The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Energy-Efficient Electrochemical Oxidation of Perfluoroalkyl Substances Using a Ti4O7 Reactive Electrochemical Membrane Anode
Abstract
An energy-efficient Magnéli phase Ti 4 O 7 reactive electrochemical membrane (REM) was applied for the oxidation of perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS). Approximately 5-log removal of these compounds was achieved in a single pass through the REM with residence times of ∼11 s at 3.3 V/SHE for PFOA and 3.6 V/SHE for PFOS. The permeate concentrations of PFOA and PFOS were <86 and 35 ng L –1, from initial concentrations of 4.14 and 5 mg L –1, respectively. The highest removal rates were 3415 ± 203 μmol m –2 h –1 for PFOA and 2436 ± 106 μmol m –2 h –1 for PFOS at a permeate flux of 720 L m –2 h –1 (residence times of ∼3.8 s). The levels of energy consumption (per log removal) to remove PFOA and PFOS to below the detection limits were 5.1 and 6.7 kWh m –3, respectively. These values are the lowest reported for electrochemical oxidation and approximately an order of magnitude lower than those reported for other technologies (i.e., ultrasonication, photocatalysis, vacuum ultraviolet photolysis, and microwave–hydrothermal decomposition), demonstrating the promise of the REM technology for water treatment applications.
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Cites
Novel treatment technologies for PFAS compounds: A critical review
Kucharzyk, K. H., Darlington, R., Benotti, M., Deeb, R., & Hawley, E. (2017) · Journal of Environmental Management · doi:10.1016/j.jenvman.2017.08.016 · Cited by 562
Trojanowicz, M., Bojanowska-Czajka, A., Bartosiewicz, I., & Kulisa, K. (2018) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.10.153 · Cited by 550
Review of the fate and transformation of per- and polyfluoroalkyl substances (PFASs) in landfills
Hamid, H., Li, L. Y., & Grace, J. R. (2018) · Environmental Pollution · doi:10.1016/j.envpol.2017.12.030 · Cited by 343
Post, G. B., Louis, J. B., Cooper, K. R., Boros-Russo, B. J., & Lippincott, R. L. (2009) · Environmental Science & Technology · doi:10.1021/es900301s · Cited by 155
Cited by
MOF based engineered materials in water remediation: Recent trends
Rego, R. M., Kuriya, G., Kurkuri, M. D., & Kigga, M. (2021) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2020.123605 · Cited by 384
Hydroxyl radicals in anodic oxidation systems: generation, identification and quantification
Xie, J., Zhang, C., & Waite, T. D. (2022) · Water Research · doi:10.1016/j.watres.2022.118425 · Cited by 303
Radjenovic, J., Duinslaeger, N., Avval, S. S., & Chaplin, B. P. (2020) · Environmental Science & Technology · doi:10.1021/acs.est.0c06212 · Cited by 268
Self-citationO’Connor, J., Bolan, N. S., Kumar, M., Nitai, A. S., Ahmed, M. B., Bolan, S. S., Vithanage, M., Rinklebe, J., Mukhopadhyay, R., Srivastava, P., et al. (2022) · Process Safety and Environmental Protection · doi:10.1016/j.psep.2022.06.002 · Cited by 183
Veciana, M., Bräunig, J., Farhat, A., Pype, M.-L., Freguia, S., Carvalho, G., Keller, J., & Ledezma, P. (2022) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2022.128886 · Cited by 148
Metadata
- Authors
- Le, T. X. H., Haflich, H., Shah, A. D., & Chaplin, B. P.
- Venue
- Environmental Science & Technology Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-07-24
- Volume
- 6
- Issue
- 8
- Pages
- 504-510
- ISSN
- 2328-8930 (ISSN-L)
- OpenAlex
- W2962744115
- Cited by
- 297
- References
- 4
- FWCI
- 12.63
- Type
- journal article
- Language
- en
- Open access
- closed
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- Le, T. X. H., Haflich, H., Shah, A. D., & Chaplin, B. P. (2019). Energy-Efficient Electrochemical Oxidation of Perfluoroalkyl Substances Using a Ti4O7 Reactive Electrochemical Membrane Anode. Environmental Science & Technology Letters. https://doi.org/10.1021/acs.estlett.9b00397
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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