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Chemistry and Mass Density of Aluminum Hydroxide Gel in Eco-Cements by Ptychographic X-ray Computed Tomography
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Eco-cements are a desirable alternative to ordinary Portland cements because of their lower CO 2 footprints. Some ye’elimite-based eco-cements are attracting a lot of interest. Understanding the reasons for the mechanical performances requires the characterization of features such as mass density of the hydrated component phases, including the amorphous gel, on the submicrometer scale, which is challenging. Here we use ptychographic X-ray computed tomography to provide 3D mass density and attenuation coefficient distributions of eco-cement pastes with an isotropic resolution close to 100 nm allowing to distinguish between component phases with very similar contrast. In combination with laboratory techniques such as the Rietveld method, 27 Al MAS NMR, and electron microscopies, we report compositions and densities of key components. The ettringite and gel volume distributions have been mapped out in the segmented tomograms. Moreover, we discriminate between an aluminum hydroxide gel and calcium aluminum monosulfate, which have close electron density values. Specifically, the composition and mass density of two aluminum hydroxide gel agglomerates have been determined: (CaO) 0.04 Al(OH) 3 ·2.3H 2 O with 1.48(3) g·cm –3 and (CaO) 0.12 Al(OH) 3 with 2.05(3) g·cm –3, which was a long-standing challenge.
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The smaller carbonate weight loss in Y-A_carb points towards partial presence of calcium within the Al(OH)3 gel.
“pointing towards partial presence of calcium within the Al(OH) 3 gel as previously reported [57].”
From X-ray Total Scattering Study of Phases Formed from Cement Phases Carbonation (2021) · cites this paper as [57]
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Metadata
- Authors
- Cuesta, A., De la Torre, A. G., Santacruz, I., Trtik, P., da Silva, J. C., Diaz, A., Holler, M., & Aranda, M. A. G.
- Affiliations
- ALBA Synchrotron (Spain) (ES)
- Departamento de Química Inorgánica, Cristalografía y Mineralogía, Universidad de Málaga, 29071-Málaga, Spain
- Universidad de Málaga (ES)
- Paul Scherrer Institute (CH)
- Paul Scherrer Institut, Villigen PSI 5232, Switzerland
- ALBA Synchrotron, Carrer de la Llum 2-26, E-08290 Cerdanyola del Vallès, Barcelona, Spain
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-02-01
- Volume
- 121
- Issue
- 5
- Pages
- 3044-3054
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2572522967
- Cited by
- 55
- References
- 51
- Citations by year
- 2026: 4 · 2025: 7 · 2024: 3 · 2023: 3 · 2022: 2 · 2021: 9 · 2020: 5 · 2019: 9 · 2018: 9 · 2017: 4
- FWCI
- 7.73
- Type
- journal article
- Language
- en
- Open access
- green
- hal.science
- Licence
- other-oa
- Locations
- The Journal of Physical Chemistry C (publishedVersion)
- HAL (acceptedVersion, other-oa)
- DORA PSI (Paul Scherrer Institute) (submittedVersion, other-oa)
- LA Referencia (Red Federada de Repositorios Institucionales de Publicaciones Científicas) (submittedVersion, other-oa)
- Repositorio Institucional de la Universidad de Málaga (University of Málaga) (submittedVersion)
- Funders
- Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung (137772)
- European Regional Development Fund (BIA2014-57658-C2-1-R, BIA2014-57658-C2-2-R)
- Ministerio de Economía y Competitividad (BIA2014-57658-C2-1-R, BIA2014-57658-C2-2-R)
- Topics
- Physical Sciences › Engineering › Civil and Structural Engineering › Concrete and Cement Materials Research
- Physical Sciences › Physics and Astronomy › Radiation › Advanced X-ray Imaging Techniques
- Physical Sciences › Materials Science › Materials Chemistry › Magnesium Oxide Properties and Applications
- Keywords
- aluminum hydroxide gel, eco-cement, ye'elimite, ptychographic X-ray computed tomography, mass density, ettringite, amorphous gel, carbon footprint, 27Al MAS NMR, Rietveld refinement
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