methacrylate polymer networks
Ligon, S. C., Seidler, K., Gorsche, C., Grießer, M., Moszner, N., & Liska, R. (2015) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.27788 · Cited by 31
New Insight into Cluster Aggregation Mechanism during Polymerization-Induced Self-Assembly by Molecular Dynamics Simulation
Brunel, F., de la Haye, J. L., Lansalot, M., & D’Agosto, F. (2019) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.9b03622 · Cited by 31
Sequential flow process for the controlled polymerisation and thermolysis of RAFT-synthesised polymers
Hornung, C., Postma, A., Saubern, S., & Chiefari, J. (2014) · Polymer · doi:10.1016/j.polymer.2014.01.023 · Cited by 30
Blue‐Emitting Polymers Based on 4‐Hydroxythiazoles Incorporated in a Methacrylate Backbone
Menzel, R., Breul, A. M., Pietsch, C., Schäfer, J., Friebe, C., Täuscher, E., Weiss, D. G., Dietzek, B., Popp, J., Beckert, R., et al. (2011) · Macromolecular Chemistry and Physics · doi:10.1002/macp.201000752 · Cited by 30
Substituent Effects on RAFT Polymerization with Benzyl Aryl Trithiocarbonates
Bicciocchi, E., Chong, Y. K., Giorgini, L., Moad, G., Rizzardo, E., & Thang, S. H. (2010) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200900557 · Cited by 30
Self-citation
Controlled Cationic Copolymerization of Vinyl Monomers and Cyclic Acetals via Concurrent Vinyl-Addition and Ring-Opening Mechanisms
Shirouchi, T., Kanazawa, A., Kanaoka, S., & Aoshima, S. (2016) · Macromolecules · doi:10.1021/acs.macromol.6b01565 · Cited by 30
Diverse approaches to star polymers via cationic and radical RAFT cross-linking reactions using mechanistic transformation
Uchiyama, M., Satoh, K., McKenzie, T. G., Fu, Q., Qiao, G. G., & Kamigaito, M. (2017) · Polymer Chemistry · doi:10.1039/c7py01401e · Cited by 30
Determining the effect of side reactions on product distributions in RAFT polymerization by MALDI-TOF MS
Veloso, A., García, W., Agirre, A., Ballard, N., Ruipérez, F., de la Cal, J. C., & Asúa, J. M. (2015) · Polymer Chemistry · doi:10.1039/c5py00838g · Cited by 30
Reversible “Self-Locked” Micelles from a Zwitterion-Containing Triblock Copolymer
Flores, J. D., Xu, X., Treat, N. J., & McCormick, C. L. (2009) · Macromolecules · doi:10.1021/ma900517w · Cited by 30
Polymer‐based fluoride‐selective chemosensor: Synthesis, sensing property, and its use for the design of molecular‐scale logic devices
Wei, L., Chen, D., Jiang, H., Jiang, L., & Shen, Z. (2011) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.25068 · Cited by 30
Tunable synthesis of starch‐poly(vinyl acetate) bioconjugate
Xiao, C., Lu, D., Xu, S., & Huang, L. (2011) · Starch - Stärke · doi:10.1002/star.201000128 · Cited by 30
Thermal Properties of Oligo(2‐ethyl‐2‐oxazoline) Containing Comb and Graft Copolymers and their Aqueous Solutions
Weber, C., Krieg, A., Paulus, R. M., Lambermont‐Thijs, H. M. L., Becer, C. R., Hoogenboom, R., & Schubert, U. S. (2011) · Macromolecular Symposia · doi:10.1002/masy.201151004 · Cited by 30
Complementary light scattering and synchrotron small-angle X-ray scattering studies of the micelle-to-unimer transition of polysulfobetaines
Doncom, K. E. B., Pitto‐Barry, A., Willcock, H., Lu, A., McKenzie, B. E., Kirby, N. M., & O’Reilly, R. K. (2015) · Soft Matter · doi:10.1039/c5sm00602c · Cited by 32
End-crosslinking of controlled telechelic poly(N-isopropylacrylamide) toward a homogeneous gel network with photo-induced self-healing
Ida, S., Kimura, R., Tanimoto, S., & Hirokawa, Y. (2016) · Polymer Journal · doi:10.1038/pj.2016.112 · Cited by 30
Fabrication of completely water soluble graphene oxides graft poly citric acid using different oxidation methods and comparison of them
Sarlak, N., & Meyer, T. J. (2017) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2017.08.086 · Cited by 30
Cellulose-g-PDMAam copolymers by controlled radical polymerization in homogeneous medium and their aqueous solution properties
Hiltunen, M., Siirilä, J., Aseyev, V. O., & Maunu, S. L. (2011) · European Polymer Journal · doi:10.1016/j.eurpolymj.2011.10.010 · Cited by 29
Hierarchical Self-Assembly in Supramolecular Double-Comb Diblock Copolymer Complexes
Faber, M., Hofman, A. H., Polushkin, E., van Ekenstein, G. A., Seitsonen, J. J. T., Ruokolainen, J., Loos, K., & ten Brinke, G. (2013) · Macromolecules · doi:10.1021/ma302295v · Cited by 29
Carprofen-imprinted monolith prepared by reversible addition–fragmentation chain transfer polymerization in room temperature ionic liquids
Ban, L., Han, X., Wang, X.-H., Huang, Y., & Liu, Z. (2013) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-013-7276-4 · Cited by 29
Cobalt‐mediated radical polymerization routes to poly(vinyl ester) block copolymers
Bunck, D. N., Sorenson, G. P., & Mahanthappa, M. K. (2010) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24445 · Cited by 29
Polymernetzwerke: Von Kunststoffen und Gelen zu porösen Gerüsten
Gu, Y., Zhao, J. X., & Johnson, J. A. (2019) · Angewandte Chemie · doi:10.1002/ange.201902900 · Cited by 30
Time-resolved small-angle neutron scattering studies of the thermally-induced exchange of copolymer chains between spherical diblock copolymer nanoparticles prepared via polymerization-induced self-assembly
