The DOI matches its Crossref record; 18 of the 18 references it cites were found in a registry or an index.
Dominating Role of Ni0 on the Interface of Ni/NiO for Enhanced Hydrogen Evolution Reaction
Abstract
The research of a robust catalytic system based on single NiO x electrocatalyst for hydrogen evolution reaction (HER) remains a huge challenge. Particularly, the factors that dominate the catalytic properties of NiO x -based hybrids for HER have not been clearly demonstrated. Herein, a convenient protocol for the fabrication of NiO x @bamboo-like carbon nanotube hybrids (NiO x @BCNTs) is designed. The hybrids exhibit superb catalytic ability and considerable durability in alkaline solution. A benchmark HER current density of 10 mA cm –2 has been achieved at an overpotential of ∼79 mV. In combination with the experimental results and density functional theory (DFT) calculations, this for the first time definitely validates that the inherent high Ni 0 ratio and the Ni 0 on the interface of Ni/NiO play a vital role in the outstanding catalytic performance. Especially, the Ni 0 on the interface of Ni/NiO performs superior activity for water splitting compared with that of bulk Ni 0 . These conclusions provide guidance for the rational design of the future non-noble metallic catalysts.
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Cites
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
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Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
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Hydrogen evolution by a metal-free electrocatalyst
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Self-citationHigh-Performance Electrocatalysis Using Metallic Cobalt Pyrite (CoS2) Micro- and Nanostructures
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Cited by
Sun, H., Ma, Z., Qiu, Y., Liu, H., & Gao, G. (2018) · Small · doi:10.1002/smll.201800294 · Cited by 175
Chen, J., Qin, M., Ma, S., Fan, R., Zheng, X., Mao, S., Chen, C., & Wang, Y. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120640 · Cited by 95
Self-citationDo, H. H., Tekalgne, M. A., Le, Q. V., Cho, J. H., Ahn, S. H., & Kim, S. Y. (2023) · Nano Convergence · doi:10.1186/s40580-023-00354-w · Cited by 84
Zhang, X., Li, Y., Guo, Y., Hu, A., Li, M., Hang, T., & Ling, H. (2019) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2019.09.193 · Cited by 71
Construction of Ru/WO3 with hetero-interface structure for efficient hydrogen evolution reaction
Xie, X., Fan, Y., Tian, W., Zhang, M., Cai, J., Zhang, X., Ding, J., Liu, Y., & Lu, S. (2023) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2023.04.026 · Cited by 56
Metadata
- Authors
- Wang, J., Mao, S., Liu, Z., Wei, Z., Wang, H., Chen, Y., & Wang, Y.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-02-15
- Volume
- 9
- Issue
- 8
- Pages
- 7139-7147
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2586523306
- Cited by
- 256
- References
- 18
- FWCI
- 7.26
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, J., Mao, S., Liu, Z., Wei, Z., Wang, H., Chen, Y., & Wang, Y. (2017). Dominating Role of Ni0 on the Interface of Ni/NiO for Enhanced Hydrogen Evolution Reaction. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.6b15377
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