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Mixed 1T–2H Phase MoS2/Reduced Graphene Oxide as Active Electrode for Enhanced Supercapacitive Performance
Abstract
A hybrid aerogel, composed of MoS 2 sheets of 1T (distorted octahedral) and 2H (trigonal prismatic) phases, finely mixed with few layers of reduced graphene oxide (rGO) and obtained by means of a facile environment-friendly hydrothermal cosynthesis, is proposed as electrode material for supercapacitors. By electrochemical characterizations in three- and two-electrode configurations and symmetric planar devices, unique results have been obtained, with specific capacitance values up to 416 F g -1 and a highly stable capacitance behavior over 50000 charge-discharge cycles. The in-depth morphological and structural characterizations through field emission scanning electron microscopy, Raman, X-ray photoelectron spectroscopy, X-ray diffraction, Brunauer-Emmett-Teller, and transmission electron microscopy analysis provides the proofs of the unique assembly of such 3D structured matrix. The unpacked MoS 2 structure exhibits an excellent distribution of 1T and 2H phase sheets that are highly exposed to interaction with the electrolyte, and so available for surface/near-surface redox reactions, notwithstanding the quite low overall content of MoS 2 embedded in the reduced graphene oxide (rGO) matrix. A comparison with other "more conventional" hybrid rGO-MoX 2 electrochemically active materials, synthesized in the same conditions, is provided to support the outstanding behavior of the cosynthesized rGO-MoS 2 .
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“Such graphene-based nanocomposites have the potential to ameliorate energy storage devices by leveraging the ample specific surface area of graphene and Faradaic redox reactions of TMDs or LDHs.27−32”
From Integrated Energy Aerogel of N,S-rGO/WSe 2 /NiFe-LDH for Both Energy Conversion and Storage (2017) · cites this paper as [27]
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Cites
Thommes, M., Kaneko, K., Neimark, A. V., Olivier, J. P., Rodriguez-Reinoso, F., Rouquerol, J., & Sing, K. S. W. (2015) · Pure and Applied Chemistry · doi:10.1515/pac-2014-1117 · Cited by 21,202
Materials for electrochemical capacitors
Simon, P., & Gogotsi, Y. G. (2008) · Nature Materials · doi:10.1038/nmat2297 · Cited by 16,636
Emerging Photoluminescence in Monolayer MoS 2
Splendiani, A., Sun, L., Zhang, Y., Li, T., Kim, J., Chim, C. Y., Galli, G., & Wang, F. (2010) · Nano Letters · doi:10.1021/nl903868w · Cited by 9,615
What are batteries, fuel cells, and supercapacitors?
Winter, M., & Brodd, R. J. (2004) · Chemical Reviews · doi:10.1021/cr020730k · Cited by 7,389
The reduction of graphene oxide
Pei, S., & Cheng, H. (2011) · Carbon · doi:10.1016/j.carbon.2011.11.010 · Cited by 5,271
Quantifying Defects in Graphene via Raman Spectroscopy at Different Excitation Energies
Cançado, L. G., Jório, A., Ferreira, E. H. M., Junior, F. L. S., Achete, C. A., Capaz, R. B., Moutinho, M. V. O., Lombardo, A., Kulmala, T. S., & Ferrari, A. C. (2011) · Nano Letters · doi:10.1021/nl201432g · Cited by 3,727
Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process
Xu, Y., Sheng, K., Li, C., & Shi, G. (2010) · ACS Nano · doi:10.1021/nn101187z · Cited by 3,251
Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems
