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Tuning the Kinetic Water Stability and Adsorption Interactions of Mg-MOF-74 by Partial Substitution with Co or Ni
Open accessAbstract
Varying amounts of Co and Ni were substituted into the metal–organic framework Mg-MOF-74 via a one-pot solvothermal reaction, and the effects of these substitutions on CO 2 adsorption and kinetic water stability properties were examined. Based on elemental analyses, Co and Ni are more favorably incorporated into the MOF-74 framework from solution than Mg. In addition, reaction temperature more strongly impacts the final metal composition in these mixed-metal (MM) MOF-74 structures than does the reaction solvent composition. Single-component CO 2 adsorption isotherms were measured for the MM-MOF-74 systems at 5, 25, and 45 °C, and isosteric heats of adsorption were calculated. These results suggest that CO 2 adsorption properties can be adjusted by partial metal substitution. Water adsorption isotherms were also measured for the MM-MOF-74 samples, with powder X-ray diffraction patterns and Brunauer–Emmett–Teller surface areas measured both before and after water exposure. Results show that Mg-MOF-74 can gain partial kinetic water stability by the incorporation of Ni 2+ or Co 2+ metal ions that are less vulnerable to hydrolysis than Mg 2+ . Of particular note, Mg–Ni-MM-MOF-74 shows a significant increase in water stability when incorporating as little as 16 mol % Ni into the Mg-MOF-74 structure.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
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Younas, M., Rezakazemi, M., Daud, M., Wazir, M. B., Ahmad, S., Ullah, N., Inamuddin, & Ramakrishna, S. (2020) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2020.100849 · Cited by 421
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Metadata
- Authors
- Jiao, Y., Morelock, C. R., Burtch, N. C., Mounfield, W. P., Hungerford, J. T., & Walton, K. S.
- Venue
- Industrial & Engineering Chemistry Research
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-12-02
- Volume
- 54
- Issue
- 49
- Pages
- 12408-12414
- ISSN
- 0888-5885 (ISSN-L)
- 1520-5045
- OpenAlex
- W2501797864
- Cited by
- 208
- References
- 1
- FWCI
- 6.13
- Type
- journal article
- Language
- en
- Open access
- green
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- Jiao, Y., Morelock, C. R., Burtch, N. C., Mounfield, W. P., Hungerford, J. T., & Walton, K. S. (2015). Tuning the Kinetic Water Stability and Adsorption Interactions of Mg-MOF-74 by Partial Substitution with Co or Ni. Industrial & Engineering Chemistry Research. https://doi.org/10.1021/acs.iecr.5b03843
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