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Cited by 213

The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.

Surface-Confined Amorphous Films from Metal-Coordinated Simple Phenolic Ligands

Open access
Rahim, Md. Arifur, Kempe, Kristian, Müllner, Markus, Ejima, Hirotaka, Ju, Yi, van Koeverden, Martin P., Suma, Tomoya, Braunger, Julia A., Leeming, Michael G., Abrahams, Brendan F., Caruso, Frank·2015·Chemistry of Materials

Abstract

Coordination chemistry of natural polyphenols and transition metals allows rapid self-assembly of conformal coatings on diverse substrates. Herein, we report that this coordination-driven self-assembly process applies to simple phenolic molecules with monotopic or ditopic chelating sites (as opposed to macromolecular, multitopic polyphenols), leading to surface-confined amorphous films upon metal coordination. Films fabricated from gallic acid, pyrogallol, and pyrocatechol, which are the major monomeric building blocks of polyphenols, have been studied in detail. Pyrocatechol, with one vicinal diol group (i.e., bidentate), has been observed to be the limiting case for such assembly. This study expands the toolbox of available phenolic ligands for the formation of surface-confined amorphous films, which may find application in catalysis, energy, optoelectronics, and the biomedical sciences.

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Metadata

Authors
Rahim, M. A., Kempe, K., Müllner, M., Ejima, H., Ju, Y., van Koeverden, M. P., Suma, T., Braunger, J. A., Leeming, M. G., Abrahams, B. F., & Caruso, F.
Venue
Chemistry of Materials
Published
2015-08-06
Volume
27
Issue
16
Pages
5825-5832
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2514001782
Cited by
213
References
5
FWCI
6.42
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Surface-Confined Amorphous Films from Metal-Coordinated Simple Phenolic Ligands. https://app.cochat.ai/papers/10.1021/acs.chemmater.5b02790
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Rahim, M. A., Kempe, K., Müllner, M., Ejima, H., Ju, Y., van Koeverden, M. P., Suma, T., Braunger, J. A., Leeming, M. G., Abrahams, B. F., & Caruso, F. (2015). Surface-Confined Amorphous Films from Metal-Coordinated Simple Phenolic Ligands. Chemistry of Materials. https://doi.org/10.1021/acs.chemmater.5b02790

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.