The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Surface-Enhanced Infrared Spectroscopy Using Resonant Nanoantennas
Abstract
Infrared spectroscopy is a powerful tool widely used in research and industry for a label-free and unambiguous identification of molecular species. Inconveniently, its application to spectroscopic analysis of minute amounts of materials, for example, in sensing applications, is hampered by the low infrared absorption cross-sections. Surface-enhanced infrared spectroscopy using resonant metal nanoantennas, or short "resonant SEIRA", overcomes this limitation. Resonantly excited, such metal nanostructures feature collective oscillations of electrons (plasmons), providing huge electromagnetic fields on the nanometer scale. Infrared vibrations of molecules located in these fields are enhanced by orders of magnitude enabling a spectroscopic characterization with unprecedented sensitivity. In this Review, we introduce the concept of resonant SEIRA and discuss the underlying physics, particularly, the resonant coupling between molecular and antenna excitations as well as the spatial extent of the enhancement and its scaling with frequency. On the basis of these fundamentals, different routes to maximize the SEIRA enhancement are reviewed including the choice of nanostructures geometries, arrangements, and materials. Furthermore, first applications such as the detection of proteins, the monitoring of dynamic processes, and hyperspectral infrared chemical imaging are discussed, demonstrating the sensitivity and broad applicability of resonant SEIRA.
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Cites
Infrared spectroscopy of proteins
Barth, A. (2007) · Biochimica et Biophysica Acta (BBA) - Bioenergetics · doi:10.1016/j.bbabio.2007.06.004 · Cited by 5,129
Surface raman spectroelectrochemistry
Jeanmaire, D. L., & Van Duyne, R. P. (1977) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/s0022-0728(77)80224-6 · Cited by 4,738
Fourier Transform Infrared Spectrometry
Griffiths, P. R., & de Haseth, J. A. (2007) · doi:10.1002/047010631x · Cited by 3,052
Mid-infrared plasmonic biosensing with graphene
Rodrigo, D., Limaj, O., Janner, D., Etezadi, D., García de Abajo, F. J., Pruneri, V., & Altug, H. (2015) · Science · doi:10.1126/science.aab2051 · Cited by 1,462
Adato, R., & Altug, H. (2013) · Nature Communications · doi:10.1038/ncomms3154 · Cited by 406
Surface-Enhanced Infrared Spectroscopy Using Nanometer-Sized Gaps
Huck, C., Neubrech, F., Vogt, J., Toma, A., Gerbert, D., Katzmann, J., Härtling, T., & Pucci, A. (2014) · ACS Nano · doi:10.1021/nn500903v · Cited by 225
Self-citationInfrared Plasmonic Biosensor for Real-Time and Label-Free Monitoring of Lipid Membranes
Limaj, O., Etezadi, D., Wittenberg, N. J., Rodrigo, D., Yoo, D., Oh, S.-H., & Altug, H. (2016) · Nano Letters · doi:10.1021/acs.nanolett.5b05316 · Cited by 196
Cited by
Rodrigo, D., Tittl, A., Ait-Bouziad, N., John-Herpin, A., Limaj, O., Kelly, C., Yoo, D., Wittenberg, N. J., Oh, S.-H., Lashuel, H. A., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-04594-x · Cited by 269
Gas identification with graphene plasmons
Hu, H., Yang, X., Guo, X., Khaliji, K., Biswas, S. R., García de Abajo, F. J., Low, T., Sun, Z., & Dai, Q. (2019) · Nature Communications · doi:10.1038/s41467-019-09008-0 · Cited by 225
Yoo, D., Gurunatha, K. L., Choi, H.-K., Mohr, D. A., Ertsgaard, C. T., Gordon, R., & Oh, S.-H. (2018) · Nano Letters · doi:10.1021/acs.nanolett.8b00732 · Cited by 173
Zhou, H., Hui, X., Li, D., Hu, D., Chen, X., He, X., Gao, L., Huang, H., Lee, C., & Mu, X. (2020) · Advanced Science · doi:10.1002/advs.202001173 · Cited by 136
All-Dielectric Surface-Enhanced Infrared Absorption-Based Gas Sensor Using Guided Resonance
Chang, Y., Hasan, D., Dong, B., Wei, J., Ma, Y., Zhou, G., Ang, K. W., & Lee, C. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b16623 · Cited by 115
Metadata
- Authors
- Neubrech, F., Huck, C., Weber, K., Pucci, A., & Giessen, H.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-03-30
- Volume
- 117
- Issue
- 7
- Pages
- 5110-5145
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2602600633
- Cited by
- 643
- References
- 7
- FWCI
- 5.35
- Type
- journal article
- Language
- en
- Open access
- closed
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- Neubrech, F., Huck, C., Weber, K., Pucci, A., & Giessen, H. (2017). Surface-Enhanced Infrared Spectroscopy Using Resonant Nanoantennas. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.6b00743
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