The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Surface-Confined Amorphous Films from Metal-Coordinated Simple Phenolic Ligands
Open accessAbstract
Coordination chemistry of natural polyphenols and transition metals allows rapid self-assembly of conformal coatings on diverse substrates. Herein, we report that this coordination-driven self-assembly process applies to simple phenolic molecules with monotopic or ditopic chelating sites (as opposed to macromolecular, multitopic polyphenols), leading to surface-confined amorphous films upon metal coordination. Films fabricated from gallic acid, pyrogallol, and pyrocatechol, which are the major monomeric building blocks of polyphenols, have been studied in detail. Pyrocatechol, with one vicinal diol group (i.e., bidentate), has been observed to be the limiting case for such assembly. This study expands the toolbox of available phenolic ligands for the formation of surface-confined amorphous films, which may find application in catalysis, energy, optoelectronics, and the biomedical sciences.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Liu, Y., Ai, K., & Lu, L. (2014) · Chemical Reviews · doi:10.1021/cr400407a · Cited by 4,794
Holten-Andersen, N., Harrington, M. J., Birkedal, H., Lee, B. P., Messersmith, P. B., Lee, K. Y. C., & Waite, J. H. (2011) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1015862108 · Cited by 1,597
A Review of the Antioxidant Mechanisms of Polyphenol Compounds Related to Iron Binding
Perron, N. R., & Brumaghim, J. L. (2009) · Cell Biochemistry and Biophysics · doi:10.1007/s12013-009-9043-x · Cited by 1,370
Strong reversible Fe 3+ -mediated bridging between dopa-containing protein films in water
Zeng, H., Hwang, D. S., Israelachvili, J. N., & Waite, J. H. (2010) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1007416107 · Cited by 517
Robust, self-healing hydrogels synthesised from catechol rich polymers
Yavvari, P. S., & Srivastava, A. (2015) · Journal of Materials Chemistry B · doi:10.1039/c4tb01307g · Cited by 126
Cited by
Shao, C., Wang, M., Meng, L., Chang, H., Wang, B., Xu, F., Yang, J., & Wan, P. (2018) · Chemistry of Materials · doi:10.1021/acs.chemmater.8b01172 · Cited by 783
Metal Ion-Directed Functional Metal–Phenolic Materials
Geng, H., Zhong, Q.-Z., Li, J., Lin, Z., Cui, J., Caruso, F., & Hao, J. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c01042 · Cited by 531
Self-citationVoid Engineering in Metal–Organic Frameworks via Synergistic Etching and Surface Functionalization
Hu, M., Ju, Y., Liang, K., Suma, T., Cui, J., & Caruso, F. (2016) · Advanced Functional Materials · doi:10.1002/adfm.201601193 · Cited by 406
Self-citationPhenolic-enabled nanotechnology: versatile particle engineering for biomedicine
Wu, D., Zhou, J., Creyer, M. N., Yim, W., Chen, Z., Messersmith, P. B., & Jokerst, J. V. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00908c · Cited by 317
Al Zoubi, W., Kamil, M. P., Fatimah, S., Nashrah, N., & Ko, Y. G. (2020) · Progress in Materials Science · doi:10.1016/j.pmatsci.2020.100663 · Cited by 265
Metadata
- Authors
- Rahim, M. A., Kempe, K., Müllner, M., Ejima, H., Ju, Y., van Koeverden, M. P., Suma, T., Braunger, J. A., Leeming, M. G., Abrahams, B. F., & Caruso, F.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-08-06
- Volume
- 27
- Issue
- 16
- Pages
- 5825-5832
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2514001782
- Cited by
- 213
- References
- 5
- FWCI
- 6.42
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Surface-Confined Amorphous Films from Metal-Coordinated Simple Phenolic Ligands. https://app.cochat.ai/papers/10.1021/acs.chemmater.5b02790
- The paper
- Rahim, M. A., Kempe, K., Müllner, M., Ejima, H., Ju, Y., van Koeverden, M. P., Suma, T., Braunger, J. A., Leeming, M. G., Abrahams, B. F., & Caruso, F. (2015). Surface-Confined Amorphous Films from Metal-Coordinated Simple Phenolic Ligands. Chemistry of Materials. https://doi.org/10.1021/acs.chemmater.5b02790
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.