Ferrari, A. C., Bonaccorso, F., Fal’ko, V. I., Novoselov, K. S., Roche, S., Bøggild, P., Borini, S., Koppens, F. H. L., Palermo, V., Pugno, N. M., et al. (2014) · Nanoscale · doi:10.1039/c4nr01600a · Cited by 3,065
Review on supercapacitors: Technologies and materials
González, A., Goikolea, E., Barrena, J. A., & Mysyk, R. (2016) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2015.12.249 · Cited by 3,011
Metallic 1T phase MoS2 nanosheets as supercapacitor electrode materials
Acerce, M., Voiry, D., & Chhowalla, M. (2015) · Nature Nanotechnology · doi:10.1038/nnano.2015.40 · Cited by 2,810
Electrochemical Characteristics and Impedance Spectroscopy Studies of Carbon-Carbon Supercapacitors
Taberna, P., Simon, P., & Fauvarque, J. F. (2003) · Journal of The Electrochemical Society · doi:10.1149/1.1543948 · Cited by 2,024
Chang, K., & Chen, W. (2011) · ACS Nano · doi:10.1021/nn200659w · Cited by 1,663
3D carbon based nanostructures for advanced supercapacitors
Jiang, H., Lee, P. S., & Li, C. (2012) · Energy & Environmental Science · doi:10.1039/c2ee23284g · Cited by 1,521
Ultralight and Highly Compressible Graphene Aerogels
Hu, H., Zhao, Z., Wan, W., Gogotsi, Y. G., & Qiu, J. (2013) · Advanced Materials · doi:10.1002/adma.201204530 · Cited by 1,389
Flexible solid-state supercapacitors: design, fabrication and applications
Lu, X., Yu, M., Wang, G., Tong, Y., & Li, Y. (2014) · Energy & Environmental Science · doi:10.1039/c4ee00960f · Cited by 1,326
Surface Analysis by Auger and X-Ray Photoelectron Spectroscopy
Briggs, D., & Grant, J. T. (1983) · Cited by 1,118
Hybrid nanostructured materials for high-performance electrochemical capacitors
Yu, G., Xie, X., Pan, L., Bao, Z., & Cui, Y. (2012) · Nano Energy · doi:10.1016/j.nanoen.2012.10.006 · Cited by 1,113
Vacancy-Induced Ferromagnetism of MoS 2 Nanosheets
Cai, L., He, J., Liu, Q., Yao, T., Chen, L., Yan, W., Hu, F., Jiang, Y., Zhao, Y., Hu, T., et al. (2015) · Journal of the American Chemical Society · doi:10.1021/ja5120908 · Cited by 835
Porous Graphene Materials for Advanced Electrochemical Energy Storage and Conversion Devices
Han, S., Wu, D., Li, S., Zhang, F., & Feng, X. (2013) · Advanced Materials · doi:10.1002/adma.201303115 · Cited by 711
Two-dimensional layered MoS 2 : rational design, properties and electrochemical applications
Zhang, G., Liu, H., Qu, J., & Li, J. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03761a · Cited by 647
Free-standing graphene at atomic resolution
Gass, M. H., Bangert, U., Bleloch, A. L., Wang, P., Nair, R. R., & Geim, A. K. (2008) · Nature Nanotechnology · doi:10.1038/nnano.2008.280 · Cited by 647
Baltrušaitis, J., Mendoza‐Sánchez, B., Fernandez, V., Veenstra, R., Dukštienė, N., Roberts, A. J., & Fairley, N. (2014) · Applied Surface Science · doi:10.1016/j.apsusc.2014.11.077 · Cited by 565
Structures and Phase Transition of a MoS 2 Monolayer
Kan, M., Wang, J. Y., Li, X. W., Zhang, S. H., Li, Y., Kawazoe, Y., Sun, Q., & Jena, P. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp4076355 · Cited by 500
Electrochemical Double-Layer Capacitance of MoS[sub 2] Nanowall Films
Soon, J. M., & Loh, K. P. (2007) · Electrochemical and Solid-State Letters · doi:10.1149/1.2778851 · Cited by 477
Characterization of MoS2–Graphene Composites for High-Performance Coin Cell Supercapacitors
Bissett, M. A., Kinloch, I. A., & Dryfe, R. A. W. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b04672 · Cited by 460
