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Membrane-Confined Iron Oxychloride Nanocatalysts for Highly Efficient Heterogeneous Fenton Water Treatment
Open accessAbstract
Abstract Heterogeneous advanced oxidation processes (AOPs) allow for the destruction of aqueous organic pollutants via oxidation by hydroxyl radicals (•OH). However, practical treatment scenarios suffer from the low availability of short-lived •OH in aqueous bulk, due to both mass transfer limitations and quenching by water constituents, such as natural organic matter (NOM). Herein, we overcome these challenges by loading iron oxychloride catalysts within the pores of a ceramic ultrafiltration membrane, resulting in an internal heterogeneous Fenton reaction that can degrade organics in complex water matrices with pH up to 6.2. With •OH confined inside the nanopores (∼ 20 nm), this membrane reactor completely removed various organic pollutants with water fluxes of up to 100 L m–2 h–1 (equivalent to a retention time of 10 s). This membrane, with a pore size that excludes NOM (>300 kDa), selectively exposed smaller organics to •OH within the pores under confinement and showed excellent resiliency to representative water matrices (simulated surface water and sand filtration effluent samples). Moreover, the membrane exhibited sustained AOPs (>24 h) and could be regenerated for multiple cycles. Our results suggest the feasibility of exploiting ultrafiltration membrane-based AOP platforms for organic pollutant degradation in complex water scenarios.
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Cites
Buxton, G. V., Greenstock, C. L., Helman, W. P., & Ross, A. B. (1988) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555805 · Cited by 12,332
Metal Sulfides as Excellent Co-catalysts for H2O2 Decomposition in Advanced Oxidation Processes
Xing, M., Xu, W., Dong, C., Bai, Y., Zeng, J., Zhou, Y., Zhang, J., & Yin, Y. (2018) · Chem · doi:10.1016/j.chempr.2018.03.002 · Cited by 1,036
Spin trapping. Kinetics of the reaction of superoxide and hydroxyl radicals with nitrones
Finkelstein, E., Rosen, G. M., & Rauckman, E. J. (1980) · Journal of the American Chemical Society · doi:10.1021/ja00535a029 · Cited by 660
Yang, X.-J., Xu, X.-M., Xu, J., & Han, Y.-F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja409130c · Cited by 647
Kinetics of Nitrate, Nitrite, and Cr(VI) Reduction by Iron Metal
Alowitz, M. J., & Scherer, M. M. (2002) · Environmental Science & Technology · doi:10.1021/es011000h · Cited by 635
Bisphenol A and Reproductive Health: Update of Experimental and Human Evidence, 2007–2013
Peretz, J., Vrooman, L., Ricke, W. A., Hunt, P. A., Ehrlich, S., Hauser, R., Padmanabhan, V., Taylor, H. S., Swan, S. H., VandeVoort, C. A., et al. (2014) · Environmental Health Perspectives · doi:10.1289/ehp.1307728 · Cited by 555
Mechanism of Heterogeneous Fenton Reaction Kinetics Enhancement under Nanoscale Spatial Confinement
Zhang, S., Sun, M., Hedtke, T., Deshmukh, A., Zhou, X., Weon, S., Elimelech, M., & Kim, J.-H. (2020) · Environmental Science & Technology · doi:10.1021/acs.est.0c02192 · Cited by 422
Self-citationMechanism of the OH Radical Generation in Photocatalysis with TiO2 of Different Crystalline Types
Zhang, J., & Nosaka, Y. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp501214m · Cited by 396
Jin, H., Tian, X., Nie, Y., Zhou, Z., Yang, C., Li, Y., & Lu, L. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.7b04503 · Cited by 336
Inhibition of Hydroxyl Radical Reaction with Aromatics by Dissolved Natural Organic Matter
Lindsey, M. E., & Tarr, M. A. (2000) · Environmental Science & Technology · doi:10.1021/es990457c · Cited by 311
Zhang, G., Gao, Y., Zhang, Y., & Guo, Y. (2010) · Environmental Science & Technology · doi:10.1021/es1011093 · Cited by 301
Jiang, W.-L., Xia, X., Han, J.-L., Ding, Y.-C., Haider, M. R., & Wang, A.-J. (2018) · Environmental Science & Technology · doi:10.1021/acs.est.8b01894 · Cited by 293
Reinventing Fenton Chemistry: Iron Oxychloride Nanosheet for pH-Insensitive H2O2 Activation
Sun, M., Chu, C., Geng, F., Lu, X., Qu, J., Crittenden, J., Elimelech, M., & Kim, J.-H. (2018) · Environmental Science & Technology Letters · doi:10.1021/acs.estlett.8b00065 · Cited by 275
Self-citationQian, X., Ren, M., Zhu, Y., Yue, D., Han, Y., Jia, J., & Zhao, Y. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.6b06429 · Cited by 272
Self-citationBio-Electro-Fenton Process Driven by Microbial Fuel Cell for Wastewater Treatment
Feng, C.-H., Li, F.-B., Mai, H.-J., & Li, X.-Z. (2010) · Environmental Science & Technology · doi:10.1021/es9032925 · Cited by 265
Du, J., Bao, J., Fu, X., Lu, C., & Kim, S. H. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2015.11.015 · Cited by 236
