The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Atomic Tuning of Single-Atom Fe–N–C Catalysts with Phosphorus for Robust Electrochemical CO2 Reduction
Abstract
The electrochemical reduction of CO 2 to produce carbon-based fuels and chemicals possesses huge potentials to alleviate current environmental problems. However, it is confronted by great challenges in the design of active electrocatalysts with low overpotentials and high product selectivity. Here we report the atomic tuning of a single-Fe-atom catalyst with phosphorus (Fe–N/P–C) on commercial carbon black as a robust electrocatalyst for CO 2 reduction. The Fe–N/P–C catalyst exhibits impressive performance in the electrochemical reduction of CO 2 to CO, with a high Faradaic efficiency of 98% and a high mass-normalized turnover frequency of 508.8 h –1 at a low overpotential of 0.34 V. On the basis of ex-situ X-ray absorption spectroscopy measurements and DFT calculations, we reveal that the tuning of P in single-Fe-atom catalysts reduces the oxidation state of the Fe center and decreases the free-energy barrier of *CO intermediate formation, consequently maintaining the electrocatalytic activity and stability of single-Fe-atom catalysts.
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Cites
Direct Capture of CO2 from Ambient Air
Sanz-Pérez, E. S., Murdock, C. R., Didas, S. A., & Jones, C. W. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00173 · Cited by 2,406
Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
Yang, H. B., Hung, S.-F., Liu, S., Yuan, K., Miao, S., Zhang, L., Huang, X., Wang, H.-Y., Cai, W., Chen, R., et al. (2018) · Nature Energy · doi:10.1038/s41560-017-0078-8 · Cited by 2,239
Self-citationEnhanced electrocatalytic CO2 reduction via field-induced reagent concentration
Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., et al. (2016) · Nature · doi:10.1038/nature19060 · Cited by 2,000
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594
What Should We Make with CO2 and How Can We Make It?
Bushuyev, O. S., De Luna, P., Dinh, C. T., Tao, L., Saur, G., van de Lagemaat, J., Kelley, S. O., & Sargent, E. H. (2018) · Joule · doi:10.1016/j.joule.2017.09.003 · Cited by 1,593
Large-Scale and Highly Selective CO2 Electrocatalytic Reduction on Nickel Single-Atom Catalyst
Zheng, T., Jiang, K., Ta, N., Hu, Y., Zeng, J., Liu, J., & Wang, H. (2019) · Joule · doi:10.1016/j.joule.2018.10.015 · Cited by 887
Xia, C., Zhu, P., Jiang, Q., Pan, Y., Liang, W., Stavitski, E., Alshareef, H. N., & Wang, H. (2019) · Nature Energy · doi:10.1038/s41560-019-0451-x · Cited by 782
Cited by
Boosting Oxygen Electrocatalytic Activity of Fe–N–C Catalysts by Phosphorus Incorporation
Zhou, Y., Lu, R., Tao, X., Qiu, Z., Chen, G., Yang, J., Zhao, Y., Feng, X., & Müllen, K. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.2c12933 · Cited by 567
Metadata
- Authors
- Li, K., Zhang, S., Zhang, X., Liu, S., Jiang, H., Jiang, T., Shen, C., Yu, Y., & Chen, W.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2022-02-01
- Volume
- 22
- Issue
- 4
- Pages
- 1557-1565
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W4210407942
- Cited by
- 278
- References
- 7
- FWCI
- 10.52
- Type
- journal article
- Language
- en
- Open access
- closed
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- Li, K., Zhang, S., Zhang, X., Liu, S., Jiang, H., Jiang, T., Shen, C., Yu, Y., & Chen, W. (2022). Atomic Tuning of Single-Atom Fe–N–C Catalysts with Phosphorus for Robust Electrochemical CO2 Reduction. Nano Letters. https://doi.org/10.1021/acs.nanolett.1c04382
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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