Rao, C. N. R., Gopalakrishnan, K., & Maitra, U. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/am509096x · Cited by 414
Fu, C., Zhao, G., Zhang, H., & Li, S. (2013) · International Journal of Electrochemical Science · doi:10.1016/s1452-3981(23)14760-2 · Cited by 344
Supercapacitive properties of hydrothermally synthesized sphere like MoS2 nanostructures
Krishnamoorthy, K., Veerasubramani, G. K., Radhakrishnan, S., & Kim, S. (2013) · Materials Research Bulletin · doi:10.1016/j.materresbull.2013.11.019 · Cited by 302
Graphene-based materials with tailored nanostructures for energy conversion and storage
Yang, Y., Han, C., Jiang, B., Iocozzia, J., He, C., Shi, D., Jiang, T., & Lin, Z. (2016) · Materials Science and Engineering R Reports · doi:10.1016/j.mser.2015.12.003 · Cited by 279
Three-dimensional graphene-based composites for energy applications
Mao, S., Lu, G., & Chen, J. (2014) · Nanoscale · doi:10.1039/c4nr06609j · Cited by 275
Thangappan, R., Kalaiselvam, S., Elayaperumal, A., Jayavel, R., Arivanandhan, M., Karthikeyan, R., & Hayakawa, Y. (2015) · Dalton Transactions · doi:10.1039/c5dt04832j · Cited by 263
Comparison of Two-Dimensional Transition Metal Dichalcogenides for Electrochemical Supercapacitors
Bissett, M., Worrall, S., Kinloch, I., & Dryfe, R. (2016) · Electrochimica Acta · doi:10.1016/j.electacta.2016.03.190 · Cited by 238
Xiong, F., Cai, Z., Qu, L., Zhang, P., Yuan, Z., Owusu, K. A., Xu, W., Lin, C., & Mai, L. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b02978 · Cited by 202
Wu, Z., Li, B., Xue, Y., Li, J., Zhang, Y., & Gao, F. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta04549e · Cited by 199
Qin, W., Chen, T., Pan, L., Niu, L., Hu, B., Li, D., Li, J., & Sun, Z. (2014) · Electrochimica Acta · doi:10.1016/j.electacta.2014.11.034 · Cited by 185
Taberna, P., Portet, C., & Simon, P. (2005) · Applied Physics A · doi:10.1007/s00339-005-3404-0 · Cited by 182
Sha, C., Lu, B., Mao, H., Cheng, J. P., Pan, X., Lü, J., & Ye, Z. (2015) · Carbon · doi:10.1016/j.carbon.2015.11.066 · Cited by 168
Extraordinary attributes of 2-dimensional MoS2 nanosheets
Rao, C. N. R., Maitra, U., & Waghmare, U. V. (2014) · Chemical Physics Letters · doi:10.1016/j.cplett.2014.06.003 · Cited by 158
X-ray photoelectron spectroscopy characterization of amorphous molybdenum oxysulfide thin films
Benoist, L., Gonbeau, D., Pfister‐Guillouzo, G., Schmidt, E., Meunier, G., & Levasseur, A. (1995) · Thin Solid Films · doi:10.1016/0040-6090(94)06383-4 · Cited by 158
Synthesis of rGO-supported layered MoS2 for high-performance rechargeable Mg batteries
Liu, Y., Jiao, L., Wu, Q., Zhao, Y., Cao, K., Liu, H., Wang, Y., & Yuan, H. (2013) · Nanoscale · doi:10.1039/c3nr02850j · Cited by 139
Ji, H., Liu, X., Liu, Z., Yan, B., Chen, L., Xie, Y., Liu, C., Hou, W., & Yang, G. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201404378 · Cited by 133
Graphene based 2D-materials for supercapacitors
Palaniselvam, T., & Baek, J. (2015) · 2D Materials · doi:10.1088/2053-1583/2/3/032002 · Cited by 127
In-situ and tunable nitrogen-doping of MoS2 nanosheets
Qin, S. A., Lei, W., Liu, D., & Chen, Y. I. (2014) · Scientific Reports · doi:10.1038/srep07582 · Cited by 123
Applications of XPS in bioengineering
McArthur, S. L. (2006) · Surface and Interface Analysis · doi:10.1002/sia.2498 · Cited by 115
Hydrothermal fabrication of porous MoS2 and its visible light photocatalytic properties
