METAL ION CATALYZED AUTOXIDATION REACTIONS: KINETICS AND MECHANISMS
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A variety of antioxidants can act as pro-oxidants and promote the production of OH• radicals in the presence of inappropriately or inadequately liganded Fe(II).
“One interpretation for these disappointing results, that is consistent with the general theme of this review, involves the recognition that a variety of antioxidants can in fact act as pro-oxidants and thus actually promote the production of OH• radicals in the presence of inappropriately or inadequately liganded Fe(II) [130,528,1602,1604,1659,1660].”
From Iron behaving badly: inappropriate iron chelation as a major contributor to the aetiology of vascular and other progressive inflammatory and degenerative diseases (2009) · cites this paper as [1604]
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The neglected significance of “antioxidative stress”
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Self-citationExpósito, A., Maillo, J., Uriarte, I., Santibáñez, M., & Fernández-Olmo, I. (2023) · SSRN Electronic Journal · doi:10.2139/ssrn.4625022
- Authors
- FÁBIÁN, I., & CSORDÁS, V.
- Affiliations
- University of Debrecen (HU)
- ORCID
- FÁBIÁN, ISTVÁN
- Venue
- Advances in Inorganic Chemistry
- Publisher
- Elsevier
- Published
- 2003
- Pages
- 395-461
- ISSN
- 0898-8838 (ISSN-L)
- OpenAlex
- W2085861872
- Cited by
- 19
- References
- 162
- Citations by year
- 2024: 1 · 2017: 2 · 2014: 1 · 2012: 1
- FWCI
- 10.15
- Type
- book chapter
- Language
- en
- Open access
- closed
- Locations
- Advances in inorganic chemistry (publishedVersion)
- University of Debrecen Electronic Archive (University of Debrecen) (submittedVersion)
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Catalyzed Oxygenation Mechanisms
- Physical Sciences › Chemistry › Organic Chemistry › Oxidative Organic Chemistry Reactions
- Physical Sciences › Chemistry › Organic Chemistry › Free Radicals and Antioxidants
- Keywords
- metal ion catalysis, reaction kinetics, reaction mechanism, dioxygen activation, metal-substrate interaction, model systems
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