Cornel, E. J., Smith, G. N., Rogers, S. E., Hallett, J. E., Growney, D. J., Smith, T., O’Hora, P. S., van Meurs, S., Mykhaylyk, O. O., & Armes, S. P. (2020) · Soft Matter · doi:10.1039/c9sm02425e · Cited by 29
Barbier Self-Condensing Ketyl Polymerization-Induced Emission: A Polarity Reversal Approach to Reversed Polymerizability
Li, S., Zhu, N., Jing, Y., Li, Y., Bao, H., & Wan, W. (2020) · iScience · doi:10.1016/j.isci.2020.101031 · Cited by 29
The first amphiphilic graft copolymer bearing a hydrophilic poly(2-hydroxylethyl acrylate) backbone synthesized by successive RAFT and ATRP
Jiang, X., Jiang, X., Lu, G., Feng, C., & Huang, X. (2014) · Polymer Chemistry · doi:10.1039/c4py00415a · Cited by 29
Phase behavior of gradient copolymer solutions: a Monte Carlo simulation study
Pandav, G., Pryamitsyn, V. A., Gallow, K. C., Loo, Y., Genzer, J., & Ganesan, V. (2012) · Soft Matter · doi:10.1039/c2sm25577d · Cited by 29
Electrochemically Induced RAFT Polymerization of Thermoresponsive Hydrogel Films: Impact on Film Thickness and Surface Morphology
Bünsow, J., Mänz, M., Vana, P., & Johannsmann, D. (2009) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200900596 · Cited by 29
Radical‐induced oxidation of RAFT agents—A kinetic study
Li, C., He, J., Zhou, Y., Gu, Y., & Yang, Y. (2011) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24554 · Cited by 29
Polymer Fundamentals: Polymer Synthesis
Hasırcı, V., Yilgor, P., Endogan, T., Eke, G., & Hasırcı, N. (2011) · Comprehensive Biomaterials · doi:10.1016/b978-0-08-055294-1.00034-9 · Cited by 29
RAFT Polymerization of Vinylthiophene Derivatives and Synthesis of Block Copolymers Having Cross-Linkable Segments
Mori, H., Takano, K., & Endo, T. (2009) · Macromolecules · doi:10.1021/ma900833d · Cited by 29
Nanoscale Self-Assemblies from Amphiphilic Block Copolymers as Proficient Templates in Drug Delivery
Patel, D. D., Kuperkar, K. C., Yusa, S., & Bahadur, P. (2023) · Drugs and Drug Candidates · doi:10.3390/ddc2040045 · Cited by 29
Disulfide-Functionalized Unimolecular Micelles as Selective Redox-Responsive Nanocarriers
Porsch, C., Zhang, Y., Montañez, M. I., Malho, J., Kostiainen, M. A., Nyström, A. M., & Malmström, E. (2015) · Biomacromolecules · doi:10.1021/acs.biomac.5b00809 · Cited by 28
Reversible addition–fragmentation chain transfer synthesis and micellar characteristics of biocompatible amphiphilic poly(vinyl acetate)-graft-poly(N-vinyl-2-pyrrolidone) copolymers
Atanase, L. I., Winninger, J., Delaite, C., & Riess, G. (2014) · European Polymer Journal · doi:10.1016/j.eurpolymj.2014.01.029 · Cited by 28
Conventional and RAFT Copolymerization of Tetrafluoroethylene with Isobutyl Vinyl Ether
Puts, G. J., Venner, W. V., Ameduri, B. M., & Crouse, P. L. (2018) · Macromolecules · doi:10.1021/acs.macromol.8b01286 · Cited by 28
Wavelength‐Selective Folding of Single Polymer Chains with Different Colors of Visible Light
Frisch, H., Kodura, D., Bloesser, F. R., Michalek, L. F., & Barner‐Kowollik, C. (2019) · Macromolecular Rapid Communications · doi:10.1002/marc.201900414 · Cited by 28
Graft modification of lignin-based cellulose via enzyme-initiated reversible addition-fragmentation chain transfer (RAFT) polymerization and free-radical coupling
Bao, X., Fan, X., Yu, Y., Wang, Q., Wang, P., & Yuan, J. (2019) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2019.12.078 · Cited by 28
Exploitation of Monofunctional Carbonyl Resources by Barbier Polymerization for Materials with Polymerization-Induced Emission
Li, S., Jing, Y., Bao, H., & Wan, W. (2020) · Cell Reports Physical Science · doi:10.1016/j.xcrp.2020.100116 · Cited by 28
Synthesis of Highly Transparent Diblock Copolymer Vesicles via RAFT Dispersion Polymerization of 2,2,2-Trifluoroethyl Methacrylate in n -Alkanes
György, C., Derry, M. J., Cornel, E. J., & Armes, S. P. (2021) · Macromolecules · doi:10.1021/acs.macromol.0c02646 · Cited by 28
Polymer Chemistry for Haptics, Soft Robotics, and Human–Machine Interfaces
Schara, S., Blau, R., Church, D. C., Pokorski, J. K., & Lipomi, D. J. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202008375 · Cited by 28
Glycopolymer Conjugates
Eissa, A. M., & Cameron, N. R. (2012) · Advances in polymer science · doi:10.1007/12_2012_177 · Cited by 28
Ab initio RAFT emulsion polymerization of butadiene using the amphiphilic poly(acrylic acid‐b‐styrene) trithiocarbonate as both surfactant and mediator
Wei, R., Luo, Y., & Xu, P. (2011) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24736 · Cited by 30
Block Copolymer Synthesis through the Use of Switchable RAFT Agents
Moad, G., Benaglia, M., Chen, M., Chiefari, J., Chong, Y. K., Keddie, D. J., Rizzardo, E., & Thang, S. H. (2011) · ACS symposium series · doi:10.1021/bk-2011-1066.ch007 · Cited by 28
Self-citation
SAXS studies of the thermally-induced fusion of diblock copolymer spheres: formation of hybrid nanoparticles of intermediate size and shape
Cornel, E. J., O’Hora, P. S., Smith, T., Growney, D. J., Mykhaylyk, O. O., & Armes, S. P. (2020) · Chemical Science · doi:10.1039/d0sc00569j · Cited by 28
One‐pot deprotection and functionalization of polythiol copolymers via six different thiol–X reactions
Neindre, M. L., & Nicolaÿ, R. (2013) · Polymer International · doi:10.1002/pi.4665 · Cited by 27

