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Exploring the Role of Persulfate in the Activation Process: Radical Precursor Versus Electron Acceptor
Abstract
This study elucidates the mechanism behind persulfate activation by exploring the role of various oxyanions (e.g., peroxymonosulfate, periodate, and peracetate) in two activation systems utilizing iron nanoparticle (nFe 0 ) as the reducing agent and single-wall carbon nanotubes (CNTs) as electron transfer mediators. Since the tested oxyanions serve as both electron acceptors and radical precursors in most cases, oxidative degradation of organics was achievable through one-electron reduction of oxyanions on nFe 0 (leading to radical-induced oxidation) and electron transfer mediation from organics to oxyanions on CNTs (leading to oxidative decomposition involving no radical formation). A distinction between degradative reaction mechanisms of the nFe 0 /oxyanion and CNT/oxyanion systems was made in terms of the oxyanion consumption efficacy, radical scavenging effect, and EPR spectral analysis. Statistical study of substrate-specificity and product distribution implied that the reaction route induced on nFe 0 varies depending on the oxyanion (i.e., oxyanion-derived radical), whereas the similar reaction pathway initiates organic oxidation in the CNT/oxyanion system irrespective of the oxyanion type. Chronoamperometric measurements further confirmed electron transfer from organics to oxyanions in the presence of CNTs, which was not observed when applying nFe 0 instead.
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Cites
Buxton, G. V., Greenstock, C. L., Helman, W. P., & Ross, A. B. (1988) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555805 · Cited by 12,332
Rate Constants for Reactions of Inorganic Radicals in Aqueous Solution
Neta, P., Huie, R. E., & Ross, A. B. (1988) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555808 · Cited by 3,651
Perspectives on Carbon Nanotubes and Graphene Raman Spectroscopy
Dresselhaus, M. S., Jorio, A., Hofmann, M., Dresselhaus, G., & Saito, R. (2010) · Nano Letters · doi:10.1021/nl904286r · Cited by 3,254
Oh, W.-D., Dong, Z., & Lim, T.-T. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.04.003 · Cited by 2,612
A review of classic Fenton’s peroxidation as an advanced oxidation technique
Neyens, E., & Baeyens, J. (2003) · Journal of Hazardous Materials · doi:10.1016/s0304-3894(02)00282-0 · Cited by 2,438
Standard Potentials in Aqueous Solution.
Trasatti, S. (1987) · Bioelectrochemistry and Bioenergetics · doi:10.1016/0302-4598(87)80040-5 · Cited by 1,633
A rapid spectrophotometric determination of persulfate anion in ISCO
Liang, C., Huang, C.-F., Mohanty, N., & Kurakalva, R. M. (2008) · Chemosphere · doi:10.1016/j.chemosphere.2008.08.043 · Cited by 1,456
Influence of pH on the Formation of Sulfate and Hydroxyl Radicals in the UV/Peroxymonosulfate System
Guan, Y.-H., Ma, J., Li, X.-C., Fang, J.-Y., & Chen, L.-W. (2011) · Environmental Science & Technology · doi:10.1021/es2017363 · Cited by 1,338
Rastogi, A., Al-Abed, S. R., & Dionysiou, D. D. (2009) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2008.07.010 · Cited by 1,112
Non-photochemical production of singlet oxygen via activation of persulfate by carbon nanotubes
Cheng, X., Guo, H., Zhang, Y., Wu, X., & Liu, Y. (2017) · Water Research · doi:10.1016/j.watres.2017.02.016 · Cited by 1,065
Yang, Y., Pignatello, J. J., Ma, J., & Mitch, W. A. (2014) · Environmental Science & Technology · doi:10.1021/es404118q · Cited by 1,049
