The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Metal−Organic Framework Thin Film for Enhanced Localized Surface Plasmon Resonance Gas Sensing
Abstract
Despite its high refractive index sensitivity, localized surface plasmon resonance (LSPR) spectroscopy has been generally restricted to large biological analytes. Sensing of smaller molecules is a compelling target for this technique; in particular, LSPR spectroscopy could be utilized to detect hazardous or toxic gases and manage industrial processes involving gaseous chemicals. Here, we report sensing of pure gases over Ag nanoparticles using LSPR spectroscopy, where the detected changes in bulk refractive index are <5 × 10(-4) refractive index units (RIU). We further demonstrate a novel strategy for amplifying the sensing signal by coating the plasmonic substrate with a metal-organic framework (MOF) material. Cu(3)(BTC)(2)(H(2)O)(3), BTC = benzenetricarboxylate, was grown on Ag nanoparticles using a layer-by-layer method in order to control the MOF thickness, which we show greatly affects the sensor response. Preferential concentration of CO(2) within the MOF pores produces a 14-fold signal enhancement for CO(2) sensing. In principle, MOFs can be tailored for sorbing different analytes, making them ideal materials for this amplification strategy. Because the sensing signal originates in the nanoparticle extinction spectrum and not in the MOF itself, this comprises a generalizable sensing scheme applicable to any porous MOF and any analyte.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Functional Porous Coordination Polymers
Kitagawa, S., Kitaura, R., & Noro, S. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200300610 · Cited by 11,071
Selective gas adsorption and separation in metal–organic frameworks
Li, J.-R., Kuppler, R. J., & Zhou, H.-C. (2009) · Chemical Society Reviews · doi:10.1039/b802426j · Cited by 8,932
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Self-citationBiosensing with plasmonic nanosensors
Anker, J. N., Hall, W. P., Lyandres, O., Shah, N. C., Zhao, J., & Van Duyne, R. P. (2008) · Nature Materials · doi:10.1038/nmat2162 · Cited by 6,786
Self-citationLocalized Surface Plasmon Resonance Spectroscopy and Sensing
Willets, K. A., & Van Duyne, R. P. (2007) · Annual Review of Physical Chemistry · doi:10.1146/annurev.physchem.58.032806.104607 · Cited by 6,171
Self-citationA Chemically Functionalizable Nanoporous Material [Cu 3 (TMA) 2 (H 2 O) 3 ] n
Chui, S. S.-Y., Lo, S. M.-F., Charmant, J. P. H., Orpen, A. G., & Williams, I. D. (1999) · Science · doi:10.1126/science.283.5405.1148 · Cited by 6,063
Hybrid porous solids: past, present, future
Férey, G. (2008) · Chem. Soc. Rev. · doi:10.1039/b618320b · Cited by 5,822
Haynes, C. L., & Van Duyne, R. P. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp010657m · Cited by 2,500
Self-citationSecondary building units, nets and bonding in the chemistry of metal–organic frameworks
Tranchemontagne, D. J., Mendoza-Cortés, J. L., O’Keeffe, M., & Yaghi, O. M. (2009) · Chemical Society Reviews · doi:10.1039/b817735j · Cited by 2,478
Haes, A. J., & Van Duyne, R. P. (2002) · Journal of the American Chemical Society · doi:10.1021/ja020393x · Cited by 2,057
Schlichte, K., Kratzke, T., & Kaskel, S. (2004) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2003.12.027 · Cited by 1,112
Lu, G., & Hupp, J. T. (2010) · Journal of the American Chemical Society · doi:10.1021/ja101415b · Cited by 1,082
Self-citationLuminescent Open Metal Sites within a Metal–Organic Framework for Sensing Small Molecules
Chen, B., Yang, Y., Zapata, F., Lin, G., Qian, G., & Lobkovsky, E. B. (2007) · Advanced Materials · doi:10.1002/adma.200601838 · Cited by 954
Step-by-Step Route for the Synthesis of Metal−Organic Frameworks
Shekhah, O., Wang, H., Kowarik, S., Schreiber, F., Paulus, M., Tolan, M., Sternemann, C., Evers, F., Zacher, D., Fischer, R. A., et al. (2007) · Journal of the American Chemical Society · doi:10.1021/ja076210u · Cited by 910
Haes, A. J., Chang, L., Klein, W. L., & Van Duyne, R. P. (2005) · Journal of the American Chemical Society · doi:10.1021/ja044087q · Cited by 864
