The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Rapid, Microwave-Assisted Synthesis of Cubic, Three-Dimensional, Highly Porous MOF-205 for Room Temperature CO2 Fixation via Cyclic Carbonate Synthesis
Abstract
A dual-porous, three-dimensional, metal–organic framework [Zn 4 O(2,6-NDC)(BTB) 4/3 ] (MOF-205, BET = 4200 m 2 /g) has been synthesized using microwave power as an alternative energy source for the first time, and its catalytic activity has been exploited for CO 2 –epoxide coupling reactions to produce five-membered cyclic carbonates under solvent-free conditions. Microwave synthesis was performed at different time intervals to reveal the formation of the crystals. Significant conversion of various epoxides was obtained at room temperature, with excellent selectivity toward the desired five-membered cyclic carbonates. The importance of the dual porosity and the synergistic effect of quaternary ammonium salts on efficiently catalyzed CO 2 conversion were investigated using various experimental and physicochemical characterization techniques, and the results were compared with those of the solvothermally synthesized MOF-205 sample. On the basis of literature and experimental inferences, a rationalized mechanism mediated by the zinc center of MOF-205 for the CO 2 –epoxide cycloaddition reaction has been proposed.
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Cites
Recent advances in catalytic hydrogenation of carbon dioxide
Wang, W., Wang, S., Ma, X., & Gong, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15008a · Cited by 3,316
The synthesis of organic carbonates from carbon dioxide
Sakakura, T., & Kohno, K. (2009) · Chemical Communications · doi:10.1039/b819997c · Cited by 1,067
Cited by
Yusuf, V. F., Malek, N. I., & Kailasa, S. K. (2022) · ACS Omega · doi:10.1021/acsomega.2c05310 · Cited by 894
Liang, J., Huang, Y.-B., & Cao, R. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.11.013 · Cited by 444
Cui, W.-G., Zhang, G.-Y., Hu, T.-L., & Bu, X.-H. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.02.001 · Cited by 406
Taking organic reactions over metal-organic frameworks as heterogeneous catalysis
Hu, M.-L., Safarifard, V., Doustkhah, E., Rostamnia, S., Morsali, A., Nouruzi, N., Beheshti, S., & Akhbari, K. (2018) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2017.07.057 · Cited by 283
Formation of CX Bonds in CO2 Chemical Fixation Catalyzed by Metal−Organic Frameworks
Hou, S., Dong, J., & Zhao, B. (2020) · Advanced Materials · doi:10.1002/adma.201806163 · Cited by 142
Metadata
- Authors
- Babu, R., Roshan, R., Kathalikkattil, A. C., Kim, D. W., & Park, D.-W.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-11-29
- Volume
- 8
- Issue
- 49
- Pages
- 33723-33731
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2554754498
- Cited by
- 177
- References
- 2
- FWCI
- 6.51
- Type
- journal article
- Language
- en
- Open access
- closed
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- Babu, R., Roshan, R., Kathalikkattil, A. C., Kim, D. W., & Park, D.-W. (2016). Rapid, Microwave-Assisted Synthesis of Cubic, Three-Dimensional, Highly Porous MOF-205 for Room Temperature CO2 Fixation via Cyclic Carbonate Synthesis. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.6b12458
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