Authors: Moad, G., Rizzardo, E., & Thang, S. H.
Affiliations: Commonwealth Scientific and Industrial Research Organisation (AU)
Corresponding author: Moad, Graeme
Rizzardo, Ezio
Thang, San H.
ORCID: Moad, Graeme
Thang, San H.
Venue: Polymer
Publisher: Elsevier BV
Published: 2008-03
Volume: 49
Issue: 5
Pages: 1079-1131
ISSN: 0032-3861 (ISSN-L)
DOI: 10.1016/j.polymer.2007.11.020
OpenAlex: W2040062577
Cited by: 1,397
References: 528
Citations by year: 2026: 13 · 2025: 29 · 2024: 41 · 2023: 29 · 2022: 41 · 2021: 71 · 2020: 64 · 2019: 92 · 2018: 76 · 2017: 79 · 2016: 85 · 2015: 93 · 2014: 90 · 2013: 100 · 2012: 117
FWCI: 46.82
Type: journal article
Language: en
Open access: hybrid
doi.org
Licence: cc-by-nc-nd
www.elsevier.com/tdm/userlicense/1.0/ (tdm)
creativecommons.org/licenses/by-nc-nd/4.0/ (vor, 1963 d)
Locations: Polymer (publishedVersion, cc-by-nc-nd)
Funders: Commonwealth Scientific and Industrial Research Organisation
Topics: Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
Physical Sciences › Chemistry › Organic Chemistry › Photopolymerization techniques and applications
Keywords: RAFT polymerization, RAFT agents, dithioesters, trithiocarbonates, dithiocarbamates, xanthates, controlled radical polymerization, block copolymers, star polymers, cyclopolymers, gradient copolymers, molecular weight control

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Radical addition–fragmentation chemistry in polymer synthesis

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Claims other papers make about this one

Self-check

Citations

Cites

Cited by

Related

Metadata

Record

About these checks