The formation of a peracetal and trioxane from an enol ether with Copper(II) triflate and oxygen: unexpected oxygenation of aldol intermediates
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
In vitro experiments have shown that 481 can undergo spontaneous conversion to a transient enol as proposed in step ii).
“These in vitro experiments have shown that 481 can indeed undergo sponataneous conversion to a transient enol as proposed in step ii) of Scheme 11 [204,238,243,302,303]”
From The Biosynthesis of Artemisinin (Qinghaosu) and the Phytochemistry of Artemisia annua L. (Qinghao) (2010) · cites this paper as [302]
Cites
Solvolytic routes via alkylcopper intermediates in the electron-transfer oxidation of alkyl radicals
Jenkins, C. L., & Kochi, J. K. (1972) · Journal of the American Chemical Society · doi:10.1021/ja00758a024 · Cited by 189 · see citing works
Jefford, C. W., Kohmoto, S., Boukouvalas, J., & Bürger, U. (1983) · Journal of the American Chemical Society · doi:10.1021/ja00359a028 · Cited by 65 · see citing works
Haynes, R. K., & Vonwiller, S. C. (1990) · Journal of the Chemical Society, Chemical Communications · doi:10.1039/c39900000451 · Cited by 58 · see citing works
Self-citationVonwiller, S. C., Warner, J. A., Mann, S. T., & Haynes, R. K. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00150a009 · Cited by 48 · see citing works
Paquette, L. A., DeRussy, D. T., Pegg, N. A., Taylor, R. T., & Zydowsky, T. M. (1989) · The Journal of Organic Chemistry · doi:10.1021/jo00280a023 · Cited by 43 · see citing works
Posner, G. H., Oh, C. H., & Milhous, W. K. (1991) · Tetrahedron Letters · doi:10.1016/s0040-4039(00)92136-1 · Cited by 43 · see citing works
Haynes, R. K., & Vonwiller, S. C. (1992) · Synlett · doi:10.1055/s-1992-21384 · Cited by 36 · see citing works
Polarographic evidence for the stability of copper(I) ion in some non-complexing nonaqueous solvents
Nelson, I. V., Larson, R. C., & Iwamoto, R. T. (1961) · Journal of Inorganic and Nuclear Chemistry · doi:10.1016/0022-1902(61)80444-2 · Cited by 35 · see citing works
Synthesis of tricyclic arteannuin-like compounds
Jefford, C. W., Velarde, J., & Bernardinelli, G. H. (1989) · Tetrahedron Letters · doi:10.1016/s0040-4039(01)80724-3 · Cited by 34 · see citing works
Synthesis of 1,2-dioxetanes via electron-transfer oxygenation
Curci, R., Lopez, L., Troisi, L., RASHID, S. M. K., & Schaap, A. P. (1987) · Tetrahedron Letters · doi:10.1016/s0040-4039(00)96719-4 · Cited by 22 · see citing works
A New Reaction of 1,2‐Dioxetanes. Formation of 1,2,4‐Trioxanes from Aldehydes
Jefford, C. W., Boukouvalas, J., & Kohmoto, S. (1983) · Helvetica Chimica Acta · doi:10.1002/hlca.19830660828 · Cited by 22 · see citing works
Haynes, R. K., Vonwiller, S. C., & Wang, H. (1995) · Tetrahedron Letters · doi:10.1016/0040-4039(95)00806-n · Cited by 19 · see citing works
Lopez, L., Troisi, L., RASHID, S. M. K., & Schaap, A. P. (1989) · Tetrahedron Letters · doi:10.1016/s0040-4039(00)95235-3 · Cited by 18 · see citing works
Lopez, L., & Troisi, L. (1992) · Tetrahedron · doi:10.1016/s0040-4020(01)88269-7 · Cited by 18 · see citing works
Electron-transfer induced conversion of enol-ethers into ketones
Lopez, L., & Troisi, L. (1989) · Tetrahedron Letters · doi:10.1016/s0040-4039(00)95236-5 · Cited by 9 · see citing works
Jefford, C. W., Grant, H. G., Jaggi, D., Boukouvalas, J., & Kohmoto, S. (1984) · Helvetica Chimica Acta · doi:10.1002/hlca.19840670824 · Cited by 8 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
The Biosynthesis of Artemisinin (Qinghaosu) and the Phytochemistry of Artemisia annua L. (Qinghao)
Brown, G. D. (2010) · Molecules · doi:10.3390/molecules15117603 · Cited by 363 · see citing works
Dussault, P. H., Lee, H., & Liu, X. (2000) · Journal of the Chemical Society Perkin Transactions 1 · doi:10.1039/b001391i · Cited by 41 · see citing works
Korshin, E. E., & Bachi, M. D. (2009) · Patai's chemistry of functional groups · doi:10.1002/9780470682531.pat0351 · Cited by 8 · see citing works
Copper(II) Trifluoromethanesulfonate
Laali, K. K., Sarca, V. D., & Ollevier, T. (2016) · Encyclopedia of Reagents for Organic Synthesis · doi:10.1002/047084289x.rc250.pub3
Copper(II) Trifluoromethanesulfonate
Laali, K. K., Sarca, V. D., & Laali, K. K. (2007) · Encyclopedia of Reagents for Organic Synthesis · doi:10.1002/9780470842898.rc250.pub2
Copper(II) Trifluoromethanesulfonate
Laali, K. K., Sarca, V. D., & Laali, K. K. (2007) · Encyclopedia of Reagents for Organic Synthesis · doi:10.1002/047084289x.rc250.pub2
- Authors
- Vonwiller, S. C., Warner, J. A., Mann, S. T., & Haynes, R. K.
- Affiliations
- The University of Sydney (AU)
- Hong Kong University of Science and Technology (HK)
- ORCID
- Haynes, Richard K.
- Venue
- Tetrahedron Letters
- Publisher
- Elsevier BV
- Published
- 1997-03
- Volume
- 38
- Issue
- 13
- Pages
- 2363-2366
- ISSN
- 0040-4039 (ISSN-L)
- OpenAlex
- W1978577888
- Cited by
- 5
- References
- 16
- Citations by year
- 2016: 1
- FWCI
- 0.30
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Tetrahedron Letters (publishedVersion)
- Rare & Special e-Zone (The Hong Kong University of Science and Technology) (submittedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Oxidative Organic Chemistry Reactions
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Catalyzed Oxygenation Mechanisms
- Physical Sciences › Chemistry › Organic Chemistry › Organic Chemistry Synthesis Methods
- Keywords
- enol ethers, copper(II) triflate, oxygenation, ketoaldehydes
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