Feng, J., Hu, X., & Yue, P. L. (2003) · Environmental Science & Technology · doi:10.1021/es034515c · Cited by 224
The sacrificial role of graphene oxide in stabilising a Fenton-like catalyst GO–Fe3O4
Zubir, N. A., Yacou, C., Motuzas, J., Zhang, X., Zhao, X. S., & Diniz da Costa, J. C. (2015) · Chemical Communications · doi:10.1039/c5cc02292d · Cited by 211
Brame, J., Long, M., Li, Q., & Alvarez, P. (2015) · Water Research · doi:10.1016/j.watres.2015.07.044 · Cited by 193
Suspect and Nontarget Screening for Contaminants of Emerging Concern in an Urban Estuary
Tian, Z., Peter, K. T., Gipe, A. D., Zhao, H., Hou, F., Wark, D. A., Khangaonkar, T., Kolodziej, E. P., & James, C. A. (2020) · Environmental Science & Technology · doi:10.1021/acs.est.9b06126 · Cited by 192
Reactive, Self-Cleaning Ultrafiltration Membrane Functionalized with Iron Oxychloride Nanocatalysts
Sun, M., Zucker, I., Davenport, D. M., Zhou, X., Qu, J., & Elimelech, M. (2018) · Environmental Science & Technology · doi:10.1021/acs.est.8b01916 · Cited by 178
Self-citationRen, Y., Shi, M., Zhang, W., Dionysiou, D. D., Lu, J., Shan, C., Zhang, Y., Lv, L., & Pan, B. (2020) · Environmental Science & Technology · doi:10.1021/acs.est.0c00203 · Cited by 167
Gu, Y., Gong, L., Qi, J., Cai, S., Tu, W., & He, F. (2019) · Water Research · doi:10.1016/j.watres.2019.04.061 · Cited by 161
Neurological Effects of Bisphenol A and its Analogues
Inadera, H. (2015) · International Journal of Medical Sciences · doi:10.7150/ijms.13267 · Cited by 159
Zheng, J., Wang, Z., Ma, J., Xu, S., & Wu, Z. (2018) · Environmental Science & Technology · doi:10.1021/acs.est.7b06407 · Cited by 156
Wang, X., Sun, M., Zhao, Y., Wang, C., Ma, W., Wong, M. S., & Elimelech, M. (2020) · Environmental Science & Technology · doi:10.1021/acs.est.0c01590 · Cited by 152
Self-citationAlpatova, A. L., Meshref, M. N. A., McPhedran, K. N., et al. (2015) · Journal of Membrane Science · doi:10.1016/j.memsci.2015.05.001 · Cited by 119
Yu, T., Li, Q., Zhao, X., Xia, H., Ma, L., Wang, J., Meng, Y. S., & Shen, X. (2017) · ACS Energy Letters · doi:10.1021/acsenergylett.7b00699 · Cited by 118
Mixed iron oxides as Fenton catalysts for gallic acid removal from aqueous solutions
Fontecha-Cámara, M. A., Moreno‐Castilla, C., López‐Ramón, M. V., & Álvarez, M. A. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.05.032 · Cited by 109
Plakas, K. V., Mantza, A., Sklari, S. D., Zaspalis, V. T., & Karabelas, A. J. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.05.092 · Cited by 108
Lan, H., Wang, F., Lan, M., An, X., Liu, H., & Qu, J. (2019) · Environmental Science & Technology · doi:10.1021/acs.est.9b00790 · Cited by 107
Açışlı, Ö., Khataee, A., Soltani, R. D. C., & Karaca, S. (2016) · Ultrasonics Sonochemistry · doi:10.1016/j.ultsonch.2016.09.020 · Cited by 102
Oxidative Degradation of Nalidixic Acid by Nano-magnetite via Fe 2+ /O 2 -Mediated Reactions
Ardo, S., Nélieu, S., Ona-Nguéma, G., Delarue, G., Brest, J., Pironin, E., & Morin, G. (2015) · Environmental Science & Technology · doi:10.1021/es505649d · Cited by 89
Yang, X., Tian, P., Zhang, X. H., Yu, X. P., Wu, T., Xu, J. M., & Yi-fan, H. (2014) · AIChE Journal · doi:10.1002/aic.14625 · Cited by 79
Zhang, L., Liu, Z., Faraj, Y., Zhao, Y., Zhuang, R., Xie, R., Ju, X., Wang, W., & Chu, L. (2018) · Journal of Membrane Science · doi:10.1016/j.memsci.2018.12.032 · Cited by 72
Self-citationJarrige, I., Cai, Y. Q., Shieh, S. R., Ishii, H., Hiraoka, N., Karna, S., & Li, W.-H. (2010) · Physical Review B · doi:10.1103/physrevb.82.165121 · Cited by 42
Ji, X.-X., Wang, H., & Hu, P. (2018) · Rare Metals · doi:10.1007/s12598-018-1140-9 · Cited by 31
Zhang, S., Quan, X., & Wang, D. (2017) · Chemical Communications · doi:10.1039/c6cc09536d · Cited by 27
Self-citationTotal alkalinity of surface waters: a map of the upper midwest region of the United States
Omernik, J. M., & Griffith, G. E. (1986) · Environmental Management · doi:10.1007/bf01867735 · Cited by 14
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Meng, C., Ding, B., Zhang, S., Cui, L., Ostrikov, K. K., Huang, Z., Yang, B., Kim, J.-H., & Zhang, Z. (2022) · Nature Communications · doi:10.1038/s41467-022-31807-1 · Cited by 371
Self-citation
Metadata
- Authors
- Zhang, S., Hedtke, T., Zhu, Q., Sun, M., Weon, S., Zhao, Y., Stavitski, E., Elimelech, M., & Kim, J.-H.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2021-06-21
- Volume
- 55
- Issue
- 13
- Pages
- 9266-9275
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W3176776530
- Cited by
- 316
- References
- 40
- FWCI
- 13.65
- Type
- journal article
- Language
- en
- Open access
- green
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