Anipsitakis, G. P., Dionysiou, D. D., & Gonzalez, M. A. (2006) · Environmental Science & Technology · doi:10.1021/es050634b · Cited by 910
Insights into Heterogeneous Catalysis of Persulfate Activation on Dimensional-Structured Nanocarbons
Duan, X., Sun, H., Kang, J., Wang, Y., Indrawirawan, S., & Wang, S. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00774 · Cited by 799
Zhang, T., Chen, Y., Wang, Y., Le Roux, J., Yang, Y., & Croué, J.-P. (2014) · Environmental Science & Technology · doi:10.1021/es501218f · Cited by 798
Bactericidal Effect of Zero-Valent Iron Nanoparticles on Escherichia coli
Lee, C., Kim, J. Y., Lee, W. I., Nelson, K. L., Yoon, J., & Sedlak, D. L. (2008) · Environmental Science & Technology · doi:10.1021/es800408u · Cited by 766
Activation of Persulfates by Graphitized Nanodiamonds for Removal of Organic Compounds
Lee, H., Kim, H.-I., Weon, S., Choi, W., Hwang, Y. S., Seo, J., Lee, C., & Kim, J.-H. (2016) · Environmental Science & Technology · doi:10.1021/acs.est.6b02079 · Cited by 688
Self-citationLee, H., Lee, H.-J., Jeong, J., Lee, J., Park, N.-B., & Lee, C. (2015) · Chemical Engineering Journal · doi:10.1016/j.cej.2014.12.065 · Cited by 671
Self-citationRaman and IR Spectroscopy of Chemically Processed Single-Walled Carbon Nanotubes
Kim, U. J., Furtado, C. A., Liu, X., Chen, G., & Eklund, P. C. (2005) · Journal of the American Chemical Society · doi:10.1021/ja052951o · Cited by 567
Ji, Y., Dong, C., Kong, D., Lu, J., & Zhou, Q. (2015) · Chemical Engineering Journal · doi:10.1016/j.cej.2014.10.097 · Cited by 552
Haag, W. R., & Hoigne, J. (1986) · Environmental Science & Technology · doi:10.1021/es00146a005 · Cited by 538
Heterogeneous Activation of Oxone Using Co3O4
Anipsitakis, G. P., Stathatos, E., & Dionysiou, D. D. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp052166y · Cited by 518
Liang, P., Zhang, C., Duan, X., Sun, H., Liu, S., Tade, M. O., & Wang, S. (2017) · Environmental Science: Nano · doi:10.1039/c6en00633g · Cited by 466
Chan, K. H., & Chu, W. (2009) · Water Research · doi:10.1016/j.watres.2009.02.029 · Cited by 463
Sun, L., & Bolton, J. R. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp9505800 · Cited by 416
Wang, Y., Sun, H., Ang, H. M., Tadé, M. O., & Wang, S. (2015) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2014.09.004 · Cited by 400
A Silica-Supported Iron Oxide Catalyst Capable of Activating Hydrogen Peroxide at Neutral pH Values
Pham, A. L.-T., Lee, C., Doyle, F. M., & Sedlak, D. L. (2009) · Environmental Science & Technology · doi:10.1021/es902296k · Cited by 364
Ahn, Y.-Y., Yun, E.-T., Seo, J.-W., Lee, C., Kim, S. H., Kim, J.-H., & Lee, J. (2016) · Environmental Science & Technology · doi:10.1021/acs.est.6b02841 · Cited by 321
Self-citationEfficient activation of peroxymonosulfate by magnetic Mn-MGO for degradation of bisphenol A
Du, J., Bao, J., Liu, Y., Ling, H., Zheng, H., Kim, S. H., & Dionysiou, D. D. (2016) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2016.08.021 · Cited by 290
Efficient removal of endosulfan from aqueous solution by UV-C/peroxides: A comparative study
Shah, N. S., He, X., Khan, H. M., Khan, J. A., O'Shea, K. E., Boccelli, D. L., & Dionysiou, D. D. (2013) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2013.10.019 · Cited by 260
Stefan, M. I., & Bolton, J. R. (1998) · Environmental Science & Technology · doi:10.1021/es970633m · Cited by 253
