Ion-Specific and pH-Dependent Hydration of Mica–Electrolyte Interfaces
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Hydration forces play a crucial role in a wide range of phenomena in physics, chemistry, and biology. Here, we study the hydration of mica surfaces in contact with various alkali chloride solutions over a wide range of concentrations and pH values. Using atomic force microscopy and molecular dynamics simulations, we demonstrate that hydration forces consist of a superposition of a monotonically decaying and an oscillatory part, each with a unique dependence on the specific type of cation. The monotonic hydration force gradually decreases in strength with decreasing bulk hydration energy, leading to a transition from an overall repulsive (Li+, Na+) to an attractive (Rb+, Cs+) force. The oscillatory part, in contrast, displays a binary character, being hardly affected by the presence of strongly hydrated cations (Li+, Na+), but it becomes completely suppressed in the presence of weakly hydrated cations (Rb+, Cs+), in agreement with a less pronounced water structure in simulations. For both aspects, K+ plays an intermediate role, and decreasing pH follows the trend of increasing Rb+ and Cs+ concentrations.
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The correlation between the hydration strength of an anion and the decay length of the hydration force is similar to that involving kosmotropic cations.
“This correlation between hydration strength of anion and decay length of hydration force is similar to that involving kosmotropic cations [58,73].”
From Effect of Hofmeister Anions on Interfacial Properties of Mica Surface in Concentrated Aqueous Solution (2020) · cites this paper as [73]
In Results and Discussion, “Dependence on Specific Ions” (page unavailable), the paper reports that hydration-force decay lengths show no appreciable dependence on cation type. The “pH Dependence” section likewise says decay length is largely independent of added ions, while hydration-force strength varies with them. It does not establish the claimed analogous relationship for anions. (LLM, conf=0.88)
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- Authors
- van Lin, S. R., Grotz, K. K., Siretanu, I., Schwierz, N., & Mugele, F.
- Affiliations
- University of Twente , , P.O. Box 217, ,
- Max Planck Institute of Biophysics (DE)
- University of Twente (NL)
- Corresponding author
- Mugele, Frieder
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-04-11
- Volume
- 35
- Issue
- 17
- Pages
- 5737-5745
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- PMC
- PMC6495383
- OpenAlex
- W2939361347
- Cited by
- 79
- References
- 74
- Citations by year
- 2026: 13 · 2025: 8 · 2024: 7 · 2023: 16 · 2022: 13 · 2021: 8 · 2020: 11 · 2019: 3
- FWCI
- 5.78
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Locations
- Langmuir (publishedVersion, cc-by-nc-nd)
- Europe PMC (PubMed Central) (publishedVersion)
- PubMed Central (publishedVersion)
- PubMed (publishedVersion)
- University of Twente Research Information (publishedVersion, cc-by-nc-nd)
- MPG.PuRe (Max Planck Society) (submittedVersion)
- OPUS (Augsburg University) (submittedVersion, cc-by-nc-nd)
- University of Twente Research Information (submittedVersion, cc-by-nc-nd)
- Funders
- Deutsche Forschungsgemeinschaft (NA)
- Stichting voor de Technische Wetenschappen (i40)
- Topics
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Electrostatics and Colloid Interactions
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Biophysics › Chemical and Physical Studies
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Force Microscopy Techniques and Applications
- Keywords
- hydration forces, mica surface, pH dependence, hydration energy, cation hydration, alkali metal cations, water structure
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