Na + -gated water-conducting nanochannels for boosting CO 2 conversion to liquid fuels
Abstract
Water-selective zeolite membranes: The yield of many gas-phase industrial reactions is limited by the formation of water as a by-product. Li et al. harnessed the water-sieving properties of NaA zeolite crystals by forming them into continuous defect-free membranes within tube reactors (see the Perspective by Carreon). These membranes can let water pass but reject gases such as hydrogen, carbon monoxide, and carbon dioxide (CO 2 ). When these membranes were used in CO 2 hydrogenation to form methanol with water as a by-product, substantial increases were observed in both the CO 2 conversion and methanol yield. Science , this issue p. 667 ; see also p. 624
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Membranes of NaA zeolite have been proposed for drying industrially relevant streams.
“Even membranes of NaA zeolite have been proposed for drying of industrially relevant streams.425”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [425]
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- Authors
- Li, H., Qiu, C., Ren, S., Dong, Q., Zhang, S., Zhou, F., Liang, X., Wang, J., Li, S., & Yu, M.
- Affiliations
- Rensselaer Polytechnic Institute (US)
- Zhejiang University of Technology (CN)
- Missouri University of Science and Technology (US)
- Gas Technology Institute (US)
- Corresponding author
- Yu, Miao
- ORCID
- Venue
- Science
- Published
- 2020-02-07
- Volume
- 367
- Issue
- 6478
- Pages
- 667-671
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W3004482724
- Cited by
- 271
- References
- 75
- Citations by year
- 2026: 55 · 2025: 52 · 2024: 31 · 2023: 43 · 2022: 39 · 2021: 27 · 2020: 24
- FWCI
- 6.79
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Science (publishedVersion)
- PubMed (publishedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- U.S. Department of Energy (DE-AR0000806)
- Rensselaer Polytechnic Institute (startup fund)
- National Natural Science Foundation of China (NCFC-21625604)
- Topics
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Physical Sciences › Engineering › Mechanical Engineering › Membrane Separation and Gas Transport
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Keywords
- zeolite A, water-selective membranes, nanochannels, CO2 hydrogenation, methanol synthesis, tubular reactor, CO2 conversion, liquid fuels, gas separation
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