Free-Radical ring-opening polymerization of cyclic allylic sulfides
Abstract
A new type of ring-opening monomer has been investigated and found to undergo facile and efficient free-radical polymerization. The monomers are cyclic allylic sulfides with 6-methylene-1,4-dithiepane ( 3 ) and 3-methylene-1,5-dithiacyclooctane ( 4 ) synthesized and investigated as two examples. 6-Methylene-1,4-dithiepane ( 3 ) is a clear oil and 3-methylene-1,5-dithiacyclooctane ( 4 ) has a low, near ambient temperature melting point, and in contrast to many ring-opening monomers, they readily survive exposure to moisture and aqueous acids and bases. These compounds were polymerized in bulk with complete ring opening to give highly insoluble crystalline homopolymers of high molecular weight ( M w ca. 500 000−700 000) with glass transition temperatures of ca. −30 to −50 °C and melting points of ca. 100−130 °C. The homopolymers and their 1:1 copolymer were characterized by FT-IR and high-temperature 1 H and 13 C NMR spectroscopies, high-temperature GPC, and DSC. They displayed volume shrinkages in the range expected of ring-opening monomers (4.5−8.5%) of their molecular weights in spite of the crystallinity present in the final polymers.
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Heterocyclic monomers with nitrogen or sulfur heteroatoms have been shown to undergo radical ROP.
“Heterocyclic monomers with nitrogen or sulfur heteroatoms have also been shown to undergo radical ROP (see Figure 7).”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [18]
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Dynamic Bond Exchange in Allyl Sulfides: Applications in Film Stress Relaxation and Re/upcycling
Katsumata, R. (2025) · Kobunshi · doi:10.1295/kobunshi.74.5_229
- Authors
- Evans, R. A., & Rizzardo, E.
- Affiliations
- Commonwealth Scientific and Industrial Research Organisation (AU)
- ORCID
- Evans, Richard A.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 1996-01-01
- Volume
- 29
- Issue
- 22
- Pages
- 6983-6989
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2062765845
- Cited by
- 110
- References
- 15
- Citations by year
- 2026: 8 · 2025: 9 · 2024: 7 · 2023: 11 · 2022: 6 · 2021: 2 · 2020: 3 · 2019: 4 · 2018: 4 · 2017: 1 · 2016: 4 · 2015: 5 · 2014: 3 · 2013: 4 · 2012: 3
- FWCI
- 0.60
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecules (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Keywords
- copolymers, volume shrinkage, glass transition temperature, polymer crystallinity
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