Authigenesis of native sulphur and dolomite in a lacustrine evaporitic setting (Hellín basin, Late Miocene, SE Spain)

LINDTKE, J.; ZIEGENBALG, S. B.; BRUNNER, B.; ROUCHY, J. M.; PIERRE, C.; PECKMANN, J.

doi:10.1017/s0016756811000124

Cited by 50Paleontology and Stratigraphy of FossilsGeochemistry and Elemental AnalysisGeological formations and processes

Authigenesis of native sulphur and dolomite in a lacustrine evaporitic setting (Hellín basin, Late Miocene, SE Spain)

LINDTKE, J., ZIEGENBALG, S. B., BRUNNER, B., ROUCHY, J. M., PIERRE, C., PECKMANN, J.·2011·Geological Magazine

DOI 10.1017/s0016756811000124

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Abstract

Abstract Abundant sulphur is present in the Late Miocene evaporitic sequence of the lacustrine Hellín basin in SE Spain. Weathering of Triassic evaporites controlled the chemical composition of the Miocene lake. The lacustrine deposits comprise gypsum, marlstones, diatomites and carbonate beds. Sulphur-bearing carbonate deposits predominantly consist of early diagenetic dolomite. Abundant dolomite crystals with a spheroidal habit are in accordance with an early formation and point to a microbial origin. The carbon isotopic composition of the dolomite (δ13C values between −10 and −4‰) indicates mixing of lake water carbonate and carbonate derived from the remineralization of organic matter by heterotrophic bacteria. Dolomite precipitated syngenetically under evaporitic conditions as indicated by high oxygen isotope values (δ18O between +6 and +11‰). Nodules of native sulphur are found in gypsum, carbonate beds and marlstone layers. Sulphur formed in the course of microbial sulphate reduction, as reflected by its strong depletion in34S (δ34S values as low as −17‰). Near to the surface many of the sulphur nodules were in part or completely substituted by secondary gypsum, which still reflects the sulphur isotopic composition of native sulphur (−18 to −10‰). This study exemplifies the role of bacterial sulphate reduction in the formation of dolomite and native sulphur in a semi-enclosed lacustrine basin during Late Miocene time.

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In modern environments, dolomite currently forms through the direct route only in a restricted number of hypersaline environments, such as evaporitic lakes or sabkhas.
“In modern environments dolomite currently forms through the 'direct' route, but only in a restricted number of hypersaline environments [i.e., evaporitic lakes or sabkhas; e.g., Jones (1965), Lindtke et al. (2011), Meister et al. (2011)].”
From A route for the direct crystallization of dolomite (2015) · cites this paper as Lindtke et al. (2011)

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Authors: LINDTKE, J., ZIEGENBALG, S. B., BRUNNER, B., ROUCHY, J. M., PIERRE, C., & PECKMANN, J.
Affiliations: University of Bremen (DE)
Max Planck Institute for Marine Microbiology (DE)
Muséum national d'Histoire naturelle (FR)
Centre National de la Recherche Scientifique (FR)
University of Vienna (AT)
Corresponding author: PECKMANN, J.
ORCID: BRUNNER, B.
PIERRE, C.
PECKMANN, J.
Venue: Geological Magazine
Publisher: Cambridge University Press (CUP)
Published: 2011-02-17
Volume: 148
Issue: 4
Pages: 655-669
ISSN: 0016-7568 (ISSN-L)
1469-5081
DOI: 10.1017/s0016756811000124
OpenAlex: W2334442893
Cited by: 50
References: 92
Citations by year: 2026: 1 · 2025: 5 · 2024: 1 · 2023: 5 · 2022: 8 · 2021: 2 · 2020: 5 · 2019: 5 · 2018: 3 · 2017: 1 · 2016: 5 · 2015: 3 · 2014: 1 · 2013: 3 · 2012: 1
FWCI: 1.34
Type: journal article
Language: en
Open access: closed
Licence: www.cambridge.org/core/terms (unspecified)
Locations: Geological Magazine (publishedVersion)
Max Planck Digital Library (submittedVersion)
MPG.PuRe (Max Planck Society) (submittedVersion)
Topics: Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
Physical Sciences › Earth and Planetary Sciences › Earth-Surface Processes › Geological formations and processes
Keywords: microbial sulfate reduction, lacustrine evaporites, Late Miocene, carbon isotopes, oxygen isotopes, sulfur isotopes, gypsum, diatomite, marlstone, heterotrophic bacteria, semi-enclosed basins

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Authigenesis of native sulphur and dolomite in a lacustrine evaporitic setting (Hellín basin, Late Miocene, SE Spain)

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