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A review of classic Fenton’s peroxidation as an advanced oxidation technique

Neyens, E., Baeyens, J.·2003·Journal of Hazardous Materials
DOI 10.1016/s0304-3894(02)00282-0
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Abstract

Hydrogen peroxide (H(2)O(2)) is a strong oxidant and its application in the treatment of various inorganic and organic pollutants is well established. Still H(2)O(2) alone is not effective for high concentrations of certain refractory contaminants because of low rates of reaction at reasonable H(2)O(2) concentrations. Improvements can be achieved by using transition metal salts (e.g. iron salts) or ozone and UV-light can activate H(2)O(2) to form hydroxyl radicals, which are strong oxidants. Oxidation processes utilising activation of H(2)O(2) by iron salts, classically referred to as Fenton's reagent is known to be very effective in the destruction of many hazardous organic pollutants in water. The first part of our paper presents a literature review of the various Fenton reagent reactions which constitute the overall kinetic scheme with all possible side reactions. It also summarises previous publications on the relationships between the dominant parameters (e.g. [H(2)O(2)], [Fe(2+)], . . .). The second part of our review discusses the possibility of improving sludge dewaterability using Fenton's reagent.

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Crossref · 10.1016/s0304-3894(02)00282-0

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Citations

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Research works printed but not linked: 27

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  3. Huang, 1993, Advanced chemical oxidation: its present role and potential future in hazardous waste treatment, Waste Mgmt., 13, 361, 10.1016/0956-053X(93)90070-D · DOI
  4. Kitis, 1999, The effects of Fenton’s reagent pretreatment on the biodegradability of non-ionic surfactants, Wat. Res., 33, 2561, 10.1016/S0043-1354(98)00476-X · DOI
  5. Yoon, 2001, Investigation of the reaction pathway of OH radicals produced by Fenton oxidation in the conditions of wastewater treatment, Wat. Sci. Technol., 44, 15, 10.2166/wst.2001.0242 · DOI
  6. Lu, 2001, Influence of pH on the dewatering of activated sludge by Fenton’s reagent, Wat. Sci. Technol., 44, 327, 10.2166/wst.2001.0654 · DOI
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  24. Pere, 1993, Characterisation and dewatering of activated sludge from the pulp and paper industry, Water Sci. Technol., 28, 193, 10.2166/wst.1993.0046 · DOI
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  26. V.L. Snoeyink, D. Jenkins, Water Chemistry, Wiley, New York, 1982.
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Metadata

Authors
Neyens, E., & Baeyens, J.
Venue
Journal of Hazardous Materials
Publisher
Elsevier BV
Published
2003-03
Volume
98
Issue
1-3
Pages
33-50
ISSN
0304-3894
DOI
10.1016/s0304-3894(02)00282-0
Cited by
2,438
References
4
Language
en
Licence
www.elsevier.com/tdm/userlicense/1.0/ (tdm)

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CoChat. (2026). Citation check: A review of classic Fenton’s peroxidation as an advanced oxidation technique. https://app.cochat.ai/papers/10.1016/s0304-3894(02)00282-0
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Neyens, E., & Baeyens, J. (2003). A review of classic Fenton’s peroxidation as an advanced oxidation technique. Journal of Hazardous Materials. https://doi.org/10.1016/s0304-3894(02)00282-0