The DOI matches its Crossref record; 92 of the 96 references it cites were found in a registry or an index.
Recycling of rubber wastes by devulcanization
Abstract
Abstract Disposal of used tires and rubber wastes is one of the biggest challenges of the 21st century waste management. One of the environmentally friendly possibilities of recycling this type of material is to go through the breaking of their three-dimensional structure. This treatment, called the devulcanization, can be defined as a process that causes the selective breakup of the sulfur-sulfur (S-S) and carbon-sulfur (C-S) chemical bonds without breaking the backbone network and without degrading the material. The devulcanized rubber can be mixed with virgin rubber or with other kinds of matrices to give new compounds without generating a significant decrease in mechanical and physical properties. Many devulcanization process types are presented in the literature: chemical, ultrasound, microwave, thermomechanical, etc. The thermomechanical devulcanization based on extrusion seems to be the more suitable to be applied on an industrial scale. The supercritical CO2 has been proposed as a green atmosphere that can be used to improve this type of devulcanization. In fact, it seems that in supercritical conditions, the CO2 swells the rubber and stretches the sulfide links, making them easier to break. This paper presents a literature review on rubbers recycling by devulcanization. It is focused on the different devulcanization techniques used in the last decades. Particular attention is paid to the thermomechanical method, those in the presence of supercritical CO2 and, finally, the combined thermomechanical process with supercritical CO2 atmosphere.
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“Existing strategies to create reprocessable thermosets have focused on dynamic covalent bond exchange, 3-8 thermomechanical degradation, 9 or wholesale replacement of network components with degradable versions. 10-13”
From Cleavable comonomers enable degradable, recyclable thermoset plastics (2020) · cites this paper as [9]
Citations
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Cited by
Cleavable comonomers enable degradable, recyclable thermoset plastics
Shieh, P., Zhang, W., Husted, K. E. L., Kristufek, S. L., Xiong, B., Lundberg, D. J., Lem, J., Veysset, D., Sun, Y., Nelson, K. A., et al. (2020) · Nature · doi:10.1038/s41586-020-2495-2 · Cited by 498
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Metadata
- Authors
- Asaro, L., Gratton, M., Seghar, S., & Aït Hocine, N.
- Affiliations
- Université d'Orléans (FR)
- PHENIX laboratory (FR)
- ORCID
- Gratton, Michel
- Venue
- Resources, Conservation and Recycling
- Publisher
- Elsevier BV
- Published
- 2018-06
- Volume
- 133
- Pages
- 250-262
- ISSN
- 0921-3449 (ISSN-L)
- OpenAlex
- W2789999880
- Cited by
- 328
- References
- 96
- Citations by year
- 2026: 33 · 2025: 49 · 2024: 50 · 2023: 41 · 2022: 47 · 2021: 41 · 2020: 36 · 2019: 24 · 2018: 7
- FWCI
- 13.47
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- www.elsevier.com/tdm/userlicense/1.0/ (tdm)
- www.elsevier.com/legal/tdmrep-license (tdm)
- Locations
- Resources Conservation and Recycling (publishedVersion)
- HAL (submittedVersion)
- Funders
- “la Région Centre Val de Loire, France”
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Environmental Science › Waste Management and Disposal › Recycling and Waste Management Techniques
- Physical Sciences › Engineering › Building and Construction › Recycling and utilization of industrial and municipal waste in materials production
- Keywords
- rubber recycling, devulcanization, used tires, supercritical carbon dioxide, extrusion
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- Asaro, L., Gratton, M., Seghar, S., & Aït Hocine, N. (2018). Recycling of rubber wastes by devulcanization. Resources, Conservation and Recycling. https://doi.org/10.1016/j.resconrec.2018.02.016
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.