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Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics

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Kumar, Amit, Daw, Prosenjit, Milstein, David·2022·Chemical Reviews
DOI 10.1021/acs.chemrev.1c00412
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Abstract

As the world pledges to significantly cut carbon emissions, the demand for sustainable and clean energy has now become more important than ever.This includes both production and storage of energy carriers, a majority of which involve catalytic reactions.This article reviews recent developments of homogeneous catalysts in emerging applications of sustainable energy.The most important focus has been on hydrogen storage as several efficient homogeneous catalysts have been reported recently for (de)hydrogenative transformations promising to the hydrogen economy.Another direction that has been extensively covered in this review is that of the methanol economy.Homogeneous catalysts investigated for the production of methanol from CO 2 , CO, and HCOOH have been discussed in detail.Moreover, catalytic processes for the production of conventional fuels (higher alkanes such as diesel, wax) from biomass or lower alkanes have also been discussed.A section has also been dedicated to the production of ethylene glycol from CO and H 2 using homogeneous catalysts.Well-defined transition metal complexes, in particular, pincer complexes, have been discussed in more detail due to their high activity and well-studied mechanisms.

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Cited by

Metadata

Authors
Kumar, A., Daw, P., & Milstein, D.
Venue
Chemical Reviews
Publisher
American Chemical Society (ACS)
Published
2021-11-02
Volume
122
Issue
1
Pages
385-441
ISSN
  • 0009-2665 (ISSN-L)
  • 1520-6890
DOI
10.1021/acs.chemrev.1c00412
OpenAlex
W3208020068
Cited by
648
References
12
FWCI
3.87
Type
journal article
Language
en
Open access
hybrid
Licence
creativecommons.org/licenses/by/4.0/ (unspecified)
Funders
H2020 European Research Council (ERC AdG 692775)

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