The DOI matches its Crossref record; 39 of the 39 references it cites were found in a registry or an index.
Confinement Effects in Low-Dimensional Lead Iodide Perovskite Hybrids
Open accessAbstract
We use a layered solution crystal growth technique to synthesize high-quality single crystals of phenylalkylammonium lead iodide organic/inorganic hybrid compounds. Single-crystal X-ray diffraction reveals low-dimensional structures consisting of inorganic sheets separated by bilayers of the organic cations. The shortest alkyls yield two-dimensional structures consisting of inorganic sheets of corner-sharing PbI 6 -octahedra. However, the longer alkyls induce both corner- and face-sharing of the PbI 6 -octahedra, and form new compounds. Density functional theory calculations including spin–orbit coupling show quantum confinement in two dimensions for the shorter alkyls, and in one dimension for the longer alkyls, respectively. The face-sharing PbI 6 -octahedra create a confinement leading to effectively one-dimensional behavior. These confinement effects are responsible for the observed peak shifts in photoluminescence for the different phenylalkylammonium lead iodide hybrids. Our results show how the connectivity of the octahedra leads to confinement effects that directly tune the optical band gap.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
Kojima, A., Teshima, K., Shirai, Y., & Miyasaka, T. (2009) · Journal of the American Chemical Society · doi:10.1021/ja809598r · Cited by 23,090
Efficient planar heterojunction perovskite solar cells by vapour deposition
Liu, M., Johnston, M. B., & Snaith, H. J. (2013) · Nature · doi:10.1038/nature12509 · Cited by 7,976
Electron-hole diffusion lengths > 175 μm in solution-grown CH 3 NH 3 PbI 3 single crystals
Dong, Q., Fang, Y., Shao, Y., Mulligan, P., Qiu, J., Cao, L., & Huang, J. (2015) · Science · doi:10.1126/science.aaa5760 · Cited by 5,643
Stoumpos, C. C., Malliakas, C. D., & Kanatzidis, M. G. (2013) · Inorganic Chemistry · doi:10.1021/ic401215x · Cited by 5,416
Noh, J. H., Im, S. H., Heo, J. H., Mandal, T. N., & Seok, S. I. (2013) · Nano Letters · doi:10.1021/nl400349b · Cited by 4,829
Bright light-emitting diodes based on organometal halide perovskite
Tan, Z.-K., Moghaddam, R. S., Lai, M. L., Docampo, P., Higler, R., Deschler, F., Price, M., Sadhanala, A., Pazos, L. M., Credgington, D., et al. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.149 · Cited by 4,450
Eperon, G. E., Stranks, S. D., Menelaou, C., Johnston, M. B., Herz, L. M., & Snaith, H. J. (2014) · Energy & Environmental Science · doi:10.1039/c3ee43822h · Cited by 4,140
Low-temperature solution-processed wavelength-tunable perovskites for lasing
Xing, G., Mathews, N., Lim, S. S., Yantara, N., Liu, X., Sabba, D., Grätzel, M., Mhaisalkar, S., & Sum, T. C. (2014) · Nature Materials · doi:10.1038/nmat3911 · Cited by 3,219
Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors
Zhu, H., Fu, Y., Meng, F., Wu, X., Gong, Z., Ding, Q., Gustafsson, M. V., Trinh, M. T., Jin, S., & Zhu, X.-Y. (2015) · Nature Materials · doi:10.1038/nmat4271 · Cited by 2,836
Liu, D., & Kelly, T. L. (2014) · Nature Photonics · doi:10.1038/nphoton.2013.342 · Cited by 2,663
Cited by
Two-Dimensional Hybrid Halide Perovskites: Principles and Promises
Mao, L., Stoumpos, C. C., & Kanatzidis, M. G. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.8b10851 · Cited by 1,584
2D Ruddlesden–Popper Perovskites for Optoelectronics
Chen, Y., Sun, Y., Peng, J., Tang, J., Zheng, K., & Liang, Z. (2018) · Advanced Materials · doi:10.1002/adma.201703487 · Cited by 892
Quantum and Dielectric Confinement Effects in Lower-Dimensional Hybrid Perovskite Semiconductors
Katan, C., Mercier, N., & Even, J. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00417 · Cited by 864
Weidman, M. C., Seitz, M., Stranks, S. D., & Tisdale, W. A. (2016) · ACS Nano · doi:10.1021/acsnano.6b03496 · Cited by 629
Ren, H., Yu, S., Chao, L., Xia, Y., Sun, Y., Zuo, S., Li, F., Niu, T., Yang, Y., Ju, H., et al. (2020) · Nature Photonics · doi:10.1038/s41566-019-0572-6 · Cited by 578
Metadata
- Authors
- Kamminga, M. E., Fang, H.-H., Filip, M. R., Giustino, F., Baas, J., Blake, G. R., Loi, M. A., & Palstra, T. T. M.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-06-24
- Volume
- 28
- Issue
- 13
- Pages
- 4554-4562
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2425887664
- Cited by
- 366
- References
- 39
- FWCI
- 14.94
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Confinement Effects in Low-Dimensional Lead Iodide Perovskite Hybrids. https://app.cochat.ai/papers/10.1021/acs.chemmater.6b00809
- The paper
- Kamminga, M. E., Fang, H.-H., Filip, M. R., Giustino, F., Baas, J., Blake, G. R., Loi, M. A., & Palstra, T. T. M. (2016). Confinement Effects in Low-Dimensional Lead Iodide Perovskite Hybrids. Chemistry of Materials. https://doi.org/10.1021/acs.chemmater.6b00809
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
