Lipase/esterase-catalyzed synthesis of aliphatic polyesters via polycondensation: A review
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The high costs and long reaction times of enzyme catalysts largely limit their utility in large-scale manufacture.
“However, the high costs and long reaction times of enzyme catalysts largely limit their utility in large-scale manufacture.257,260”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [257]
Step-growth polymerization mediated by mild and selective enzyme catalysis provides a metal-free and eco-friendly route to polyesters and polycarbonates.
“SGP mediated by mild and selective enzyme catalysis also provides a metal-free and eco-friendly route to polyesters and polycarbonates.[255][256][257][258][259]”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [257]
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Biocatalysis for Biobased Chemicals
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“Lipases have been used to catalyze reactions in polycondensations of dicarboxylic acids with diols [143], ring-opening polymerization (ROP) of lactones [144], cyclic carbonates [145] and polycondensations of hydroxycarboxylic acids [146].”
MethodRing-opening polymerization of a five-membered lactone trans-fused to a cyclohexane ring
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“Reviews including extensive background on lipasecatalyzed synthesis of polyol-polyesters have been published by us and others [21,29–33].”
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“It has been stated that for this type of polycondensation reaction lipases show higher reactivity in case of longer chain monomers, due to a stronger activating effect of the more hydrophobic substrates [143].”
BackgroundBio-based Unsaturated Polyesters
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“In the past two decades, enzymatic polymerization, especially lipase/esterase-catalyzed synthesis of polyesters, has been greatly developed and considered as an important route for polymer synthesis [1–7].”
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Enantio‐, Regio‐, and Chemoselective Lipase‐Catalyzed Polymer Synthesis
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Self-citationLipases in Catalytic Reactions of Organic Chemistry
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“In-situ” lipase-catalyzed cotton coating with polyesters from ethylene glycol and glycerol
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“These properties allow them to be employed in a variety of biochemical reactions, including acidolysis, aminolysis, alcoholysis when in an aqueous solution, esterification, transesterification and acylation when in non-aqueous media [13,14].”
BackgroundLipase-Catalyzed Synthesis of Biobased Polyesters Containing Levoglucosan Units
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“Lipases have a variety of industrial applications as biocatalysts in the food, pharmaceutical, and cosmetic industries (Jaeger and Eggert 2002; Schmid et al. 2001; Yu et al. 2012).”
BackgroundLipase-Catalyzed Fully Aliphatic Copolyesters Based on Renewable Isohexide Isomers
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“The green synthesis of polyesters using lipases as biocatalysts was the subject of extensive research, demonstrated by the continuously increasing number of publications in this field, as reviewed by Kobayashi [4,11,12] and other authors [13,14].”
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Self-citation
- Authors
- Yu, Y., Wu, D., Liu, C., Zhao, Z., Yang, Y., & Li, Q.
- Affiliations
- Jilin University (CN)
- Corresponding author
- Yang, Yan
- Li, Quanshun
- Venue
- Process Biochemistry
- Publisher
- Elsevier BV
- Published
- 2012-07
- Volume
- 47
- Issue
- 7
- Pages
- 1027-1036
- ISSN
- 0032-9592 (ISSN-L)
- 1359-5113
- OpenAlex
- W2019259143
- Cited by
- 97
- References
- 108
- Citations by year
- 2026: 4 · 2025: 7 · 2024: 2 · 2022: 8 · 2021: 7 · 2020: 6 · 2019: 12 · 2018: 5 · 2017: 6 · 2016: 8 · 2015: 7 · 2014: 12 · 2013: 12 · 2012: 1
- FWCI
- 4.15
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Process Biochemistry (publishedVersion)
- Funders
- Natural Science Foundation of China (21074042, 81102383)
- International Science & Technology Cooperation Program of China (2011DFR51090)
- China Postdoctoral Science Foundation (20110491328)
- Jilin Province Science & Technology Department in China (201101040)
- National University Student Innovation Program (2011A34069)
- Fundamental Research Funds of the Central Universities in China
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Biology › Enzyme Catalysis and Immobilization
- Physical Sciences › Chemistry › Organic Chemistry › Chemical Synthesis and Reactions
- Keywords
- aliphatic polyesters, enzymatic synthesis, esterification, transesterification, diols, diacids, vinyl esters, self-polycondensation, enzymatic ring-opening polymerization, functional polymers
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