The DOI matches its Crossref record; 28 of the 28 references it cites were found in a registry or an index.
Direct Observation of the Interfacial Instability of the Fast Ionic Conductor Li10GeP2S12 at the Lithium Metal Anode
Abstract
The very high ionic conductivity of Li 10 GeP 2 S 12 (LGPS) makes it a potential solid electrolyte for lithium all-solid-state batteries. Besides the high ionic conductivity, another key requirement is the stability of the solid electrolyte against degradation reactions with the electrodes; here, we analyze the reaction of LGPS with lithium metal. In situ X-ray photoelectron spectroscopy (XPS), in combination with time-resolved electrochemical measurements offers detailed information on the chemical reactions at the Li/LGPS interface. The decomposition of Li 10 GeP 2 S 12 leads to the formation of an interphase composed of Li 3 P, Li 2 S, and Li–Ge alloy, which is in perfect agreement with theoretical predictions, and an increase of the interfacial resistance. These results highlight the necessity to perform long-term, time-resolved electrochemical measurements when evaluating potential new solid electrolytes for solid-state batteries. The kinetics of this interphase growth—comparable to SEI formation on lithium anodes in liquid electrolytes—seems to be governed by diffusion across the interphase, as a square root time dependence is observed.
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Electrochemical Methods: Fundamentals and Applications
de Rooij, D. M. R. (2003) · Anti-Corrosion Methods and Materials · doi:10.1108/acmm.2003.12850eae.001 · Cited by 13,009
Kirkpatrick, S. (1973) · Reviews of Modern Physics · doi:10.1103/revmodphys.45.574 · Cited by 5,260
A lithium superionic conductor
Kamaya, N., Homma, K., Yamakawa, Y., Hirayama, M., Kanno, R., Yonemura, M., Kamiyama, T., Kato, Y., Hama, S., Kawamoto, K., et al. (2011) · Nature Materials · doi:10.1038/nmat3066 · Cited by 4,978
Zhu, Y., He, X., & Mo, Y. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b07517 · Cited by 1,936
Interface Stability in Solid-State Batteries
Richards, W. D., Miara, L. J., Wang, Y., Kim, J. C., & Ceder, G. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b04082 · Cited by 1,652
Electrochemical Stability of Li10GeP2S12 and Li7La3Zr2O12 Solid Electrolytes
Han, F., Zhu, Y., He, X., Mo, Y., & Wang, C. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201501590 · Cited by 1,095
Zhu, Y., He, X., & Mo, Y. (2016) · Journal of Materials Chemistry A · doi:10.1039/c5ta08574h · Cited by 1,045
Pinson, M. B., & Bazant, M. Z. (2013) · Journal of The Electrochemical Society · doi:10.1149/2.044302jes · Cited by 946
Ong, S. P., Mo, Y., Richards, W. D., Miara, L., Lee, H. S., & Ceder, G. (2013) · Energy Environ. Sci. · doi:10.1039/c2ee23355j · Cited by 710
Li10SnP2S12: An Affordable Lithium Superionic Conductor
Bron, P., Johansson, S., Zick, K., Schmedt auf der Günne, J., Dehnen, S., & Roling, B. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407393y · Cited by 655
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A solid future for battery development
Janek, J., & Zeier, W. G. (2016) · Nature Energy · doi:10.1038/nenergy.2016.141 · Cited by 3,979
Self-citationDesigning solid-state electrolytes for safe, energy-dense batteries
Zhao, Q., Stalin, S., Zhao, C.-Z., & Archer, L. A. (2020) · Nature Reviews Materials · doi:10.1038/s41578-019-0165-5 · Cited by 2,372
Placke, T., Kloepsch, R., Dühnen, S., & Winter, M. (2017) · Journal of Solid State Electrochemistry · doi:10.1007/s10008-017-3610-7 · Cited by 1,117
A facile surface chemistry route to a stabilized lithium metal anode
Liang, X., Pang, Q., Kochetkov, I. R., Sempere, M. S., Huang, H., Sun, X., & Nazar, L. F. (2017) · Nature Energy · doi:10.1038/nenergy.2017.119 · Cited by 1,083
Koerver, R., Aygün, I., Leichtweiß, T., Dietrich, C., Zhang, W., Binder, J. O., Hartmann, P., Zeier, W. G., & Janek, J. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b00931 · Cited by 1,020
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Metadata
- Authors
- Wenzel, S., Randau, S., Leichtweiß, T., Weber, D. A., Sann, J., Zeier, W. G., & Janek, J.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-03-17
- Volume
- 28
- Issue
- 7
- Pages
- 2400-2407
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2294978050
- Cited by
- 854
- References
- 28
- FWCI
- 33.23
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wenzel, S., Randau, S., Leichtweiß, T., Weber, D. A., Sann, J., Zeier, W. G., & Janek, J. (2016). Direct Observation of the Interfacial Instability of the Fast Ionic Conductor Li10GeP2S12 at the Lithium Metal Anode. Chemistry of Materials. https://doi.org/10.1021/acs.chemmater.6b00610
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