The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Silica–Epoxy Vitrimer Nanocomposites
Abstract
Reinforced silica–epoxy vitrimer nanocomposites have been made in a solvent-free, easily processable, and economical way with filler contents up to 40 wt %. Increasing silica content leads to higher modulus materials in both glassy and rubbery regions. These nanocomposites are insoluble like permanent cross-linked networks but can completely relax stresses by thermoactivated exchange reactions that rearrange the network topology. Furthermore, the surface functionalization of particles improves the dispersion of fillers and accelerates the relaxation process. Similar results were obtained with industrial precipitated silica, which would allow vitrimer nanocomposites to be produced on an industrial scale.
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Citations
Cites
Silica-Like Malleable Materials from Permanent Organic Networks
Montarnal, D., Capelot, M., Tournilhac, F., & Leibler, L. (2011) · Science · doi:10.1126/science.1212648 · Cited by 3,625
Covalent Adaptable Networks (CANs): A Unique Paradigm in Cross-Linked Polymers
Kloxin, C. J., Scott, T. F., Adzima, B. J., & Bowman, C. N. (2010) · Macromolecules · doi:10.1021/ma902596s · Cited by 1,175
Mechanically Activated, Catalyst-Free Polyhydroxyurethane Vitrimers
Fortman, D. J., Brutman, J. P., Cramer, C. J., Hillmyer, M. A., & Dichtel, W. R. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08084 · Cited by 811
Making Insoluble Polymer Networks Malleable via Olefin Metathesis
Lu, Y.-X., Tournilhac, F., Leibler, L., & Guan, Z. (2012) · Journal of the American Chemical Society · doi:10.1021/ja303356z · Cited by 568
Cited by
Vitrimers: Permanently crosslinked polymers with dynamic network topology
Van Zee, N. J., & Nicolaÿ, R. (2020) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2020.101233 · Cited by 734
Approaches to Sustainable and Continually Recyclable Cross-Linked Polymers
Fortman, D. J., Brutman, J. P., De Hoe, G. X., Snyder, R. L., Dichtel, W. R., & Hillmyer, M. A. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b02355 · Cited by 559
Li, L., Chen, X., Jin, K., & Torkelson, J. M. (2018) · Macromolecules · doi:10.1021/acs.macromol.8b00922 · Cited by 424
Metadata
- Authors
- Legrand, A., & Soulié-Ziakovic, C.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-08-05
- Volume
- 49
- Issue
- 16
- Pages
- 5893-5902
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2503549090
- Cited by
- 238
- References
- 4
- FWCI
- 11.83
- Type
- journal article
- Language
- en
- Open access
- closed
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- Legrand, A., & Soulié-Ziakovic, C. (2016). Silica–Epoxy Vitrimer Nanocomposites. Macromolecules. https://doi.org/10.1021/acs.macromol.6b00826
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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