The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
The Interfacial Behavior between Biochar and Soil Minerals and Its Effect on Biochar Stability
Abstract
In this study, FeCl3, AlCl3, CaCl2, and kaolinite were selected as model soil minerals and incubated with walnut shell derived biochar for 3 months and the incubated biochar was then separated for the investigation of biochar-mineral interfacial behavior using XRD and SEM-EDS. The XPS, TGA, and H2O2 oxidation were applied to evaluate effects of the interaction on the stability of biochar. Fe8O8(OH)8Cl1.35 and AlCl3·6H2O were newly formed on the biochar surface or inside of the biochar pores. At the biochar-mineral interface, organometallic complexes such as Fe-O-C were generated. All the 4 minerals enhanced the oxidation resistance of biochar surface by decreasing the relative contents of C-O, C═O, and COOH from 36.3% to 16.6-26.5%. Oxidation resistance of entire biochar particles was greatly increased with C losses in H2O2 oxidation decreasing by 13.4-79.6%, and the C recalcitrance index (R50,bicohar) in TGA analysis increasing from 44.6% to 45.9-49.6%. Enhanced oxidation resistance of biochar surface was likely due to the physical isolation from newly formed minerals, while organometallic complex formation was probably responsible for the increase in oxidation resistance of entire biochar particles. Results indicated that mineral-rich soils seemed to be a beneficial environment for biochar since soil minerals could increase biochar stability, which displays an important environmental significance of biochar for long-term carbon sequestration.
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Cites
Organic matter and water-stable aggregates in soils
TISDALL, J. M., & OADES, J. M. (1982) · Journal of Soil Science · doi:10.1111/j.1365-2389.1982.tb01755.x · Cited by 6,267
Lehmann, J. (2007) · Nature · doi:10.1038/447143a · Cited by 2,477
Black Carbon Increases Cation Exchange Capacity in Soils
Liang, B., Lehmann, J., Solomon, D., Kinyangi, J., Grossman, J., O'Neill, B., Skjemstad, J. O., Thies, J., Luizão, F. J., Petersen, J., et al. (2006) · Soil Science Society of America Journal · doi:10.2136/sssaj2005.0383 · Cited by 2,191
Beesley, L., Moreno-Jiménez, E., Gomez-Eyles, J. L., Harris, E., Robinson, B., & Sizmur, T. (2011) · Environmental Pollution · doi:10.1016/j.envpol.2011.07.023 · Cited by 1,610
An investigation into the reactions of biochar in soil
Joseph, S. D., Camps-Arbestain, M., Lin, Y., Munroe, P., Chia, C. H., Hook, J., van Zwieten, L., Kimber, S., Cowie, A., Singh, B. P., et al. (2010) · Soil Research · doi:10.1071/sr10009 · Cited by 1,111
Harvey, O. R., Kuo, L.-J., Zimmerman, A. R., Louchouarn, P., Amonette, J. E., & Herbert, B. E. (2012) · Environmental Science & Technology · doi:10.1021/es2040398 · Cited by 429
A method for screening the relative long‐term stability of biochar
Cross, A., & Sohi, S. P. (2013) · GCB Bioenergy · doi:10.1111/gcbb.12035 · Cited by 247
Cited by
Zhu, S., Huang, X., Ma, F., Wang, L., Duan, X., & Wang, S. (2018) · Environmental Science & Technology · doi:10.1021/acs.est.8b01817 · Cited by 1,179
Wang, L., O’Connor, D., Rinklebe, J., Ok, Y. S., Tsang, D. C. W., Shen, Z., & Hou, D. (2020) · Environmental Science & Technology · doi:10.1021/acs.est.0c04033 · Cited by 655
Lian, F., & Xing, B. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.7b02528 · Cited by 641
An overview of the effect of pyrolysis process parameters on biochar stability
Leng, L., & Huang, H. (2018) · Bioresource Technology · doi:10.1016/j.biortech.2018.09.030 · Cited by 503
Sun, Y., Yu, I. K. M., Tsang, D. C. W., Cao, X., Lin, D., Wang, L., Graham, N. J. D., Alessi, D. S., Komárek, M., Ok, Y. S., et al. (2019) · Environment International · doi:10.1016/j.envint.2019.01.047 · Cited by 489
Self-citation
Metadata
- Authors
- Yang, F., Zhao, L., Gao, B., Xu, X., & Cao, X.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-02-18
- Volume
- 50
- Issue
- 5
- Pages
- 2264-2271
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2256602519
- Cited by
- 397
- References
- 7
- FWCI
- 37.66
- Type
- journal article
- Language
- en
- Open access
- closed
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