Zhou, Z., Lin, Y., Zhang, P., Ashalley, E., Shafa, M., Li, H., Wu, J., & Wang, Z. (2014) · Materials Letters · doi:10.1016/j.matlet.2014.05.162 · Cited by 99
Ye, J., Ma, L., Chen, W., Ma, Y., Huang, F., Gao, C., & Lee, J. Y. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta00006h · Cited by 96
Huang, K., Wang, L., Zhang, J.-Z., & Xing, K. (2015) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2015.06.005 · Cited by 87
Yusoff, A. R. B. M., Dai, L., Cheng, H., & Liu, J. (2015) · Nanoscale · doi:10.1039/c5nr90062j · Cited by 76
Synthesis of large scale MoS 2 for electronics and energy applications
Choudhary, N., Patel, M. D., Park, J., Sirota, B., & Choi, W. (2016) · Journal of materials research/Pratt's guide to venture capital sources · doi:10.1557/jmr.2016.100 · Cited by 64
A powerful tool for graphene functionalization: Benzophenone mediated UV-grafting
Roppolo, I., Chiappone, A., Bejtka, K., Celasco, E., Chiodoni, A. M., Giorgis, F., Sangermano, M., & Porro, S. (2014) · Carbon · doi:10.1016/j.carbon.2014.05.025 · Cited by 48
Giardi, R., Porro, S., Topuria, T., Thompson, L. E., Pirri, C. F., & Kim, H. (2015) · Applied Materials Today · doi:10.1016/j.apmt.2015.08.001 · Cited by 47
Self-citationCui, Y., He, J., Yuan, F., Xue, J., Li, X., & Wang, J. (2016) · Hydrometallurgy · doi:10.1016/j.hydromet.2016.05.002 · Cited by 29
Gopalakrishnan, K., Pramoda, K., Maitra, U., Mahima, U., Shah, M. A., & Rao, C. N. R. (2014) · Nanomaterials and Energy · doi:10.1680/nme.14.00024 · Cited by 25
A novel graphene based nanocomposite for application in 3D flexible micro-supercapacitors
Marasso, S. L., Rivolo, P., Giardi, R., Mombello, D., Gigot, A., Serrapede, M., Benetto, S., Enrico, A., Cocuzza, M., Tresso, E. M., et al. (2016) · Materials Research Express · doi:10.1088/2053-1591/3/6/065001 · Cited by 14
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Pham, P. V., Bodepudi, S. C., Shehzad, K., Liu, Y., Xu, Y., Yu, B., & Duan, X. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00735 · Cited by 736
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Metadata
- Authors
- Gigot, A., Fontana, M., Serrapede, M., Castellino, M., Bianco, S., Armandi, M., Bonelli, B., Pirri, C. F., Tresso, E., & Rivolo, P.
- Affiliations
- Politecnico di Torino (IT)
- Italian Institute of Technology (IT)
- Corresponding author
- Rivolo, Paola
- ORCID
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-11-21
- Volume
- 8
- Issue
- 48
- Pages
- 32842-32852
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2553462613
- Cited by
- 164
- References
- 54
- Citations by year
- 2026: 9 · 2025: 14 · 2024: 14 · 2023: 17 · 2022: 19 · 2021: 10 · 2020: 25 · 2019: 19 · 2018: 30 · 2017: 7
- FWCI
- 5.87
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ACS Applied Materials & Interfaces (publishedVersion)
- PubMed (publishedVersion)
- PORTO@Iris (submittedVersion)
- PORTO Publications Open Repository TOrino (Politecnico di Torino) (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
- Physical Sciences › Materials Science › Materials Chemistry › MXene and MAX Phase Materials
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Keywords
- MoS2, reduced graphene oxide, supercapacitor electrodes, hybrid aerogels, specific capacitance, cycling stability, MoS2/rGO composite
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