The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Hydrocarbon-Based Polymer Electrolyte Membranes: Importance of Morphology on Ion Transport and Membrane Stability
Abstract
A fundamental understanding of polymer microstructure is important in order to design novel polymer electrolyte membranes (PEMs) with excellent electrochemical performance and stabilities. Hydrocarbon-based polymers have distinct microstructure according to their chemical structure. The ionic clusters and/or channels play a critical role in PEMs, affecting ion conductivity and water transport, especially at medium temperature and low relative humidity (RH). In addition, physical properties such as water uptake and dimensional swelling behavior depend strongly on polymer morphology. Over the past few decades, much research has focused on the synthetic development and microstructural characterization of hydrocarbon-based PEM materials. Furthermore, blends, composites, pressing, shear field, electrical field, surface modification, and cross-linking have also been shown to be effective approaches to obtain/maintain well-defined PEM microstructure. This review summarizes recent work on developments in advanced PEMs with various chemical structures and architecture and the resulting polymer microstructures and morphologies that arise for potential application in fuel cell, lithium ion battery, redox flow battery, actuators, and electrodialysis.
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Cites
Kreuer, K.-D., Paddison, S. J., Spohr, E., & Schuster, M. (2004) · Chemical Reviews · doi:10.1021/cr020715f · Cited by 2,187
Anion-exchange membranes in electrochemical energy systems
Varcoe, J. R., Atanassov, P., Dekel, D. R., Herring, A. M., Hickner, M. A., Kohl, P. A., Kucernak, A. R., Mustain, W. E., Nijmeijer, K., Scott, K., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01303d · Cited by 2,051
Modeling Transport in Polymer-Electrolyte Fuel Cells
Weber, A. Z., & Newman, J. (2004) · Chemical Reviews · doi:10.1021/cr020729l · Cited by 738
Zhang, H., Li, X., Zhao, C., Fu, T., Shi, Y., & Na, H. (2008) · Journal of Membrane Science · doi:10.1016/j.memsci.2007.09.045 · Cited by 195
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Stability of electrocatalytic OER: from principle to application
Li, H., Lin, Y., Duan, J., Wen, Q., Liu, Y., & Zhai, T. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00010a · Cited by 540
Qu, E., Hao, X., Xiao, M., Han, D., Huang, S., Huang, Z., Wang, S., & Meng, Y. (2022) · Journal of Power Sources · doi:10.1016/j.jpowsour.2022.231386 · Cited by 363
Recent Advances on PEM Fuel Cells: From Key Materials to Membrane Electrode Assembly
Mo, S., Du, L., Huang, Z., Chen, J., Zhou, Y., Wu, P., Meng, L., Wang, N., Xing, L., Zhao, M., et al. (2023) · Electrochemical Energy Reviews · doi:10.1007/s41918-023-00190-w · Cited by 277
“These materials can be synthesized from diverse monomers via various routes to obtain a variety of structural architectures [88].”
Nguyen, H., Klose, C., Metzler, L., Vierrath, S., & Breitwieser, M. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202103559 · Cited by 133
Li, J., Cui, N., Liu, D., Zhao, Z., Yang, F., Zhong, J., & Pang, J. (2024) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2023.08.334 · Cited by 65
Metadata
- Authors
- Shin, D. W., Guiver, M. D., & Lee, Y. M.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-03-03
- Volume
- 117
- Issue
- 6
- Pages
- 4759-4805
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2591951383
- Cited by
- 989
- References
- 4
- FWCI
- 5.50
- Type
- journal article
- Language
- en
- Open access
- closed
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