Physical regulation of copper catalyst with a hydrophobic promoter for enhancing CO2 hydrogenation to methanol
Open accessAbstract
The hydrogenation of CO 2 to methanol, which is restricted by water products, requires a selective removal of water from the reaction system. Here, we show that physically combining hydrophobic polydivinylbenzene with a copper catalyst supported by silica can increase methanol production and CO 2 conversion. Mechanistic investigation reveals that the hydrophobic promoter could hinder the oxidation of copper surface by water, maintaining a small fraction of metallic copper species on the copper surface with abundant Cu δ+ , resulting in high activity for the hydrogenation. Such a physically mixed catalyst survives the continuous test for 100 h owing to the thermal stability of the polydivinylbenzene promoter.
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The reducing agents mainly include hydrogen, carbon or methane, and fluorine.
“The reducing agents mainly include hydrogen, 106-110 carbon or methane, 26,111,112 and fluorine. 113”
From Energy system and resource utilization in space: A state-of-the-art review (2024) · cites this paper as [106]
Lockheed Martin and NASA's Glenn Research Center have developed prototypes for oxygen production from lunar soil using hydrogen reduction, namely PILOT and ROxygen systems, with an oxygen yield of approximately 1%-2%.
“Lockheed Martin and NASA's Glenn Research Center have developed prototypes for oxygen production from lunar soil using hydrogen reduction, namely the Precursor in-situ lunar oxygen testbed (PILOT) 106 and ROxygen 108 systems, with an oxygen yield of approximately 1%-2%.”
From Energy system and resource utilization in space: A state-of-the-art review (2024) · cites this paper as [106]
The Introduction discusses copper catalysts for CO2 hydrogenation to methanol, not oxygen extraction from lunar soil. Searches for PILOT, ROxygen, NASA Glenn, and a 1%–2% oxygen yield found no passage addressing the claim in our copy. (LLM, conf=0.78)
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- Authors
- Li, H., Fang, W., Wang, L.-X., Liu, Y., Liu, L., Sun, T., Liao, C., Zhu, Y., Wang, L., & Xiao, F.-S.
- Affiliations
- Zhejiang University (CN)
- Zhejiang University of Technology (CN)
- Corresponding author
- Wang, Liang
- Venue
- The Innovation
- Publisher
- Elsevier BV
- Published
- 2023-07
- Volume
- 4
- Issue
- 4
- Pages
- 100445
- ISSN
- 2666-6758 (ISSN-L)
- PMC
- PMC10251151
- OpenAlex
- W4377232032
- Cited by
- 67
- References
- 49
- Citations by year
- 2026: 20 · 2025: 26 · 2024: 19 · 2023: 2
- FWCI
- 3.13
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- The Innovation (publishedVersion, cc-by)
- PubMed Central (publishedVersion, cc-by)
- PubMed (publishedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
- Funders
- National Natural Science Foundation of China (22102142, 22241801, 22288101, U21B20101)
- National Key Research and Development Program of China (2022YFA1503502)
- Topics
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Keywords
- CO2 hydrogenation, methanol synthesis, copper catalysts, polydivinylbenzene, water removal, catalyst stability
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