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Redox activity of argyrodite Li6PS5Cl electrolyte in all-solid-state Li-ion battery: An XPS study
Open accessAbstract
Argyrodite Li 6 PS 5 Cl is a good candidate as solid electrolyte for bulk all-solid-state Li-ion batteries due to its high ionic conductivity and its good processability , although it shows some interface reactivity towards electrode active materials. In this work we have cycled LiCoO 2 /Li 6 PS 5 Cl/Li 4 Ti 5 O 12 full cells and analyzed the interfacial mechanisms by surface-sensitive characterization techniques: Auger Electron Spectroscopy (AES) and X-ray Photoelectron Spectroscopy (XPS). We show that Li 6 PS 5 Cl has an electrochemical redox activity in the positive electrode . It is partially oxidized into LiCl, P 2 S 5 and polysulfides Li 2 S n upon charge, with some reversibility upon discharge. Li 6 PS 5 Cl also reacts with LiCoO 2 upon cycling, leading to the formation of phosphates at the interface.
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New, Highly Ion‐Conductive Crystals Precipitated from Li2S–P2S5 Glasses
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Electron Transfer Mechanisms upon Lithium Deintercalation from LiCoO2 to CoO2 Investigated by XPS
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Cited by
Koerver, R., Aygün, I., Leichtweiß, T., Dietrich, C., Zhang, W., Binder, J. O., Hartmann, P., Zeier, W. G., & Janek, J. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b00931 · Cited by 1,020
Metadata
- Authors
- Auvergniot, J., Cassel, A., Foix, D., Viallet, V., Seznec, V., & Dedryvère, R.
- Venue
- Solid State Ionics
- Publisher
- Elsevier BV
- Published
- 2017-02
- Volume
- 300
- Pages
- 78-85
- ISSN
- 0167-2738 (ISSN-L)
- OpenAlex
- W2565080434
- Cited by
- 367
- References
- 14
- FWCI
- 8.54
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Auvergniot, J., Cassel, A., Foix, D., Viallet, V., Seznec, V., & Dedryvère, R. (2017). Redox activity of argyrodite Li6PS5Cl electrolyte in all-solid-state Li-ion battery: An XPS study. Solid State Ionics. https://doi.org/10.1016/j.ssi.2016.11.029
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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