The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Photochemical Approaches to Complex Chemotypes: Applications in Natural Product Synthesis
Open accessAbstract
The use of photochemical transformations is a powerful strategy that allows for the formation of a high degree of molecular complexity from relatively simple building blocks in a single step. A central feature of all light-promoted transformations is the involvement of electronically excited states, generated upon absorption of photons. This produces transient reactive intermediates and significantly alters the reactivity of a chemical compound. The input of energy provided by light thus offers a means to produce strained and unique target compounds that cannot be assembled using thermal protocols. This review aims at highlighting photochemical transformations as a tool for rapidly accessing structurally and stereochemically diverse scaffolds. Synthetic designs based on photochemical transformations have the potential to afford complex polycyclic carbon skeletons with impressive efficiency, which are of high value in total synthesis.
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Cites
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Park, H., & Poo, M.-M. (2013) · Nature Reviews Neuroscience · doi:10.1038/nrn3379 · Cited by 2,060
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Nerve Growth Factor Signaling, Neuroprotection, and Neural Repair
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Cited by
Photoredox-catalyzed deuteration and tritiation of pharmaceutical compounds
Loh, Y. Y., Nagao, K., Hoover, A. J., Hesk, D., Rivera, N. R., Colletti, S. L., Davies, I. W., & MacMillan, D. W. C. (2017) · Science · doi:10.1126/science.aap9674 · Cited by 574
Xuan, J., & Studer, A. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00912c · Cited by 482
Visible-Light-Driven Reductive Carboarylation of Styrenes with CO 2 and Aryl Halides
Wang, H., Gao, Y., Zhou, C., & Li, G. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c03144 · Cited by 303
Metadata
- Authors
- Kärkäs, M. D., Porco, J. A., & Stephenson, C. R. J.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-04-27
- Volume
- 116
- Issue
- 17
- Pages
- 9683-9747
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2342892827
- Cited by
- 1,017
- References
- 5
- FWCI
- 2.91
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Kärkäs, M. D., Porco, J. A., & Stephenson, C. R. J. (2016). Photochemical Approaches to Complex Chemotypes: Applications in Natural Product Synthesis. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.5b00760
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