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Powerful CarbonCarbon Bond Forming Reactions Based on a Novel Radical Exchange Process

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Fun with radicals: Some new perspectives for organic synthesis

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The Degenerative Radical Transfer of Xanthates and Related Derivatives: An Unusually Powerful Tool for the Creation of Carbon–Carbon Bonds

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A convenient source of alkyl and acyl radicals

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Invention of new reactions useful in the chemistry of natural products

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Hypophosphorous acid and its salts: New reagents for radical chain deoxygenation, dehalogenation and deamination

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On the mechanism of the deoxygenation of secondary alcohols by the reduction of their methyl xanthates by tin hydrides

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Total synthesis of (.+-.)-atractyligenin

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The Genesis of the Reversible Radical Addition–Fragmentation–Transfer of Thiocarbonylthio Derivatives from the Barton–McCombie Deoxygenation: A Brief Account and Some Mechanistic Observations*

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Total Synthesis of (−)-Pseudolaric Acid B

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Total Synthesis of Crotophorbolone

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Total Synthesis of (+)‐Pleuromutilin

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A Dialdehyde Cyclization Cascade: An Approach to Pleuromutilin

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Absolute Rate Constants for Iminyl Radical Reactions

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On the Reduction of S-Alkyl-thionocarbonates (Xanthates) with Phosphorus Compounds

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New decarboxylative chalcogenation of aliphatic and alicyclic carboxylic acids.

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The ring-opening reactions of cyclobutylmethyl and cyclobutenylmethyl radicals

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A Direct Approach to α-Trifluoromethylamines

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The Total Synthesis of (±)‐Fortucine and a Revision of the Structure of Kirkine

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A new source of nitrogen centered radicals

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The Reaction of Acyl Halides with Organotin Hydrides. The Mechanism of Aldehyde Formation1,2

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On the Strategic Impact of the Degenerative Transfer of Xanthates on Synthetic Planning

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New routes to organofluorine compounds based on ketenes and the radical transfer of xanthates

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Radical-mediated reduction of the dithiocarbamate group under tin-free conditions

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A unified access to diverse heteroaromatic scaffolds using the radical chemistry of xanthates

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The Invention of New Radical Chain Reactions. Part XIII. High Yielding Decarboxylative Chalcogenation of Aliphatic and Alicyclic Acids

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Synthesis and synthetic chemistry of pleuromutilin

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Absolute Rate Constants for Alkoxycarbonyl Radical Reactions

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Generation and Capture of Iminyl Radicals from Ketoxime Xanthates

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New radical reactions of S-alkoxycarbonyl xanthates. Total synthesis of (±)-cinnamolide and (±)-methylenolactocin

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Tributylstannane-mediated cyclization of thionocarboxylic acid derivatives

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A practical decarboxylative hydroxylation of carboxylic acids

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The electron spin resonance spectra and decarboxylation of alkoxycarbonyl radicals

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The xanthate route to organofluorine derivatives. A brief account

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A novel radical chain reaction of xanthic anhydrides. Further observations on the intermediacy of alkoxy-thiocarbonyl radicals in the Barton-McCombie reaction

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A practical modification of the Barton-McCombie reaction and radical O- to S- rearrangement of xanthates

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Thione–Thiol Rearrangement: Miyazaki–Newman–Kwart Rearrangement and Others

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Iminyl Radical Generation via Iminodithiocarbonate Group Transfer

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Some intriguing mechanistic aspects of the radical chemistry of xanthates

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Application of an amidyl radical cascade to the total synthesis of (±)-fortucine leading to the structural revision of kirkine

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Xanthic anhydrides: A novel and convenient source of alkoxythiocarbonyl and alkyl radicals.

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Factors Affecting the Relative and Absolute Rates of β-Scission of Alkoxythiocarbonyl Radicals and Alkoxycarbonyl Radicals

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Leveraging of Sulfur Anions in Photoinduced Molecular Transformations

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Thiocarbonyl chemistry in polymer science

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The Cyclopropane Ring as a Reporter of Radical Leaving-Group Reactivity for Ni-Catalyzed C(sp 3 )–O Arylation

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Discovery of the RAFT/MADIX Process: Mechanistic Insights and Polymer Chemistry Implications

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Direct Radical Copolymerizations of Thioamides To Generate Vinyl Polymers with Degradable Thioether Bonds in the Backbones

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Radical Alliances: Solutions and Opportunities for Organic Synthesis

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Radical-promoted single-unit monomer insertion (SUMI) [aka. reversible-deactivation radical addition (RDRA)]

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Photocatalytic C–O Bond Cleavage of Alcohols Using Xanthate Salts

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Unified Approach to Deamination and Deoxygenation Through Isonitrile Hydrodecyanation: A Combined Experimental and Computational Investigation

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Deoxy sugars. General methods for carbohydrate deoxygenation and glycosidation

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The Xanthate Route to Indolines, Indoles, and their Aza Congeners

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Selective Biocatalytic Defunctionalization of Raw Materials

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Ph3P═O-Catalyzed Reductive Deoxygenation of Alcohols

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Redox-active alkyl xanthate esters enable practical C–S cross-coupling by nickel catalysis

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Radical chain monoalkylation of pyridines

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Radical Clock Probes to Determine Carbohydrate Radical Stabilities

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Redox-Active Thiocarbonyl Auxiliaries in Ni-Catalyzed Cross-Couplings of Aliphatic Alcohols

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Ph 3 P/ICH 2 CH 2 I-promoted reductive deoxygenation of alcohols

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Deoxygenation of Alcohols in Organic Electrosynthesis: Basic Strategies and Recent Developments

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A Route to 5,5-Dithiospiroketals and to Long-Chain Monomers from the Biomass

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Desulfitative Thioalkylation of Alkenes

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Radicals and Carbohydrates: A Grand Alliance

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Radical click reaction for C–S bond construction via reductive coupling of phthalimide derivatives

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A Sterically Tuned 2-Fluoropyridinium Salt for the Catalyst-Free, Visible-Light-Mediated Deoxygenation of Alcohols via an Electron Donor–Acceptor Complex

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Unprecedented Epimerization of an Azithromycin Analogue: Synthesis, Structure and Biological Activity of 2′-Dehydroxy-5″-Epi-Azithromycin

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Overview of RAFT Polymerization

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Zn-Doped Copper Nanoparticles Emerged on V3O4 for Selective Catalytic Activity toward Nitroarenes Reduction

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Efficient Synthesis of the Key Intermediate of Scopolamine by [4+3] Cycloaddition Reaction

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