Green Hydrogen Production in an Optofluidic Planar Microreactor via Photocatalytic Water Splitting under Visible/Simulated Sunlight Irradiation
Abstract
The visible light-active Pt/TiO 2 photocatalyst thin films were prepared by photo-depositing Pt onto the sol–gel TiO 2 spin-coated films. An optofluidic planar microreactor was fabricated using a Pt/TiO 2 film-coated glass substrate as the bottom plate and an uncoated glass substrate containing a planar reaction chamber as the cover plate. The Pt/TiO 2 thin films were tested for the photocatalytic water splitting activity in the presence of methanol as the sacrificial agent to produce hydrogen under visible/solar light irradiation. The effect of catalyst film thickness, reactant flow rate, light intensity, and type of light source on the rate of hydrogen production was studied. The Pt/TiO 2 film with a thickness of 1650 ± 119 nm showed a highest rate of 16.35 mmol h –1 g –1 (4.7 μmol h –1 cm –2 ) hydrogen production at an optimum reactant flow rate of 0.3 mL min –1 under visible light (400 W metal halide lamp) irradiation. The stability study carried out for four cycles of 5 h runs proved that the photocatalyst was stable and the film was well adhered to the glass substrate. A hydrogen production rate of 0.766 mmol h –1 g –1 (0.22 μmol h –1 cm –2 ) and a solar to hydrogen conversion efficiency of 0.015% were obtained under a simulated solar light irradiation of ∼100 mW cm –2 intensity, proving the solar light activity of the Pt/TiO 2 film.
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The photocatalytic aerogel achieved a hydrogen generation rate of 60.7 mmol m−2 h−1, significantly outperforming conventional thin-film photocatalytic platforms.
“As a result, the photocatalytic aerogels achieved a high hydrogen generation rate of 60.7 mmol m 2 h 1 , significantly outperforming the conventional thin-film photocatalytic platforms.”
From Gradient-structured directional porous floatable aerogels for effective solar-driven hydrogen production and steam generation (2025) · cites this paper as [58]
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Study of the feasibility of hydrogen production from heterogeneous photocatalysis: a review
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- Authors
- Rao Pala, L. P., & Peela, N. R.
- Affiliations
- Department of Chemical Engineering, Indian Institute of Technology Guwahati, Assam 781039, India
- Indian Institute of Technology Guwahati (IN)
- Corresponding author
- Peela, Nageswara Rao
- ORCID
- Peela, Nageswara Rao
- Venue
- Energy & Fuels
- Publisher
- American Chemical Society (ACS)
- Published
- 2021-11-16
- Volume
- 35
- Issue
- 23
- Pages
- 19737-19747
- ISSN
- 0887-0624 (ISSN-L)
- 1520-5029
- OpenAlex
- W3213393963
- Cited by
- 35
- References
- 74
- Citations by year
- 2026: 10 · 2025: 10 · 2024: 7 · 2023: 4 · 2022: 4
- FWCI
- 0.70
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Energy & Fuels (publishedVersion)
- Funders
- Department of Science and Technology, Ministry of Science and Technology (DST/TM/CERI/C19(G))
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › TiO2 Photocatalysis and Solar Cells
- Physical Sciences › Energy › Energy Engineering and Power Technology › Hybrid Renewable Energy Systems
- Keywords
- green hydrogen production, photocatalytic water splitting, Pt/TiO2 photocatalyst, visible light photocatalysis, simulated sunlight, methanol sacrificial agent, solar-to-hydrogen efficiency, photocatalyst stability, catalyst film thickness, reactant flow rate
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