Self-citationPrestipino, C., Regli, L., Vitillo, J. G., Bonino, F., Damin, A., Lamberti, C., Zecchina, A., Solari, P. L., Kongshaug, K. O., & Bordiga, S. (2006) · Chemistry of Materials · doi:10.1021/cm052191g · Cited by 761
Hydrogen storage in metal–organic frameworks
Collins, D. J., & Zhou, H.-C. (2007) · Journal of Materials Chemistry · doi:10.1039/b702858j · Cited by 720
Biomolecular Recognition Based on Single Gold Nanoparticle Light Scattering
Raschke, G., Kowarik, S., Franzl, T., Sönnichsen, C., Klar, T. A., Feldmann, J., Nichtl, A., & Kürzinger, K. (2003) · Nano Letters · doi:10.1021/nl034223+ · Cited by 716
An Interweaving MOF with High Hydrogen Uptake
Sun, D., Ma, S., Ke, Y., Collins, D. J., & Zhou, H.-C. (2006) · Journal of the American Chemical Society · doi:10.1021/ja058777l · Cited by 591
Yazaydın, A. Ö., Benin, A. I., Faheem, S. A., Jakubczak, P., Low, J. J., Willis, R. R., & Snurr, R. Q. (2009) · Chemistry of Materials · doi:10.1021/cm900049x · Cited by 588
A Catalytically Active, Permanently Microporous MOF with Metalloporphyrin Struts
Shultz, A. M., Farha, O. K., Hupp, J. T., & Nguyen, S. T. (2009) · Journal of the American Chemical Society · doi:10.1021/ja900203f · Cited by 546
Self-citationJensen, T. R., Duval, M. L., Kelly, K. L., Lazarides, A. A., Schatz, G. C., & Van Duyne, R. P. (1999) · The Journal of Physical Chemistry B · doi:10.1021/jp9926802 · Cited by 542
Self-citationBiemmi, E., Scherb, C., & Bein, T. (2007) · Journal of the American Chemical Society · doi:10.1021/ja0701208 · Cited by 535
Stress-Induced Chemical Detection Using Flexible Metal−Organic Frameworks
Allendorf, M. D., Houk, R. J. T., Andruszkiewicz, L., Talin, A. A., Pikarsky, J., Choudhury, A., Gall, K. A., & Hesketh, P. J. (2008) · Journal of the American Chemical Society · doi:10.1021/ja805235k · Cited by 488
Liquid Phase Adsorption by Microporous Coordination Polymers: Removal of Organosulfur Compounds
Cychosz, K. A., Wong-Foy, A. G., & Matzger, A. J. (2008) · Journal of the American Chemical Society · doi:10.1021/ja802121u · Cited by 391
A Highly Porous Luminescent Terbium–Organic Framework for Reversible Anion Sensing
Wong, K. ‐., Law, G. ‐., Yang, Y. ‐., & Wong, W. ‐. (2006) · Advanced Materials · doi:10.1002/adma.200502138 · Cited by 387
Chowdhury, P., Bikkina, C., Meister, D., Dreisbach, F., & Gumma, S. (2008) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2008.07.029 · Cited by 269
Determination of environmental organic pollutants with a portable optical immunosensor
Mauriz, E., Calle, A., Montoya, A., & Lechuga, L. M. (2005) · Talanta · doi:10.1016/j.talanta.2005.09.049 · Cited by 127
Chen, Y.-Q., & Lu, C.-J. (2008) · Sensors and Actuators B Chemical · doi:10.1016/j.snb.2008.09.030 · Cited by 90
Cited by
MOF positioning technology and device fabrication
Falcaro, P., Ricco, R., Doherty, C. M., Liang, K., Hill, A. J., & Styles, M. J. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00089g · Cited by 710
Facile “Modular Assembly” for Fast Construction of a Highly Oriented Crystalline MOF Nanofilm
Xu, G., Yamada, T., Otsubo, K., Sakaida, S., & Kitagawa, H. (2012) · Journal of the American Chemical Society · doi:10.1021/ja307953m · Cited by 353
Gas identification with graphene plasmons
Hu, H., Yang, X., Guo, X., Khaliji, K., Biswas, S. R., García de Abajo, F. J., Low, T., Sun, Z., & Dai, Q. (2019) · Nature Communications · doi:10.1038/s41467-019-09008-0 · Cited by 225
All-Dielectric Surface-Enhanced Infrared Absorption-Based Gas Sensor Using Guided Resonance
Chang, Y., Hasan, D., Dong, B., Wei, J., Ma, Y., Zhou, G., Ang, K. W., & Lee, C. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b16623 · Cited by 115
Metadata
- Authors
- Kreno, L. E., Hupp, J. T., & Van Duyne, R. P.
- Venue
- Analytical Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-09-14
- Volume
- 82
- Issue
- 19
- Pages
- 8042-8046
- ISSN
- 0003-2700 (ISSN-L)
- 1520-6882
- OpenAlex
- W2323506142
- Cited by
- 367
- References
- 29
- FWCI
- 11.95
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
