The DOI matches its Crossref record; 224 of the 238 references it cites were found in a registry or an index.
Direct Capture of CO2 from Ambient Air
Open accessAbstract
The increase in the global atmospheric CO2 concentration resulting from over a century of combustion of fossil fuels has been associated with significant global climate change. With the global population increase driving continued increases in fossil fuel use, humanity’s primary reliance on fossil energy for the next several decades is assured. Traditional modes of carbon capture such as precombustion and postcombustion CO2 capture from large point sources can help slow the rate of increase of the atmospheric CO2 concentration, but only the direct removal of CO2 from the air, or “direct air capture” (DAC), can actually reduce the global atmospheric CO2 concentration. The past decade has seen a steep rise in the use of chemical sorbents that are cycled through sorption and desorption cycles for CO2 removal from ultradilute gases such as air. This Review provides a historical overview of the field of DAC, along with an exhaustive description of the use of chemical sorbents targeted at this application. Solvents and solid sorbents that interact strongly with CO2 are described, including basic solvents, supported amine and ammonium materials, and metal–organic frameworks (MOFs), as the primary classes of chemical sorbents. Hypothetical processes for the deployment of such sorbents are discussed, as well as the limited array of technoeconomic analyses published on DAC. Overall, it is concluded that there are many new materials that could play a role in emerging DAC technologies. However, these materials need to be further investigated and developed with a practical sorbent–air contacting process in mind if society is to make rapid progress in deploying DAC as a means of mitigating climate change.
Overview
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
In the citing paper
“DAC on zeolites has been studied and most of the works point at commercial and, in general, aluminosilicate zeolites not being promising adsorbents for this application due to water adsorption.534,537−539”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [534]
In the citing paper
“For gas product separation, pressure swing adsorption is an industrially used process with low operating costs, high efficiency, and limited footprint.82”
From General Techno-Economic Analysis of CO 2 Electrolysis Systems (2018) · cites this paper as [82]
Citations
Cites
Electrochemical Methods: Fundamentals and Applications
de Rooij, M. R. (2003) · Anti-Corrosion Methods and Materials · doi:10.1108/acmm.2003.12850eae.001 · Cited by 13,120
Kyoto Protocol to the United Nations Framework Convention on Climate Change
(2016) · Cambridge University Press eBooks · doi:10.1017/9781316577226.067 · Cited by 4,372
Global surface temperature change
Hansen, J., Ruedy, R., Sato, M., & Lo, K. (2010) · Reviews of Geophysics · doi:10.1029/2010rg000345 · Cited by 3,081
Water Stability and Adsorption in Metal–Organic Frameworks
Burtch, N. C., Jasuja, H., & Walton, K. S. (2014) · Chemical Reviews · doi:10.1021/cr5002589 · Cited by 2,792
Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources
Choi, S., Drese, J. H., & Jones, C. W. (2009) · ChemSusChem · doi:10.1002/cssc.200900036 · Cited by 2,602
Self-citationPorous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
Nugent, P., Belmabkhout, Y., Burd, S. D., Cairns, A., Luebke, R., Forrest, K. A., Pham, T., Ma, S., Space, B., Wojtas, Ł., et al. (2013) · Nature · doi:10.1038/nature11893 · Cited by 2,388
Post-Combustion CO 2 Capture Using Solid Sorbents: A Review
Samanta, A., Zhao, A., Shimizu, G. K. H., Sarkar, P., & Gupta, R. (2012) · Industrial & Engineering Chemistry Research · doi:10.1021/ie200686q · Cited by 1,889
Design and Preparation of Porous Polymers
Wu, D., Xu, F., Sun, B., Fu, R., He, H., & Matyjaszewski, K. A. (2012) · Chemical Reviews · doi:10.1021/cr200440z · Cited by 1,779
Separation of CO 2 from Flue Gas: A Review
Aaron, D. S., & Tsouris, C. (2005) · Separation Science and Technology · doi:10.1081/ss-200042244 · Cited by 1,529
Water adsorption in MOFs: fundamentals and applications
Canivet, J., Fateeva, A., Guo, Y., Coasne, B., & Farrusseng, D. (2014) · Chemical Society Reviews · doi:10.1039/c4cs00078a · Cited by 1,440
Flagged first, then by citations
14 of the 238 references couldn’t be matched to a known paper.
