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Highly Flexible Freestanding Porous Carbon Nanofibers for Electrodes Materials of High-Performance All-Carbon Supercapacitors
Open accessAbstract
Highly flexible porous carbon nanofibers (P-CNFs) were fabricated by electrospining technique combining with metal ion-assistant acid corrosion process. The resultant fibers display high conductivity and outstanding mechanical flexibility, whereas little change in their resistance can be observed under repeatedly bending, even to 180°. Further results indicate that the improved flexibility of P-CNFs can be due to the high graphitization degree caused by Co ions. In view of electrode materials for high-performance supercapacitors, this type of porous nanostructure and high graphitization degree could synergistically facilitate the electrolyte ion diffusion and electron transportation. In the three electrodes testing system, the resultant P-CNFs electrodes can exhibit a specific capacitance of 104.5 F g(-1) (0.2 A g(-1)), high rate capability (remain 56.5% at 10 A g(-1)), and capacitance retention of ∼94% after 2000 cycles. Furthermore, the assembled symmetric supercapacitors showed a high flexibility and can deliver an energy density of 3.22 Wh kg(-1) at power density of 600 W kg(-1). This work might open a way to improve the mechanical properties of carbon fibers and suggests that this type of freestanding P-CNFs be used as effective electrode materials for flexible all-carbon supercapacitors.
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Cited by
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Self-citation
Metadata
- Authors
- Liu, Y., Zhou, J., Chen, L., Zhang, P., Fu, W., Zhao, H., Ma, Y., Pan, X., Zhang, Z., Han, W., & Xie, E.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-10-16
- Volume
- 7
- Issue
- 42
- Pages
- 23515-23520
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2196989200
- Cited by
- 285
- References
- 22
- FWCI
- 9.00
- Type
- journal article
- Language
- en
- Open access
- green
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