Imidazole- and imidazolium-containing polymers for biology and material science applications
Open accessAbstract
The imidazole ring is ubiquitous in nature and imidazole functionality plays a critical role in many structures within the human body, notably as histamine and histadine. Imidazoles offer many biophysical interactions including their ability to hydrogen bond with drugs and proteins. In contrast, imidazolium salts have lost their strong hydrogen-bonding ability through alkylation of both nitrogens, but they are able to aggregate electrostatically. Imidazolium salts are used to extract metal ions from aqueous solutions, dissolve carbohydrates, create polyelectrolyte brushes on surfaces, coat metal nanoparticles, provide antimicrobial action, and create oriented liquid crystals. Bioactive applications include imidazolium hydrogels, antiarrhythmics, and anti-metastic agents. This review will describe the synthesis and design of imidazole derivatives and imidazolium-containing polymers as bioactive materials. Imidazole-based polymers readily associate with biological molecules through hydrogen-bonding, and imidazolium analogs offer electrostatic interactions, aggregation, and self-assembly. Design of novel imidazole- and imidazolium-based macromolecules remains as an exciting and emerging field.
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Derived compounds of traditional antifungal structures include some with better antimicrobial action than the original structures.
“The second group involves derived compounds of traditional antifungal structures [54, 55] where some of them present better antimicrobial action than the original structures [55, 140].”
From <i>Candida</i>Infections, Causes, Targets, and Resistance Mechanisms: Traditional and Alternative Antifungal Agents (2013) · cites this paper as [54]
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Cationic polymers and their self-assembly for antibacterial applications
Deka, S., Sharma, A., & Kumar, P. (2015) · Current Topics in Medicinal Chemistry · doi:10.2174/1568026615666150330110602 · Cited by 82 · see citing works
- Authors
- Anderson, E. B., & Long, T. E.
- Affiliations
- Virginia Tech (US)
- Corresponding author
- Long, Timothy E.
- ORCID
- Long, Timothy E.
- Venue
- Polymer
- Publisher
- Elsevier BV
- Published
- 2010-05
- Volume
- 51
- Issue
- 12
- Pages
- 2447-2454
- ISSN
- 0032-3861 (ISSN-L)
- OpenAlex
- W2152187896
- Cited by
- 407
- References
- 89
- Citations by year
- 2026: 17 · 2025: 24 · 2024: 26 · 2023: 32 · 2022: 30 · 2021: 25 · 2020: 25 · 2019: 26 · 2018: 31 · 2017: 19 · 2016: 33 · 2015: 24 · 2014: 29 · 2013: 21 · 2012: 24
- FWCI
- 10.46
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Polymer (publishedVersion, cc-by-nc-nd)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
- Physical Sciences › Chemistry › Organic Chemistry › Antimicrobial agents and applications
- Keywords
- imidazole-containing polymers, imidazolium salts, imidazole derivatives, hydrogen bonding, electrostatic interactions, self-assembly, metal ion extraction, polyelectrolyte brushes, antimicrobial polymers, antiarrhythmic drugs, anti-metastatic agents, bioactive materials, polymer synthesis
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