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Neutral Poly/Per-Fluoroalkyl Substances in Air from the Atlantic to the Southern Ocean and in Antarctic Snow
Abstract
The oceanic scale occurrences of typical neutral poly/per-fluoroalkyl substances (PFASs) in the atmosphere across the Atlantic, as well as their air-snow exchange at the Antarctic Peninsula, were investigated. Total concentrations of the 12 PFASs (∑PFASs) in gas phase ranged from 2.8 to 68.8 pg m(-3) (mean: 23.5 pg m(-3)), and the levels in snow were from 125 to 303 pg L(-1) (mean: 209 pg L(-1)). Fluorotelomer alcohols (FTOHs) were dominant in both air and snow. The differences of specific compounds to ∑PFASs were not significant between air and snow. ∑PFASs were higher above the northern Atlantic compared to the southern Atlantic, and the levels above the southern Atlantic <30°S was the lowest. High atmospheric PFAS levels around the Antarctic Peninsula were the results of a combination of air mass, weak elimination processes and air-snow exchange of PFASs. Higher ratios of 8:2 to 10:2 to 6:2 FTOH were observed in the southern hemisphere, especially around the Antarctic Peninsula, suggesting that PFASs in the region were mainly from the long-range atmospheric transport. No obvious decrease of PFASs was observed in the background marine atmosphere after 2005.
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Solute descriptors are unavailable for other PFAS, including frequently detected fluorotelomer compounds and perfluoroalkanesulfonamides (PFASAs) with different substitution patterns.
“Solute descriptors are unavailable for other PFAS, including those that have been frequently detected in the environment such as other fluorotelomer compounds and perfluoroalkanesulfonamides (PFASAs) with different substitution patterns.15−17”
From Intermolecular Interactions, Solute Descriptors, and Partition Properties of Neutral Per- and Polyfluoroalkyl Substances (PFAS) (2023) · cites this paper as [15]
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Metadata
- Authors
- Wang, Z., Xie, Z., Mi, W., Möller, A., Wolschke, H., & Ebinghaus, R.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-06-15
- Volume
- 49
- Issue
- 13
- Pages
- 7770-7775
- ISSN
- 0013-936X
- 1520-5851
- Cited by
- 105
- References
- 6
- Language
- en
- Funders
- China Scholarship Council
- National Natural Science Foundation of China
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