Synthesis of S-doped AuPbPt alloy nanowire-networks as superior catalysts towards the ORR and HER
Abstract
An appropriate amount of PtS in S-doped AuPbPt alloy nanowire-networks is conducive to their superior electrocatalytic performance.
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The diffraction peaks of the aerogels in the green and olive green rectangles are consistent with Pt and PtS, respectively.
“are consistent with those of the Pt”
From Realization of Au81Pd2Pt9-S8B4.6A3.4 aerogels as superior catalysts toward HER and ORR by synergism of coarse and fine tuning d-band center of Pt (2023) · cites this paper as [21]
The AuPb3, PbS and PbS2 in the S-doped AuPb networks are involved in the formation of AuPdPt, PtS, Pd2.8S and Pd(II)-Pt(II)S2 during conversion to the aerogels, and Pb diffuses into the reaction media.
“This is because the AuPb3,”
From Realization of Au81Pd2Pt9-S8B4.6A3.4 aerogels as superior catalysts toward HER and ORR by synergism of coarse and fine tuning d-band center of Pt (2023) · cites this paper as [21]
The long-time stability of S-doped AuPbPt alloy nanowire-networks towards the HER and ORR is significantly improved due to the formation of a proper portion of PtS on their outermost surface to enhance oxidation resistance.
“their long-time stability towards the HER and the ORR is significantly improved due to the formation of a proper”
From Realization of Au81Pd2Pt9-S8B4.6A3.4 aerogels as superior catalysts toward HER and ORR by synergism of coarse and fine tuning d-band center of Pt (2023) · cites this paper as [21]
S-doped AuPbPt alloy nanowire-networks exhibit ORR activity in acidic media with E1/2 = 0.921 V and ΔE1/2 = 60 mV, and HER activity with η10 = 12 mV and Δη10 = 17 mV, compared with commercial Pt/C (ORR E1/2 = 0.861 V; HER η10 = 29 mV).
“S-doped AuPbPt alloy nanowire-networks (NWNs) exhibit excellent electro”
From Realization of Au81Pd2Pt9-S8B4.6A3.4 aerogels as superior catalysts toward HER and ORR by synergism of coarse and fine tuning d-band center of Pt (2023) · cites this paper as [21]
The broader CO adsorption potential range suggests increasing adsorption active sites on the surfaces of the as-prepared Au81Pd2Pt9-S8B4.6A3.4 aerogels.
“The results suggest the”
From Realization of Au81Pd2Pt9-S8B4.6A3.4 aerogels as superior catalysts toward HER and ORR by synergism of coarse and fine tuning d-band center of Pt (2023) · cites this paper as [21]
The formation of PtS on the outermost surfaces of Au81Pd2Pt9-S8B4.6A3.4 aerogels can enhance the anti-oxidation ability.
“indicating that the formation of PtS on the outermost surfaces of the Au81Pd2Pt9-S8 B4.6A3.4 aerogels indeed can enhance the anti-oxidation ability [21,65].”
From Realization of Au81Pd2Pt9-S8B4.6A3.4 aerogels as superior catalysts toward HER and ORR by synergism of coarse and fine tuning d-band center of Pt (2023) · cites this paper as [21]
AuPt-S aerogels with only apical S2- ligands exhibit excellent HER and ORR performance in acid media and unstable excellent ORR performance in alkaline media.
“Accordingly, AuPt-S aerogels just exhibit excellent HER and ORR performance in acid media and unstably excellent ORR performance in alkaline media.”
From Realization of Au81Pd2Pt9-S8B4.6A3.4 aerogels as superior catalysts toward HER and ORR by synergism of coarse and fine tuning d-band center of Pt (2023) · cites this paper as [21]
In AuPt-S aerogels with only apical S2- ligands forming PtS, the d-band center of Pt shifts positively by about 0.9 eV relative to pure Pt NPs.
“when only apical S2- ligands are introduced into the AuPt-S aerogels to form PtS in our another work [21], the sole presence of apical S2- ligands renders the d-band center of Pt in AuPt-S aerogels positively shift about 0.9 eV, compared with pure Pt NPs.”
From Realization of Au81Pd2Pt9-S8B4.6A3.4 aerogels as superior catalysts toward HER and ORR by synergism of coarse and fine tuning d-band center of Pt (2023) · cites this paper as [21]
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411Chapter 9 Electrocatalyticelectrocatalytic hydrogenhydrogen productionproduction
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- Authors
- Zhang, X., Wang, S., Wu, C., Li, H., Cao, Y., Li, S., & Xia, H.
- Affiliations
- Shandong University (CN)
- Zhejiang University of Technology (CN)
- Chinese Academy of Sciences (CN)
- Corresponding author
- Wang, Shibin
- Xia, Haibing
- Venue
- Journal of Materials Chemistry A
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2020
- Volume
- 8
- Issue
- 45
- Pages
- 23906-23918
- ISSN
- 2050-7488 (ISSN-L)
- 2050-7496
- OpenAlex
- W3093511984
- Cited by
- 54
- References
- 77
- Citations by year
- 2026: 8 · 2025: 8 · 2024: 12 · 2023: 10 · 2022: 8 · 2021: 8
- FWCI
- 1.29
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Materials Chemistry A (publishedVersion)
- Funders
- National Natural Science Foundation of China (21773142)
- Taishan Scholar Foundation of Shandong Province (tsqn20161001)
- Fundamental Research Fund of Shandong University
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › Catalytic Processes in Materials Science
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Keywords
- nanowire networks, PTS, oxygen reduction reaction, hydrogen evolution reaction, electrocatalysts, sulfur doping, bimetallic catalysts
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