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Electron Transfer Mechanisms upon Lithium Deintercalation from LiCoO2 to CoO2 Investigated by XPS
Open accessAbstract
Lithium deintercalation of Li x CoO 2 from x = 1 to x ≈ 0 has been carried out electrochemically. The changes in the electronic structure from LiCoO 2 to CoO 2 have been investigated by X-ray photoelectron spectroscopy (XPS) to bring some new developments about the electron transfer mechanisms upon lithium deintercalation. All available XPS core peaks (Co 2p, Co 3p, Co 3s, O 1s, F 1s, P 2p, C 1s) and valence spectra have been analyzed. The contributions of the electrode material and of the electrode/electrolyte interface have been clearly distinguished. We show that cobalt and oxygen simultaneously undergo a partial oxidation process and that the sole participation of oxygen atoms to the charge transfer process, as it is sometimes assumed, can be excluded. The surface film consists of organic and inorganic species resulting from degradation of the electrolyte.
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Cites
Ageing mechanisms in lithium-ion batteries
Vetter, J., Novák, P., Wagner, M. R., Veit, C., Möller, K.-C., Besenhard, J. O., Winter, M., Wohlfahrt-Mehrens, M., Vogler, C., & Hammouche, A. (2005) · Journal of Power Sources · doi:10.1016/j.jpowsour.2005.01.006 · Cited by 3,987
Hüfner, S. (1995) · Springer Series in Solid-State Sciences · doi:10.1007/978-3-662-03150-6 · Cited by 854
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Redox activity of argyrodite Li6PS5Cl electrolyte in all-solid-state Li-ion battery: An XPS study
Auvergniot, J., Cassel, A., Foix, D., Viallet, V., Seznec, V., & Dedryvère, R. (2017) · Solid State Ionics · doi:10.1016/j.ssi.2016.11.029 · Cited by 367
Self-citationYu, M., Waag, F., Chan, C. K., Weidenthaler, C., Barcikowski, S., & Tüysüz, H. (2020) · ChemSusChem · doi:10.1002/cssc.201903186 · Cited by 93
Wang, X., Peng, X., Ran, H., Lin, B., Ni, J., Lin, J., & Jiang, L. (2018) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.8b04915 · Cited by 64
Metadata
- Authors
- Dahéron, L., Dedryvère, R., Martinez, H., Ménétrier, M., Denage, C., Delmas, C., & Gonbeau, D.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-12-15
- Volume
- 20
- Issue
- 2
- Pages
- 583-590
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2071247948
- Cited by
- 533
- References
- 2
- FWCI
- 6.93
- Type
- journal article
- Language
- en
- Open access
- green
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- Dahéron, L., Dedryvère, R., Martinez, H., Ménétrier, M., Denage, C., Delmas, C., & Gonbeau, D. (2008). Electron Transfer Mechanisms upon Lithium Deintercalation from LiCoO2 to CoO2 Investigated by XPS. Chemistry of Materials. https://doi.org/10.1021/cm702546s
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