The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.
Suppressing the Phase Transition of the Layered Ni-Rich Oxide Cathode during High-Voltage Cycling by Introducing Low-Content Li2MnO3
Abstract
The layered Ni-rich oxide cathode (LiNi0.8Co0.1Mn0.1O2) suffers from a tremendous structural degradation during high-voltage cycling (4.8 V), causing the drastic rise of electrode impedance and deterioration of the capacity retention. Here, we develop an effective strategy to overcome these problems of the Ni-rich cathode material through doping low-content Li2MnO3 as an excellent structure stabilizer. Cyclic voltammogram and ex-situ X-ray diffraction measurements have reveled that Li2MnO3 could display a remarkable suppression effect on the phase transition of LiNi0.8Co0.1Mn0.1O2. The electrochemical tests showed that Li2MnO3-stabilized LiNi0.8Co0.1Mn0.1O2 could realize the large reversible capacity, stable discharge voltage and excellent cycling life during high-voltage cycling, which could be benefited from the enhanced structural stability of the modified Ni-rich cathode. The Li2MnO3 could sufficiently suppress the phase transition between two hexagonal phase (H2 and H3) with distinctly different lattice parameters, significantly reducing variation of unit-cell volume, which facilitates stabilization of the original layered structure of LiNi0.8Co0.1Mn0.1O2 cathode during high-voltage cycling.
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Cites
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Cited by
Holoubek, J., Yu, M., Yu, S., Li, M., Wu, Z., Xia, D., Bhaladhare, P., Gonzalez, M. S., Pascal, T. A., Liu, P., et al. (2020) · ACS Energy Letters · doi:10.1021/acsenergylett.0c00643 · Cited by 351
Advances in Structure and Property Optimizations of Battery Electrode Materials
Meng, J., Guo, H., Niu, C., Zhao, Y., Xu, L., Li, Q., & Mai, L. (2017) · Joule · doi:10.1016/j.joule.2017.08.001 · Cited by 312
Metadata
- Authors
- Yang, J., & Xia, Y.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-01-05
- Volume
- 8
- Issue
- 2
- Pages
- 1297-1308
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2337376462
- Cited by
- 334
- References
- 27
- FWCI
- 8.98
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yang, J., & Xia, Y. (2016). Suppressing the Phase Transition of the Layered Ni-Rich Oxide Cathode during High-Voltage Cycling by Introducing Low-Content Li2MnO3. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.5b09938
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