Intermediates and Reaction Pathways from the Degradation of Microcystin-LR with Sulfate Radicals
Antoniou, M. G., de la Cruz, A. A., & Dionysiou, D. D. (2010) · Environmental Science & Technology · doi:10.1021/es1000243 · Cited by 225
Oxidizing Capacity of Periodate Activated with Iron-Based Bimetallic Nanoparticles
Lee, H., Yoo, H.-Y., Choi, J., Nam, I.-H., Lee, S., Lee, S., Kim, J., Lee, C., & Lee, J. (2014) · Environmental Science & Technology · doi:10.1021/es5002902 · Cited by 219
Self-citationMunicipal-Treated Wastewater Reuse for Plant Nurseries Irrigation
Lubello, C., Gori, R., Nicese, F. P., & Ferrini, F. (2004) · Water Research · doi:10.1016/j.watres.2004.03.037 · Cited by 194
Ferrous-activated persulfate oxidation of arsenic(III) and diuron in aquatic system
Zhou, L., Zheng, W., Ji, Y., Zhang, J., Zeng, C., Zhang, Y., Wang, Q., & Yang, X. (2013) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2013.09.056 · Cited by 187
Rokhina, E. V., Makarova, K., Golovina, E., As, H. V., & Virkutyte, J. (2010) · Environmental Science and Technology · doi:10.1021/es1009136 · Cited by 155
Lee, C., & Yoon, J. (2004) · Journal of Photochemistry and Photobiology A Chemistry · doi:10.1016/j.jphotochem.2004.02.018 · Cited by 142
Eibenberger, H., Steenken, S., O’Neill, P., et al. (1978) · The Journal of Physical Chemistry · doi:10.1021/j100495a028 · Cited by 137
Lee, J., Hong, S. W., Mackeyev, Y., Lee, C., Chung, E., Wilson, L. J., Kim, J., & Alvarez, P. J. J. (2011) · Environmental Science & Technology · doi:10.1021/es2029944 · Cited by 119
Self-citationWeavers, L. K., Hua, I., & Hoffmann, M. R. (1997) · Water Environment Research · doi:10.2175/106143097x125849 · Cited by 113
Effects of inorganic oxidants on kinetics and mechanisms of WO3-mediated photocatalytic degradation
Kim, H., Yoo, H.-Y., Hong, S. W., Lee, S., Lee, S., Park, B.-S., Park, H., Lee, C., & Lee, J. (2014) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2014.07.019 · Cited by 107
Self-citationHaque, M. M., Muneer, M., & Bahnemann, D. W. (2006) · Environmental Science & Technology · doi:10.1021/es060051h · Cited by 83
Kim, H., Lee, H., Kim, H.-E., Seo, J., Hong, S. W., Lee, J., & Lee, C. (2015) · Water Research · doi:10.1016/j.watres.2015.06.016 · Cited by 73
Self-citationSteele, W. V., & Appelman, E. H. (1982) · The Journal of Chemical Thermodynamics · doi:10.1016/0021-9614(82)90052-0 · Cited by 68
Oxidation of bisphenol A by UV/S2O : Comparison with UV/H2O2
Yoon, S. H., Jeong, S., & Lee, S. (2011) · Environmental Technology · doi:10.1080/09593330.2011.579181 · Cited by 39
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Wang, J., & Wang, S. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.126158 · Cited by 1,585
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Duan, X., Sun, H., & Wang, S. (2018) · Accounts of Chemical Research · doi:10.1021/acs.accounts.7b00535 · Cited by 1,329
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Self-citationTang, L., Liu, Y., Wang, J., Zeng, G., Deng, Y., Dong, H., Feng, H., Wang, J., & Peng, B. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.02.059 · Cited by 827
Metadata
- Authors
- Yun, E.-T., Yoo, H.-Y., Bae, H., Kim, H.-I., & Lee, J.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-08-16
- Volume
- 51
- Issue
- 17
- Pages
- 10090-10099
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2739613792
- Cited by
- 359
- References
- 44
- FWCI
- 14.48
- Type
- journal article
- Language
- en
- Open access
- closed
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