Research works printed but not linked: 18
- IPCC, 2014, Climate Change 2014: Synthesis Report. Contribution of Working Groups I, II and III to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change
- IPCC, 2013, Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change
- IPCC, 2005, Special Report on Carbon Dioxide Capture and Storage. Prepared by Working Group III of the Intergovernmental Panel on Climate Change
- Gaikwad, 2003, Wet Flue Gas Desulfurization Technology Evaluation
- Reichle, 1999, Carbon Sequestration. State of the Science
- United Nations., 2015, Adoption of the Paris Agreement, 31
- Zeman, 2004, Capturing Carbon Dioxide Directly from the Atmosphere, World Res. Rev., 16, 157
- Zeman, 2004, World Res. Rev., 16, 157
- American Physical Society., 2011, Direct Air Capture of CO2 with Chemicals: A Technology Assesment for the APS Panel on Public Affairs
- Hoddenbagh, 2002, Borate Autocausticizing: A Cost Effective Technology, Pulp Pap. Can., 103, 16
- Nikulshina, 2006, CO2 Capture from Air and Co-Production of H2 via the Ca(OH)2-CaCO3 Cycle Using Concentrated Solar Power-Thermodynamic Analysis, Energy, 31, 1715, 10.1016/j.energy.2005.09.014 · DOI
- Choi, 2009, A New Paradigm of Anthropogenic CO2 Reduction: Adsorptive Fixation of CO2 from the Ambient Air as a Carbon Negative Technology, AIChE Annual Meeting, 679e
- Kohl, 1997, Gas Purification
- Lackner, 2008, Thermodynamics of the Humidity Swing Driven Air Capture of Carbon Dioxide
- Bandi, 1995, CO2 Recycling for Hydrogen Storage and Transportation-Electrochemical CO2 Removal and Fixation, Energy Convers. Manage., 36, 899, 10.1016/0196-8904(95)00148-7 · DOI
- Zeman, F. S. An Investigation into the Feasibility of Capturing Carbon Dioxide Directly from the Atmosphere. In Proceedings of the 2nd Annual Conference on Carbon Sequestration, 2003.
- Tepe, 1943, Absorption of Carbon Dioxide by Sodium Hydroxide Solutions in a Packed Column, Trans. Am. Inst. Chem. Eng., 39, 255
- Spector, 1946, Removal of Carbon Dioxide from Atmospheric Air, Trans. Am. Inst. Chem. Eng., 42, 827
Cited by
Sorted by citations
Carbon capture and storage (CCS): the way forward
Bui, M., Adjiman, C. S., Bardow, A., Anthony, E. J., Boston, A., Brown, S., Fennell, P. S., Fuss, S., Galindo, A., Hackett, L. A., et al. (2018) · Energy & Environmental Science · doi:10.1039/c7ee02342a · Cited by 4,374
Carbon capture and conversion using metal–organic frameworks and MOF-based materials
Ding, M., Flaig, R. W., Jiang, H., & Yaghi, O. M. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00829a · Cited by 2,652
Artz, J., Müller, T. E., Thenert, K., Kleinekorte, J., Meys, R., Sternberg, A., Bardow, A., & Leitner, W. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00435 · Cited by 2,489
A Process for Capturing CO2 from the Atmosphere
Keith, D. W., Holmes, G., St. Angelo, D., & Heidel, K. (2018) · Joule · doi:10.1016/j.joule.2018.05.006 · Cited by 1,910
General Techno-Economic Analysis of CO 2 Electrolysis Systems
Jouny, M., Luc, W., & Jiao, F. (2018) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.7b03514 · Cited by 1,628
Metadata
- Authors
- Sanz-Pérez, E. S., Murdock, C. R., Didas, S. A., & Jones, C. W.
- Affiliations
- Georgia Institute of Technology , , 311 Ferst Drive , , ,
- Georgia Institute of Technology (US)
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-08-25
- Volume
- 116
- Issue
- 19
- Pages
- 11840-11876
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2508859475
- Semantic Scholar
- 1730cf009126df0e913e24859aaee075b31b6a00
- Cited by
- 2,406
- References
- 238
- Citations by year
- 2026: 325 · 2025: 350 · 2024: 335 · 2023: 281 · 2022: 263 · 2021: 257 · 2020: 223 · 2019: 158 · 2018: 119 · 2017: 87 · 2016: 7
- FWCI
- 11.84
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Chemical Reviews (publishedVersion, other-oa)
- PubMed (publishedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- Basic Energy Sciences (DE-SC0012577)
- Topics
- Physical Sciences › Chemical Engineering › Filtration and Separation › Carbon Dioxide Capture Technologies
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- direct air capture, CO2 capture, basic solvents, metal-organic frameworks, sorption-desorption cycles, climate change mitigation, techno-economic analysis
- MeSH terms
- Adsorption, Air, Alkalies, Amines, Carbon Dioxide, Coordination Complexes
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review