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A novel magnetic Fe@Au core–shell nanoparticles anchored graphene oxide recyclable nanocatalyst for the reduction of nitrophenol compounds

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Gupta, Vinod Kumar, Atar, Necip, Yola, Mehmet Lütfi, Üstündağ, Zafer, Uzun, Lokman·2014·Water Research

Abstract

In this study, a novel catalyst based on Fe@Au bimetallic nanoparticles involved graphene oxide was prepared and characterized by transmission electron microscope (TEM), and x-ray photoelectron spectroscopy (XPS). The nanomaterial was used in catalytic reductions of 4-nitrophenol and 2-nitrophenol in the presence of sodium borohydride. The experimental parameters such as temperature, the dosage of catalyst and the concentration of sodium borohydride were studied. The rates of catalytic reduction of the nitrophenol compounds have been found as the sequence: 4-nitrophenol>2-nitrophenol. The kinetic and thermodynamic parameters of nitrophenol compounds were determined. Activation energies were found as 2.33 kcal mol(-1) and 3.16 kcal mol(-1) for 4-nitrophenol and 2-nitrophenol, respectively. The nanomaterial was separated from the product by using a magnet and recycled after the reduction of nitrophenol compounds. The recyclable of the nanocatalyst is economically significant in industry.

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Metadata

Authors
Gupta, V. K., Atar, N., Yola, M. L., Üstündağ, Z., & Uzun, L.
Venue
Water Research
Publisher
Elsevier BV
Published
2014-01
Volume
48
Pages
210-217
ISSN
0043-1354 (ISSN-L)
OpenAlex
W1991830983
Cited by
606
References
5
FWCI
12.05
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: A novel magnetic Fe@Au core–shell nanoparticles anchored graphene oxide recyclable nanocatalyst for the reduction of nitrophenol compounds. https://app.cochat.ai/papers/10.1016/j.watres.2013.09.027
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Gupta, V. K., Atar, N., Yola, M. L., Üstündağ, Z., & Uzun, L. (2014). A novel magnetic Fe@Au core–shell nanoparticles anchored graphene oxide recyclable nanocatalyst for the reduction of nitrophenol compounds. Water Research. https://doi.org/10.1016/j.watres.2013.09.027

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