The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Multilayered Perovskite Materials Based on Polymeric-Ammonium Cations for Stable Large-Area Solar Cell
Abstract
Despite the dramatic rise in power conversion efficiencies (PCEs) of perovskite solar cells (PeSCs), concerns surrounding the long-term stability as well as the poor reproducibility in the archetypal three-dimensional (3D) perovskite, MAPbI 3 (MA = CH 3 NH 3 ), have the potential to derail commercialization. We have reported the fabrication and properties of a series of 2D perovskite compounds (PEI) 2 (MA) n −1 Pb n I 3 n +1 ( n = 3, 5, 7) by incorporating polyethylenimine (PEI) cations within the layered structure. The benefits of using intercalated polymer cations in the multilayered films are multiple: moisture resistance and film quality are greatly enhanced compared to that of their 3D MAPbI 3 analogue; charge transport within solar cells can also be improved compared to that of 2D materials using small-molecule bulky ammonium. The moisture-stable nature of the multilayered perovskite materials allow for the simple one-step fabrication of cells with an aperture area of 2.32 cm 2 under ambient humidity that have a PCE up to 8.77%. Overall, the 2D perovskite family offers rich multitudes of substituent and crystal structures, defining a promising class of stable and efficient light-absorbing materials.
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Cites
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
Jeon, N. J., Noh, J. H., Kim, Y. C., Yang, W. S., Ryu, S., & Seok, S. I. (2014) · Nature Materials · doi:10.1038/nmat4014 · Cited by 6,723
Cited by
Li, X., Hoffman, J. M., & Kanatzidis, M. G. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01006 · Cited by 1,085
Ren, H., Yu, S., Chao, L., Xia, Y., Sun, Y., Zuo, S., Li, F., Niu, T., Yang, Y., Ju, H., et al. (2020) · Nature Photonics · doi:10.1038/s41566-019-0572-6 · Cited by 578
Self-citationLiu, J., Leng, J., Wu, K., Zhang, J., & Jin, S. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b12581 · Cited by 566
Enhanced Thermal Stability in Perovskite Solar Cells by Assembling 2D/3D Stacking Structures
Lin, Y., Bai, Y., Fang, Y., Chen, Z., Yang, S., Zheng, X., Tang, S., Liu, Y., Zhao, J., & Huang, J. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b02679 · Cited by 554
Impact of H2O on organic–inorganic hybrid perovskite solar cells
Huang, J., Tan, S., Lund, P. D., & Zhou, H. (2017) · Energy & Environmental Science · doi:10.1039/c7ee01674c · Cited by 489
Metadata
- Authors
- Yao, K., Wang, X., Xu, Y.-X., Li, F., & Zhou, L.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-04-22
- Volume
- 28
- Issue
- 9
- Pages
- 3131-3138
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2340602524
- Cited by
- 199
- References
- 1
- FWCI
- 16.77
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Multilayered Perovskite Materials Based on Polymeric-Ammonium Cations for Stable Large-Area Solar Cell. https://app.cochat.ai/papers/10.1021/acs.chemmater.6b00711
- The paper
- Yao, K., Wang, X., Xu, Y.-X., Li, F., & Zhou, L. (2016). Multilayered Perovskite Materials Based on Polymeric-Ammonium Cations for Stable Large-Area Solar Cell. Chemistry of Materials. https://doi.org/10.1021/acs.chemmater.6b00711
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