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Dominating Role of Ni0 on the Interface of Ni/NiO for Enhanced Hydrogen Evolution Reaction
Abstract
The research of a robust catalytic system based on single NiO x electrocatalyst for hydrogen evolution reaction (HER) remains a huge challenge. Particularly, the factors that dominate the catalytic properties of NiO x -based hybrids for HER have not been clearly demonstrated. Herein, a convenient protocol for the fabrication of NiO x @bamboo-like carbon nanotube hybrids (NiO x @BCNTs) is designed. The hybrids exhibit superb catalytic ability and considerable durability in alkaline solution. A benchmark HER current density of 10 mA cm –2 has been achieved at an overpotential of ∼79 mV. In combination with the experimental results and density functional theory (DFT) calculations, this for the first time definitely validates that the inherent high Ni 0 ratio and the Ni 0 on the interface of Ni/NiO play a vital role in the outstanding catalytic performance. Especially, the Ni 0 on the interface of Ni/NiO performs superior activity for water splitting compared with that of bulk Ni 0 . These conclusions provide guidance for the rational design of the future non-noble metallic catalysts.
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Self-citation
Metadata
- Authors
- Wang, J., Mao, S., Liu, Z., Wei, Z., Wang, H., Chen, Y., & Wang, Y.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-02-15
- Volume
- 9
- Issue
- 8
- Pages
- 7139-7147
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2586523306
- Cited by
- 256
- References
- 59
- FWCI
- 7.26
- Type
- journal article
- Language
- en
- Open access
- closed
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