Solid-Liquid Interface Structure of Muscovite Mica in CsCl and RbBr Solutions
Open accessAbstract
The solid–liquid interface formed by single terminated muscovite mica in contact with two different ionic solutions is analyzed using surface X-ray diffraction. Specular and nonspecular crystal truncation rods of freshly cleaved mica immersed in CsCl or RbBr aqueous solution were measured. The half monolayer of the surface potassium ions present after the cleavage is completely replaced by the positive ions (Cs + or Rb + ) from the solution. These ions are located in the ditrigonal surface cavities with small outward relaxations with respect to the bulk potassium position. We find evidence for the presence of a partly ordered hydration shell around the surface Cs + or Rb + ions and partly ordered negative ions in the solution. The lateral liquid ordering induced by the crystalline surface vanishes at distances larger than 5 Å from the surface.
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The presence of a specific anion at the interface can influence the coverage of cations on the negatively charged surface.
“The presence of a specific anion at the interface can influence the coverage of cations on the negatively charged surface [39,40].”
From Effect of Hofmeister Anions on Interfacial Properties of Mica Surface in Concentrated Aqueous Solution (2020) · cites this paper as [39]
X-ray photoelectron spectroscopy and X-ray diffraction experiments have provided evidence that monovalent anions at water/mica interface share hydration shells with innermost cations.
“X-ray photoelectron spectroscopy and X-ray di raction experiments have provided the evidence on monovalent anions at the water / mica interface showing that the hydration shells are shared with the innermost cations [38,39].”
From Effect of Hofmeister Anions on Interfacial Properties of Mica Surface in Concentrated Aqueous Solution (2020) · cites this paper as [39]
Experimental data have indicated that bound cations and residual anions share their hydration shells on the mica surface.
“Experimental data have indicated that bound cations and residual anions share their hydration shells on the mica surface [39].”
From Effect of Hofmeister Anions on Interfacial Properties of Mica Surface in Concentrated Aqueous Solution (2020) · cites this paper as [39]
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“The presence of a specific anion at the interface can influence the coverage of cations on the negatively charged surface [39,40].”
Background
- Authors
- Pintea, S., de Poel, W., de Jong, A. E. F., Vonk, V., van der Asdonk, P., Drnec, J., Balmes, O., Isern, H., Dufrane, T., Felici, R., & Vlieg, E.
- Affiliations
- Radboud University Nijmegen (NL)
- Institute for Molecules and Materials, Radboud University, Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands
- European Synchrotron Radiation Facility (FR)
- European Synchrotron Radiation Facility, CS 40220, 38043 Grenoble Cedex 9, France
- Corresponding author
- Vlieg, Elias
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-12-02
- Volume
- 32
- Issue
- 49
- Pages
- 12955-12965
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2555075351
- Cited by
- 43
- References
- 42
- Citations by year
- 2026: 1 · 2025: 1 · 2024: 3 · 2023: 4 · 2022: 2 · 2021: 2 · 2020: 8 · 2019: 6 · 2018: 9 · 2017: 7
- FWCI
- 5.02
- Type
- journal article
- Language
- en
- Open access
- green
- bib-pubdb1.desy.de
- Locations
- Langmuir (publishedVersion)
- PubMed (publishedVersion)
- DESY Publication Database (PUBDB) (Deutsches Elektronen-Synchrotron) (submittedVersion)
- Funders
- European Synchrotron Radiation Facility
- Topics
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Electrostatics and Colloid Interactions
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Biophysics › Chemical and Physical Studies
- Physical Sciences › Materials Science › Biomaterials › Clay minerals and soil interactions
- Keywords
- muscovite, solid-liquid interface, crystal truncation rods, surface cavities, hydration shell
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