Direct Hybridization of Noble Metal Nanostructures on 2D Metal–Organic Framework Nanosheets To Catalyze Hydrogen Evolution
Abstract
Rational hybridization of two-dimensional (2D) nanomaterials with extrinsic species has shown great promise for a wide range of applications. To date, rational design and engineering of heterostructures based on 2D metal-organic frameworks (MOFs) has been rather limited. Herein, we report an efficient strategy to construct noble metal/2D MOF heterostructures, featuring the utilization of surface oxygen sites from uncoordinated MOF ligands. The incorporation of highly dispersed noble metal nanoparticles (e.g., Pt and Pd) with modulated electronic structure is enabled on a surfactant-free MOF surface. As a proof-of-concept demonstration, the 2D Ni-MOF@Pt hybrid with well-defined interfaces is applied to boost the electrochemical hydrogen evolution reaction (HER) and delivers decent electrocatalytic activity under both acidic and alkaline conditions. The present results are expected to provide new insights into furnishing MOFs with extended functionalities and applications.
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The anchoring of Pt onto GA through O-Pt interactions can be confirmed by the appearance of component peaks in the resolved O 1s spectra of Pt-GA-x.
“Moreover, the anchoring of Pt onto GA through O-Pt interactions can be confirmed by the appearance of component peaks in the resolved O 1s spectra of Pt-GA-x (Fig. 3c) [38, 39].”
From Synergistic interaction of monodisperse Pt nanoparticles with defect‐rich graphene aerogel for efficient acidic hydrogen evolution (2025) · cites this paper as [38]
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- Authors
- Rui, K., Zhao, G., Lao, M., Cui, P., Zheng, X., Zheng, X., Zhu, J., Huang, W., Dou, S. X., & Sun, W.
- Affiliations
- Nanjing Tech University (CN)
- University of Wollongong (AU)
- Chinese Academy of Sciences (CN)
- University of Science and Technology of China (CN)
- Corresponding author
- Zhu, Jixin
- Sun, Wenping
- ORCID
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-11-06
- Volume
- 19
- Issue
- 12
- Pages
- 8447-8453
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2983189655
- Cited by
- 235
- References
- 54
- Citations by year
- 2026: 13 · 2025: 28 · 2024: 41 · 2023: 52 · 2022: 33 · 2021: 40 · 2020: 28
- FWCI
- 5.37
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Nano Letters (publishedVersion)
- PubMed (publishedVersion)
- Research Online (University of Wollongong) (submittedVersion)
- Funders
- University of Wollongong
- Ministry of Science and Technology of the People's Republic of China (2015CB932200, 2017YFA0207201)
- Natural Science Foundation of Jiangsu Province (BK20170045)
- Australian Research Council (DE160100596)
- Government of Jiangsu Province (XCL-043, XCL-021)
- China Scholarship Council
- National Natural Science Foundation of China (21501091, 51902158, 51872139)
- Recruitment Program of Global Experts (1211019)
- Natural Science Foundation of Jiangsu Higher Education Institutions (19KJB430002)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Keywords
- metal-organic framework nanosheets, noble metal nanoparticles, PT, Pd, heterostructures, hydrogen evolution reaction, electrocatalysis, surfactant-free synthesis, nickel metal-organic framework, two-dimensional materials, acidic and alkaline conditions
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