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Recent advances in the construction and analytical applications of metal-organic frameworks-based nanozymes
Abstract
Abstract The nanozymes are a kind of synthetic nanomaterials with enzyme-like properties. Metal–organic frameworks (MOFs) are an important class of inorganic–organic hybrid crystals. Their unique composition, structural diversity and size tailorability enable them to be promising for the construction of novel nanozymes. This review intends to summarize the recent advance for the construction of MOFs-based nanozymes and their primary applications in chemical sensing and biosensing. Based on their synthetical strategies, the MOFs-based nanozymes are categorized into four classes: pristine MOFs, MOFs with chemical modification, MOFs-based composites and MOF derivatives. In each categorization, the design and enzyme mimetic activity are discussed. Moreover, the analytical applications of these nanozymes are covered, such as the detection of H2O2, small biomolecules releasing H2O2, reductive small biomolecules, biomacromolecules, heavy metal ions, toxic metabolite of fungi, antibiotics, and so on. Finally, a summary and future perspective on the applications of MOFs-based nanozymes are briefly discussed.
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Cites
Intrinsic peroxidase-like activity of ferromagnetic nanoparticles
Gao, L., Zhuang, J., Nie, L., Zhang, J., Zhang, Y., Gu, N., Wang, T., Feng, J., Yang, D., Perrett, S., et al. (2007) · Nature Nanotechnology · doi:10.1038/nnano.2007.260 · Cited by 7,483
Cited by
Metal-organic frameworks as novel matrices for efficient enzyme immobilization: An update review
Liang, S., Wu, X.-L., Xiong, J., Zong, M.-H., & Lou, W.-Y. (2020) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.213149 · Cited by 441
Specific Nanodrug for Diabetic Chronic Wounds Based on Antioxidase-Mimicking MOF-818 Nanozymes
Chao, D., Dong, Q., Yu, Z., Qi, D., Li, M., Xu, L., Liu, L., Fang, Y., & Dong, S. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.2c09663 · Cited by 317
Metadata
- Authors
- Li, S., Liu, X., Chai, H., & Huang, Y.
- Venue
- TrAC Trends in Analytical Chemistry
- Publisher
- Elsevier BV
- Published
- 2018-08
- Volume
- 105
- Pages
- 391-403
- ISSN
- 0165-9936 (ISSN-L)
- OpenAlex
- W2806465783
- Cited by
- 350
- References
- 1
- FWCI
- 13.74
- Type
- journal article
- Language
- en
- Open access
- closed
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- Li, S., Liu, X., Chai, H., & Huang, Y. (2018). Recent advances in the construction and analytical applications of metal-organic frameworks-based nanozymes. TrAC Trends in Analytical Chemistry. https://doi.org/10.1016/j.trac.2018.06.001
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